• Membrane Journal
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• v.18 no.4
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• pp.336-344
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• 2008

This manuscript deals with the investigation of the possibility of the crosslinked poly(vinyl alcohol) membranes with both poly(styrene sulfonic acid-co-maleic acid) and 3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA) for the fuel cell application. The studies were focused on the characterization of the resulting membranes through water content, thermal gravimetric analysis, ion exchange capacity, ion conductivity and methanol permeability measurements and then compared with the existing Nafion membrane. Typically, the ion conductivity lied in the range of $10^{-3}$ to $10^{-2}\;S/cm$ while the methanol permeability showed the range of $10^{-6}$ to $10^{-8}\;cm^2/s$.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.288-291
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• 2008

This paper describes a new S-PVA cell structure which achieves enhanced contrast ratio by adopting a step-like patterned common electrode between the high sub-pixel and low sub-pixel electrodes without loss of transmittance. A 24-inch panel was developed for monitor applications and measured contrast ratio and white luminance were over 2500:1 and 400cd/m2, respectively.

• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.421-428
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• 1998

The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

• Journal of Information Display
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• v.6 no.2
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• pp.16-18
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• 2005

Hybrid insulator pentacene thin film transistors (TFTs) are fabricated with thermally grown oxide and cross-linked polyvinylalcohol (PVA) including surface treatment by dilute ploymethylmethacrylate (PMMA) layer on $n^+$ doped silicon wafer. Through the optimization of $SiO_2$ layer thickness in hybrid insulator structure, carrier mobility is increased to more than 35 times than that of the TFT which has only a gate insulator of $SiO_2$ at the same electric field. The carrier mobility of $1.80cm^2$/V-s, subthreshold swing of 1.81 V/decade, and $I_{on}/I_{off}$ current ratio> $1.10{\times}10^5$ are obtained less than -30 V bias condition. The result is one of the best reported performances of pentacene TFTs with hybrid insulator including cross-linked PVA layer as a gate insulator at relatively low voltage operation.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08b
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• pp.1639-1641
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• 2007

We have designed cost competitive pixel structures for high performance mobile PVA LCDs. These new structures significantly bring down the price by the use of a conventional polarizer for lowest possible cost. A 4.3" prototype based on these techniques was built, achieving the world's highest mobile display contrast ratio of 1200:1, while maintaining wide viewing angle with no loss of transmittance

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.147-148
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• 2017

In this study, the tensile properties of mono and hybrid fiber reinforced cement-based composite according to fiber blending ratio under the high strain rate was evaluated. Experimental results, the HSF1.5PVA0.5 shown the highest tensile strength because the PVA fiber suppressed the micro cracks in the matrix around the hooked steel fiber and improved the pull-out resistance of hooked steel fiber. Thus, DIF of strain capacity and fracture toughness of HSF1.5PVA were greatly improved. Also, the fracture toughness was greatly improved because the tensile stress was slowly decreased after the peak stress by improvement of the pull-out resistance of hooked steel fiber at strain rate 101/s.

• Korean Membrane Journal
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• v.11 no.1
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• pp.1-7
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• 2009

This work reports the preparation of proton conductive crosslinked polymer electrolyte membranes by blending poly(vinyl chloride)-g-poly(hydroxyl ethyl acrylate) (PVC-g-PHEA) and poly(vinyl alcohol) (PVA). The PHEA chains of the graft copolymer were crosslinked with PVA using sulfosuccinic acid (SA) via the esterification reaction between -OH of polymer matrix and -COOH of SA. The PVC-g-PHEA graft copolymer was synthesized via atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of PVC backbones. Ion exchange capacity (IEC) continuously increased with increasing concentrations of SA, due to the increasing portion of charged groups in the membrane. However, the water uptake increased up to 20.0 wt% of SA concentration above which it decreased monotonically. The membrane exhibited a maximum proton conductivity of 0.026 S/cm at 20.0 wt% of SA concentration, which is presumably due to competitive effect between the increase of ionic sites and the crosslinking reaction.

• Information Display
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• v.21 no.6
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• pp.46-56
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• 2020

액정 모드 기술은 TFT-LCD의 화질, 공정, 비용을 결정짓는 핵심 기술로 당시 일본에 의해 새로운 개념의 광시야각 액정 모드들이 먼저 개발되었지만 한국의 엔지어들의 노력으로 순수 우리 기술을 개발해 상품화한 것은 돌이켜보면 대단한 일이었다고 본다. 당시 후발 주자인 국내 업계와 학연은 일본의 기술을 배우고 따라잡기 위해 일본어 공부를 하면서 일본어로 된 전문서적을 읽고 학회에서 일본 연구자들에 자존심을 버리고 끊임없는 질문으로 기술을 배웠다. 이러한 상황에서도 삼성의 연구자들은 당시 MTA보다 한 단계 향상된 PVA 모드를 개발해 세계 최초의 30인치 TV에 적용시켜 상용화했을 뿐만 아니라 엘지디스플레이의 연구자들은 IPS 기술을 발전시켜 대형 IPS TV의 세계시장을 주도하였다. 당시 제일 후발주자였던 하이디스 엔지니어들은 FFS란 액정 모드를 개발해 현재 일본 뿐만 아니라 세계의 모든 TFT-LCD 업체가 이 기술을 이용하여 제품을 양산하고 있고 향후에도 미니 LED 기술과 접목하여 고화질 LCD 기술을 주도할 것으로 보인다. 이러한 기술 개발로 액정 기술 분야에서 한국 연구자들이 세계적으로 인정받고 있다고 감히 말할 수 있다. 현재 신개념의 디스플레이 분야에서도 한국이 리드를 하고 있다고 보는데 많은 후배 연구자들이 디스플레이 역사의 한 페이지를 장식할 혁신 기술을 개발하고 있는 것을 응원한다. 마지막으로 필자의 경험을 바탕으로 평가한 각 기술들에 대해 다른 전문가들과 이견이 있을 수도 있음을 명시하며, IPS와 PVA 기술을 직접 개발하지 않은 관계로 더 많은 내용을 세밀하게 기술하지 못한 점 송구하게 생각한다. 위 액정 기술들을 우리나라 디스플레이 기술 20선에 선정해 주신 "한국 디스플레이 기술 20선 선정위원회"에 감사드립니다.

• Macromolecular Research
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• v.13 no.4
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• pp.314-320
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• 2005

Crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at various crosslinking temperatures using poly(acrylic acid-co-maleic acid) (PAM) containing different PAM contents. The thermal properties of these PVA/PAM membranes prepared at various reaction temperatures were characterized using differential scanning calorimetry (DSC). The proton conductivity and methanol permeability of PVA/PAM membranes were then investigated as PAM content was varied from 3 to 13 wt%. It was found that the proton and methanol transport were dependent on PAM content in their function both as crosslinking agent and as donor of hydrophilic -COOH groups. Both these properties decreased monotonously with increasing PAM concentration. The proton conductivities of these PVA/PAM membranes were in the range from $10^{-3}\;to\;10^{-2}S/cm$ and the methanol permeabilities from $10^{-7}\;to\;10^{-6}cm^{2}/sec$. In addition, the effect of operating temperature up to $80^{\circ}C$ on ion conductivity was examined for three selected membranes: 7, 9 and 11 wt% PAM membranes. Ion conductivity increased with increasing operating temperature and showed and S/cm at $80^{\circ}C$, respectively. The effects of crosslinking and ionomer group concentration were also examined in terms of water content, ion exchange capacity (IEC), and fixed ion concentration. In addition, the number of water molecules per ionomer site was calculated using both water contents and IEC values. With overall consideration for all the properties measured in this study, $7{\sim}9\;wt%$ PAM membrane prepared at $140^{\circ}C$ exhibited the best performance. These characteristics of PVA/PAM membranes are desirable in applications related to the direct methanol fuel cell (DMFC).

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.127-134
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• 2021

A hydrophobic emulsion consisting of PMHS and PVA was mixed into a cement mortar to observe changes in cement hydrate and microstructure, and to experimentally evaluate compressive strength and flexural strength. The hydrophobic emulsion was added with metakaolin and PVA fibers, and the stirring speed and sequence were adjusted to prepare a shell-concept hydrophobic emulsion. It was then mixed when mixing mortar to enhance filling of the internal pores and change of the hydrates. It was observed that the mortar mixed with a hydrophobic emulsion was filled with micropores and a coating film was formed on the surface of the hydrates by the emulsion. It was analyzed that the total pore area and porosity of the mortar mixed with the emulsion decreased from 30% to 60% compared to OPC, excluding the 50MK variable, which was extremely reduced and the median pore diameter decreased in some variables. It was also found that the compressive strength of the mortar mixed with emulsion 1% was increased up to 20%, but the strength of the mortar specimen mixed with 2% decreased to 50%.