• Title/Summary/Keyword: rust

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Development of chemical conversion coating technology by environment friendly method for Zn electroplated steel (아연 전기 도금 강의 환경친화적인 화성처리 기술 개발)

  • Kim, Seong-Jong;Kim, Jeong-Il;Jang, Seok-Ki
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.271-272
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    • 2006
  • Zinc confers high corrosion resistance by acting as a sacrificial anode, and a zinc coating improves the appearance of steel. Chromate conversion coating (CCC) films are still one of the most efficient surface treatments for steel. Although such films can self-repair via the dissolution of Cr(VI), dissolved Cr(VI) have adverse effects on humans, and the environment. Therefore, we examined the corrosion protection property and morphology of colloidal silica conversion films as an alternative to CCC films. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques, including electrochemical impedance spectroscopy, open circuit potential, and the salt spray test(SST). Corrosion was implied by the appearance of red rust on the specimen surface. In corrosion resistance at 3% NaCl solution, red rust appeared at 15-20, 55-70, and 83-98 days on Zn-electroplated steel, colloidal silica conversion-coated specimens, and CCC-coated specimens, respectively. In the salt spray test, the colloidal silica film provided better corrosion protection than CCC films, i.e., red rust appeared at 96 hours on the Zn-electroplated steel sheet, at 432 hours with the CCC films, and at 888 hours with silica conversion coating.

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Rust of Lysimachia clethroides Caused by Puccinia dieteliana (Puccinia dieteliana에 의한 큰까치수영녹병)

  • Kim, Seong-Hwan;Lee, Tae-Soo
    • The Korean Journal of Mycology
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    • v.36 no.2
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    • pp.196-198
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    • 2008
  • A rust disease occurred on Lysimachia clethroides in Deogyusan National Park, Jeollabukdo. The typical symptoms of the disease appeared as small, yellowish spots on leaves at first. The spots then turned yellowish brown and powdery mass of blackish brown spores appeared on the lesions. Severely infected leaves blighted and eventually shriveled. Teliospores were yellowish brown in color, clavate or fusiform in shape and $38{\sim}62\;{\times}\;14{\sim}22\;{\mu}m$ in size, the apex rounded or obtuse, the base attenuated. Pedicels hyaline, persistence, up to $75{\mu}m$ long. The causal fungus was identified as Puccinia dieteliana based on mycological characteristics and host specificity.

Sorption of I and Se onto Green Rusts with Different Interlayer Anions, GR(CO32-) AND GR(Cl-)

  • Min, J.H.;Baik, M.H.;Lee, J.K.;Jeong, J.T.
    • Journal of Nuclear Fuel Cycle and Waste Technology
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    • v.1 no.1
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    • pp.57-63
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    • 2013
  • Natural green rust (GR) can retard the migration of anions through geological media because it has a Layer Double Hydroxyl (LDH) structure with a positive charge. In this study, the sorption behaviors of anions such as selenite ($Se(IV)O{_3}^{2-}$), selenate ($Se(VI)O{_4}^{2-}$), and iodide ($I^-$) onto green rusts with different structures, i.e., GR($Cl^-$) and GR($CO{_3}^{2-}$), were investigated by conducting batch sorption experiments in an anoxic condition. Experimental results showed that selenite was mostly sorbed onto GR($CO{_3}^{2-}$) and then partly reduced to metal selenium, Se(0). However, little selenate and iodide was sorbed onto GR($CO{_3}^{2-}$) while some iodide was sorbed onto GR($Cl^-$). It is presumed from the experimental results that the major sorption mechanism of $SeO{_3}^{2-}$ and $I^-$ onto green rusts is the anion exchange reaction with the anions existing in the interlayer of the rusts. Green rust, therefore, can play an important role in the retardation of anions migrating through deep geological environments owing to its LDH structure with a high anion exchange capacity.

Development of Corrosion Removing Unit for Small Screw Propeller (소형 스크류 프로펠라의 부식제거장치 개발)

  • KIM GUI-SHIK;HAN SE-WOONG;HYUN CHANG-HAE
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.260-265
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    • 2004
  • The materials of ship screw propeller are commonly the manganese bronze. The seawater corrosion and cavitation of the screw propeller reduce tire propulsive performance of ship. In screw manufactory, tire corrosion rust of tire screw propeller is removed by a hand grinding. The grinding work makes the dust of the heavy metals from the manganese bronze. The dust makes indoor working environment poor. A friendly-environmental and automatic corrosion removing apparatus was developed for the improvement of screw processing and working environment. The corrosion rust of a screw propeller was remarkably removed by using apparatus. And the screw surface roughness was improved by a blasting effect of the apparatus performance test. Anode polarization curves on jour processing conditions, that is to say, grinding, blasting, wire-brushing, fine sand papering, were confirmed by a potentiostat. Especially, two kinds of medias, alumina and emery, were used in the blasting processing. Then, investigated tire cavitation erosion of specimen. This result proved that tire blasting work has considerably improved the corrosion resistance of a screw propeller.

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Relation between total degradation of steel concrete bond and degree of corrosion of RC beams experimental and computational studies

  • Maurel, Olivier;Dekoster, Mickael;Buyle-Bodin, Francois
    • Computers and Concrete
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    • v.2 no.1
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    • pp.1-18
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    • 2005
  • This paper presents a study on the effects of localized steel-concrete bond degradation on the flexural behaviour of RC beams. A finite element analysis is undertaken to complete the experimental analysis. The first part deals with an experimental study on beams where bond was removed by using plastic tube at different locations and for various lengths. The flexural behaviour was studied at global scale (load-deflection) and local scale (moment-curvature). The second part, a numerical study using a simplified special finite element (rust element) modelling the rust layer occurring between reinforcement and concrete with corrosion was conducted in order to find the relation between the degree of corrosion and the degradation of the steel-concrete bond. The computed value of the corrosion degree corresponding to the total degradation of bond has been used in a second time to model the tests, in order to evaluate the influence of the loss of bond, the steel cross section reduction, and the combination of both. The results enable to evaluate the influence of the different corrosion effects on the flexural behaviour, according to the length and the location of the corroded zone.

A Study on the Properties of the Heavy Duty Rust-Converting Agent used in the Potential Hazard Areas of Fire & Explosion (잠재적 화재.폭발 위험 지역 작업용 녹전환형 중방식 코팅제의 특성에 관한 연구)

  • 강영구
    • Journal of the Korean Society of Safety
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    • v.13 no.3
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    • pp.102-111
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    • 1998
  • This study was concerned with the development of a heavy duty rust-converting agent, the function of which is to form metal complex coatings, containing vinyl halide-acrylic terpolymer emulsion, defoamer, emulsifying agent, glass flakes, chelating agent such as gallotannic acid, gallic acid, and pyrogallic acid, and other additives. The resulted emulsion products(Sample No.1~No.5) were characterized through test either in the forms of emulsions, which include Viscosity, Penetration rate, Acidity and Film drying rate test, or in the forms of coated layer on rusty steel substrates by FT-IR, which include hardness, gloss, salt spray, adhesion and flame retardant test. The test results are as follows ; Penetration rate(0.1~0.4 mm/min), Solid content(70%), Acidity (pH 1.8~2.0), Specific gravity(1.30~1.35), Film drying rate(108min, RH 40% ; 150min, RH 80%), Gloss(83~92, incident angle $60^{\circ}$; 88~97, incident angle $85^{\circ}$), Pencil hardness(4H~5H), Adhesion (100/100), Salt spray test(>720Hr), LOI(%) value(38%), Vertical burning test(UL 94-v-l). According to the various performance of specimens show above, the evaluation of the availability of this heavy duty rust-converting agent can be concluded that all the samples(No.1~No.5) are capable of being used in the field of chemical plant and in the hazard areas of fire and explosion potential. It was observed that the properties of sample No.2, especially gloss and hardness, were much better than that of the other samples.

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A New Spray Chrysanthemum, "Pure Angel" with Resistant to White Rust, Single Flower Type and Pure White Petals for Cut Flower

  • Lim, Jin-Hee;Shin, Hak-Ki;Park, Sang Kun;Cho, Hae-Ryong;Rhee, Hye-Kyung;Kim, Mi-Seon;Joung, Hyang Young
    • Korean Journal of Breeding Science
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    • v.41 no.2
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    • pp.173-176
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    • 2009
  • A new spray chrysanthemum cultivar 'Pure Angel' was released by National Institute of Horticultural and Herbal Science (NIHHS), Rural Development Administration (RDA), Korea in 2007. The cross was made in 2004 between 'Innocence', a breeding cultivar of NIHHS, and 'Baeksokuk', a spray cultivar with white petals. Trials were conducted from 2005 to 2007 for the evaluation and selection of this cultivar, including shade cultures in summer and retarding cultures in autumn. The natural flowering time of 'Pure Angel' is late October, but year-round flowering is possible by photo-periodic control. The cultivar has single type flowers with pure white petals and a green flower center. It shows long vase life and resistance to white rust. The diameter of flower is 52.5 mm. The numbers of flowers per stem and petals per flower are 12 and 22.5, respectively. Days to flowering under the short day treatment is about 52 days in spring seasons.

A New Spray Chrysanthemum Cultivar, "Cherry Blossom" with Resistant to White Rust, Single Flower Type and Bright Pink Petals for Cut Flower

  • Lim, Jin-Hee;Shin, Hak-Ki;Park, Sang Kun;Cho, Hae-Ryong;Rhee, Hye-Kyung;Kim, Mi-Seon;Joung, Hyang Young
    • Korean Journal of Breeding Science
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    • v.40 no.4
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    • pp.439-442
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    • 2008
  • A new spray chrysanthemum cultivar, 'Cherry Blossom' was released by National Horticultural Research Institute (NHRI), Rural Development Administration (RDA), Korea in 2007. A cross was made in 2002 between 'Relance', a spray cultivar with red petals and resistant to white rust and 'Yeonja', a spray cultivar with pink petals. Trials were conducted from 2005 to 2007 for the evaluation and selection of this cultivar, including shading culture in summer and retarding culture in autumn. The natural flowering time of "Cherry Blossom" is late October, but year-round flowering is possible by shading and lighting treatment. This cultivar is single type flowers with dark pink petals and green flower center and resistant to white rust. It is very stable color of petals when the variety is cultivated under high temperature conditions in summer season. The diameter of flower is 55.0 mm. The number of flowers per stem is 10.5 and the number of petals per flower is 24.0. The days to flowering under the short day treatment is about 45 in spring season.

A New Spray Chrysanthemum, "Pink Berry" with Resistance to White Rust, and Long Vase Life, Single Flower Type and Pink Petals for Cut Flower

  • Lim, Jin-Hee;Shin, Hak-Ki;Park, Sang Kun;Cho, Hae-Ryong;Rhee, Hye-Kyung;Kim, Mi-Seon;Joung, Hyang-Young
    • Korean Journal of Breeding Science
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    • v.41 no.2
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    • pp.141-144
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    • 2009
  • A new spray chrysanthemum 'Pink Berry' was released by National Institute of Horticultural and Herbal Science (NIHHS), Rural Development Administration (RDA), Korea in 2007. A cross was made in 2004 between 'Lineker Salmon', a spray cultivar with salmon petals, and 'Baeksokuk', a spray cultivar with white petals. Trials were conducted from 2005 to 2007 for evaluation and selection of this cultivar, including shade cultivation in summer and retarding cultivation in autumn. The natural flowering time of 'Pink Berry' is late October, but year-round flowering is possible by photo-periodic control. The cultivar has single type flowers with pink petals and a green flower center. It shows long vase life of 22 days and resistance to white rust. The diameter of flower is 52.0 mm. The numbers of flowers per stem and petals per flower are 15.5 and 29.5, respectively. Days to flowering under the short day treatment is about 56 in autumn seasons.

Surface Appearance of Galvanized Steel with Outdoor Exposure Testing in Korea for 36 Months (36개월간 국내 옥외폭로시험에 따른 아연도강의 표면외관 변화)

  • Kim, K.T.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.17 no.6
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    • pp.301-309
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    • 2018
  • If galvanized steel is exposed to an outdoor environment, atmospheric corrosion will occur with time and red rust will form when the sacrificial protection capacity of zinc reaches its limit. With corrosion, the surface appearance of steel changes, and the properties of the exterior materials degrade. In this study, two kinds of galvanized steel, (GA and GI specimens) were subjected to an outdoor exposure test for 36 months in six regions of Korea. Chrominance (color, chroma, and brightness) and glossiness surface analyses were performed. The color change was not significant, regardless of the exposed area or the specimens tested. With increasing exposure times, the GA specimen became blackened by the formation of zinc oxide, and red coloration was increased by the formation of red rust. As the exposure time of GI specimen increased, the surface proceeded to blacken, but no red rust was formed and the color did not change significantly. Regardless of the outdoor exposure area or the specimen, longer exposure times led to lower glossiness, and this behavior appears to be influenced by the formation of zinc oxide.