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manufacture and Characterization of Glass Ceramics of P2O3-PbO-SiO2-Al2O3 System for Ic Substrate (P2O3-PbO-SiO2-Al2O3계 회로기판용 glass ceramics의 제조 및 특성평가)

  • 김용철
    • Journal of the Microelectronics and Packaging Society
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    • v.4 no.2
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    • pp.55-62
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    • 1997
  • P2O3-PbO-SiO2-Al2O3계 조성을 이용하여 저온에서 소결이 가증하며 열팽창계수와 유전율이 낮은 회로기판용 glass ceramics를 제조하고자 하였다. 155$0^{\circ}C$에서 2시간 동안 용 융하여 제조한 모유리의열팽창 거동을 확인하기 위하여 TMA로 열분석을 실시하였으며 이 유리를 분말화하여 80$0^{\circ}C$에서 열처리 하였다. 이때 cristobalite 형성억제제로 Ga2O3를 사용 하였으며 Ga2O3 첨가량에 따른 억제 영향을 XRD를 통행 확인하였다. Ga2O3를 첨가한 유리 분말로 pellet을 제조하여 열처리를 하였고 소결시편의 표면을 SEM을 통해 관찰하였다. 열 처리한 pellet에 silver paste를 screen printing하여 유전율을 측정하였으며 조성에 따른 유 전율의 변화를 확인하였다.

A Study of Al(III) Hydrolysis Species Characterization under Various Coagulation Condition (응집 pH와 응집제 종류에 따른 Al(III)가수분해종 특성변화에 대한 연구)

  • Song, Yu-Kyung;Jung, Chul-Woo;Sohn, In-Shik
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.958-967
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    • 2006
  • The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by Al(III) coagulants and to evaluate the distribution of hydrolyzed Al(III) species by coagulant dose and coagulation pH. When an Al(III) salt was added to water, monomers, polymers and solid precipitates may form. Different Al(III) coagulants (alum and PSOM) show to have different Al(III) species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved AI(III) (monomer and polymer) increases, but for PSOM, precipitates of $Al(OH)_{3(S)}$ increases rapidly. During the rapid mixing period, for high coagulant dose, Al-ferron reaction increases rapidly. The kinetic constants, Ka and Kb, derived from AI-ferron reaction. The kinetic constants followed very well the defined tendencies for coagulation condition. For pure water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. Also, for raw water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. At A/D(Adsorption and Destabilization) and sweep condition, both $Al(OH)_{3(S)}$ and dissolved Al(III) (monomer and polymer) exist, concurrent reactions by both mechanism appear to cause simultaneous precipitation.

The Correlation of Myopic Refractive Error and Ocular Components in Primary School Students (초등학생의 근시성 굴절이상과 안광학 성분들의 관련성)

  • Jeon, Soon-Woo;Lee, Hyun-Joo;Hwang, Hye-Kyung;Park, Chun-Man
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.3
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    • pp.299-303
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    • 2012
  • Purpose: In this study the correlation among the myopic refractive error and ocular components in primary school students was investigated. Methods: The subjects were 62 children who had no eye diseases. The refractive error, corneal radius, anterior chamber depth, lens thickness, axial length were measured and analysed. Results: Myopic refractive error in primary school students was negatively correlated with the axial length (1~3rd grade r=-0.653, p=0.000/4~6th grade r=-0.742, p=0.000), AL/CR ratio (1~3rd grade r=-0.571, p=0.000/4~6th grade r=-0.852, p=0.000). Conclusions: It was shown that the axial length and axial length(AL)/corneal radius(CR) ratio were very important data for myopic refractive error in primary school students.

The Dyeing Properties of Silk Fabrics of Glycyrrhizae Radix Extract (감초 추출물에 의한 견직물의 염색성)

  • 이영숙;장정대
    • Textile Coloration and Finishing
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    • v.16 no.1
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    • pp.34-39
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    • 2004
  • Dyeing properties of Glycyrrhizae Radix was investigated with silk fabrics. Dyeing water is a type of chalcone, it showed yellow in IR spectrum. K/S value showed high in following conditions; Glycyrrhizae Radix $200g/1\ell4 water, $80^{\circ}$ of dyeing temperature, 90 minute of dyeing time. Glycyrrhizae Radix dyeing water has higher K/S value in alkalinity(pH9) than in neutrality(pH7) or acidity(pH3) conditions. K/S value showed highest in pH5 premordant method of alkalinity dyeing water condition. The color of silk fabric dyed with Glycyrrhizae Radix is yellow. The change of color did not show by mordant treatment. K/S value showed higher in mordant treatment than nonmordant. Light fastness showed over 3 degree in nonmordant, premordant, simmordant(Al,Cu,Fe) and postmordant(Cu). Water fastness showed over 3 degree in dyeing water(pH3, pH5, pH7). Dry cleaning fastness showed over 3 degree in all dyeing methods. Washing fastness is showed in 2-3 degree; Al in nonmordant, premordant, simmordant and Cu in simmordant are 2-3 degree. Perspiration fastness is nearly 3-4 degree in premordant and simmordant. Perspiration fastness shows high in premordant, simmordant than postmordant. The fastness of light, water, dry cleaning, washing, perspiration shows better nonmordant, premordant, simmordant than postmordant method.

The Effect of Low Power Laser Irradiation on acute pain of Rats Induced by Wound (저강도 레이저가 흰쥐 창상 후 급성통증에 미치는 영향)

  • Kim Dong-Hyun;Baek Su-Jeong;Kim Suk-Bum;Song Ju-Min;Kim Jin-Sang
    • The Journal of Korean Physical Therapy
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    • v.14 no.2
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    • pp.234-249
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    • 2002
  • This study was performed, using c-fos and Substance P, to investigate the effect of GaAlAs laser on acute pain model induced by wound in lumbar region's spinal level. The test group was divided into control and experimental group. Control group is shamed group(c-fos and substance P expression after non-irradiation by a GaAlAs laser), The experimental group was divided into two subgroups: one is experimental group I (c-fos expression after irradiation by a GaAlAs laser), and the other is experimental group II (substance P expression after irradiation by a GaAlAs laser). The results of this study were as following: 1. The numbers of c-fos immunoreactive neuron in spinal cord was increased markedly 1 day after wound, and decreased gradually from 1 day to 2 days in wound with GaAlAs laser irradiation. 2. The changes of the average percentages of substance P immunoreactive neurons in spinal cord was increased markedly 1 day after wound, and decreased gradually from 1 day to 2 days in wound with GaAlAs laser irradiation. Therefore, decreasing the changes of c-fos and substance P expression after irradiation by a GaAlAs laser indicates and GaAlAs laser have effect on pain control.

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Influence of Different A Elements on Bonding and Elastic Properties of Zr2AC (A = Al, Si, P, S): A Theoretical Investigation

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.609-614
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    • 2013
  • Extended H$\ddot{u}$ckel tight-binding band structure calculations are used to address the chemical bonding and elastic properties of $Zr_2AC$ (A=Al, Si, P, and S). Elastic properties are interpreted by analyzing the density of states and the crystal orbital overlap population for the respective phases. Our results show that the bulk modulus of these ternary compounds is determined by the strength of Zr-A bonds.

The Syntheses of p-Acylcalix[4]arenes

  • No Kwanghyun;Kim Younhee
    • Bulletin of the Korean Chemical Society
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    • v.9 no.1
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    • pp.52-55
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    • 1988
  • Starting with readily available p-tert-butylcalix[4]arene 3 tert-butyl groups are removed by $AlCl_3$-catalyzed de-alkylation reaction, and the calix[4]arene 4 formed is converted into the tetraacyl esters. These compounds undergo Fries rearrangement to yield p-acylcalix[4]arenes. p-Acetyl, p-propionyl, p-butyryl, and p-benzoylcalix[4]arene 10, 11, 12 and 14 are synthesized in 70-80% yields by treatment of the corresponding esters 5, 6, 7 and 9 with $AlCl_3$ in nitrobenzene. When the tetraisobutyryl ester 8 was treated with the same condition, only two isobutyryl groups were rearranged to the para-positions of calix[4]arene, and remaining two groups were simply cleaved.

An Alternative X-ray Diffraction Analysis for Comprehensive Determination of Structural Properties in Compositionally Graded Strained AlGaN Epilayers

  • Das, Palash;Jana, Sanjay Kumar;Halder, Nripendra N.;Mallik, S.;Mahato, S.S.;Panda, A.K.;Chow, Peter P.;Biswas, Dhrubes
    • Electronic Materials Letters
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    • v.14 no.6
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    • pp.784-792
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    • 2018
  • In this letter, a standard deviation based optimization technique has been applied on High Resolution X-ray Diffraction symmetric and asymmetric scan results to accurately determine the Aluminum molar fraction and lattice relaxation of Molecular Beam Epitaxy grown compositionally graded Aluminum Gallium Nitride (AlGaN)/Aluminum Nitride/Gallium Nitride (GaN) heterostructures. Mathews-Blakeslee critical thickness model has been applied in an alternative way to determine the partially relaxed AlGaN epilayer thicknesses. The coupling coefficient determination has been presented in a different perspective involving sample tilt method by off set between the asymmetric planes of GaN and AlGaN. Sample tilt is further increased to determine mosaic tilt ranging between $0.01^{\circ}$ and $0.1^{\circ}$.

Molecular Cloning and Expression of Alkaline Amylase Gene of Alkalophilic Bacillus sp. in Bacillus subtilis and Escherichia coli (알카리성 Bacillus sp.의 호알카리성 amylase 유전자의 Bacillus subtilis와 Escherichia coli로의 cloning과 발현)

  • Bae, Moo;Park, Shin-Hae
    • Microbiology and Biotechnology Letters
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    • v.17 no.2
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    • pp.160-164
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    • 1989
  • A 5.7Kb EcoRI fragment containing alkaline amylase gene of Bacillus sp. AL-8 obtained in the previons experiment (10) was transformed in B. subtilis via plasmid pUB110. The enzymatic proper-ties of the amylase produced by the transformants were Identical to those of the donor strain. Thus, the alkaline amylase activity from the transformant was maximum at pH 10 and 5$0^{\circ}C$. And the enzyme was very stable over the ranges of alkaline pH. In order to determine the location of the alkaline amylase gene within the 5.7Kb DNA fragment, the fragment was subcloned in E. coli. It was found that the alkaline amylase gene was located k EcoRI fragment of 3.7Kb.

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A Study on the Influence of Al Alloy Sacrificial Anode Efficiency due to Marine Environmental Variation (해양환경 변화가 알루미늄합금 희생양극의 효율에 미치는 영향에 관한 연구)

  • 김도형
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.106-111
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    • 2000
  • Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

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