• Title/Summary/Keyword: rubbing strength

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Surface characterization of polyimides for LCDs by second-harmonic generation technique (SHG을 이용한 LCD 배향막 표면 특성분석)

  • 정태혁;윤태훈;김재창
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.3
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    • pp.114-122
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    • 1997
  • The surface characteristics of polymers for liquid crystal alignment are studied by optical second-harmonic genertion (SHG) tecnique. Using SHG technique, the LC monolayers on rubbed polymer have already been studied. But, in this paper, the SH signals of polymer were observed and the orientational distribution of oriented polymer was studied. Te SHG experiments for side-chain type and main-chain type polymers are carried out as a function of rubbing strength. The orentational distribution of surface molecules of polymers is compared with the LC pretilt angle measured by the crystal rotation method.

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Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Fluorescence Dyes (초소수성 형광염료에 의한 고강도/고분자량폴리에틸렌섬유의 염색)

  • Kim, Taekyeong;Park, Jihoon;Lee, Junheon;Kim, Taegun
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.223-230
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    • 2017
  • Three super hydrophobic fluorescence dyes were selected to dye high molecular weight polyethylene fiber and their molar absorptivity, emission spectrum, and quantum yield were measured. From the results of color strength on the fiber, all the three dyes exhibited linear increase according to the dye concentration and Fluoro3 dye showed the highest color strength among them. Emission strength of the fluorescence dyes on the fiber was investigated according to the dye concentrations. The emission was increased with the increase of the dye concentration at relatively low dye concentration and then after showing the maximum emission strength the emission was decreased at higher dye concentrations. The highest emission was obtained in Fluoro2 dye. Color fastness to washing and rubbing was generally good enough, however, especially to light, only Fluoro3 dye exhibited rating 3 acceptable practically and Fluoro1 and 2 was ratings 1 which is unacceptable level.

Anchoring and Alignment Behavior of Liquid Crystals on Poly(vinyl cinnamate) Thin Films Treated in Various Ways

  • Lee, Taek-Joon;Hahm, Suk-Gyu;Lee, Seung-Woo;Ree, Moon-Hor
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.240-240
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    • 2006
  • Thin films of poly(vinyl cinnamate) (PVCi) were prepared on indium tin oxide (ITO) glass and silicon substrates by conventional spin coating and subsequent drying process. The thicknesses of the films ranged 50-120 nm. The films' surface was treated by rubbing, ultraviolet exposure or their combinations in various ways with changing rubbing strength and exposure dose. These films were examined in detail in the aspects of surface morphology and chain orientation. Further, the anchoring and orientation behaviors of liquid crystals on the film surfaces were investigated. All the results will be discussed in detail.

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Effect of Chemical Structures and Added Amounts of Humectants in Pigment Ink on Touch of Dyed Fabrics (안료 잉크 내 휴멕턴트의 화학구조와 첨가량이 염색 직물의 태에 미치는 영향)

  • Kim, Hyungjin;Park, Seongmin;Kwon, Woong;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.34 no.1
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    • pp.10-19
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    • 2022
  • Humectants are chemical compounds which added to water based pigment inks for DTP (Digital Textile Printing) to prevent evaporation of water. The humectants usually have diol or triol type chemical structures and their -OH groups have possibility to react with functional groups of the binder polymers, such as ester, carboxylic acid, and urethane groups, acting as a crosslinking agent. The crosslinking reactions between polymer binders and humectants in inks can affect touch of the printed fabrics. In this regard, this study aims to investigate effect of chemical structures and added amounts of humectants in pigment ink on touch of dyed fabrics by using 1,6-hexanediol, ethylene glycol, diethylene glycol, and 1,4-buthanediol with various amounts added to the mixture of a black pigment and a polyurethane type binder. Then, color, rubbing strength, touch of the fabrics dyed with the prepared pigment inks were evaluated.

Natural Indigo Dyeing by Using Glucose Reduction (포도당 환원을 이용한 천연 인디고 염색)

  • Shin, Youn-Sook;Cho, A-Rang;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.21 no.3
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    • pp.10-18
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    • 2009
  • Dyeing process of the natural indigo powder onto ramie and silk fabrics was investigated by using glucose and calcium hydroxide as a reducing system. Effect of reduction and dyeing conditions such as temperature and time of reduction/dyeing, and concentrations of glucose and calcium hydroxide on the dyeing process were explored. Indigo powder was obtained by drying the conventional niram paste in an oven at $50^{\circ}C$. Color strength of the dyed fabrics was evaluated by K/S value measured at the wavelength of maximum absorption(${\lamda}$max). Munsell color coordinates(H V/C) were used to compare fabric colors of ramie and silk. Ramie fabric showed purple-blue color for all the temperature and time. On the contrary, silk fabric showed wide range of color including brown, brown-green, green at the different temperature. With the increase of K/S value, the coordinate of value(lightness) decreased for both of ramie and silk fabrics. The coordinate of hue(shade) changed drastically with the increase of K/S value for silk fabric, compared with that of ramie fabric which showed nearly constant value at the whole range of K/S value. Optimum concentrations of calcium hydroxide were for 6 g/L for ramie and 4 g/L for silk at $60^{\circ}C$ and 50 min. K/S value increased with the indigo concentration. Maximum K/S value was shown at $10{\sim}12$ g/L of glucose concentration. For both of ramie and silk fabrics, the colorfastness of washing and light was lower than that of rubbing. All the colorfastness values were improved with the increase of color strength.

Chemical Modifications of Regenerated Cellulose Fiber (셀룰로오스 재생 인조섬유의 화학개질에 관한 연구)

  • 이문철;이명선
    • Textile Coloration and Finishing
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    • v.11 no.1
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    • pp.48-60
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    • 1999
  • In this paper, a new regenerated celluosic fiber, "Tencel" was treated with cellulase enzyme. Also Tencel fabrics were pretreated with NaOH and dyed with various reactive dyes, and subsequently finished with DMDHEU. $\Delta{E}^*_{ab}$ value was calculated by measuring color difference before and after wet abrasion test to rubbing. The fibrillation propensity was estimated on Tencel by means of weight loss, $\Delta{E}^*_{ab}$ value, and SEM observation. Weight loss of NaOH pretreated Tencel fabric is more lower than that of original fabric. The cellulase treatment decreased tensile strength but improved wet abrasion strength, wrinkle recovery, and bending properties. Tendency of fibrillation for Tencel fabric was reduced by NaOH-pretreatment, dyeing with multifunctional reactive dyes, and afterfinishing by DMDHEU.by DMDHEU.

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Modification of Dyeing Property of Wool Fabrics by UV Irradiation (UV조사에 의한 양모직물의 염색성 개질)

  • 전영실;남성우;김인회
    • Textile Coloration and Finishing
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    • v.16 no.1
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    • pp.10-17
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    • 2004
  • Wool fabrics were treated with deep UV for 10 to 30min and then dyed with C.I. Acid Yellow 99, C.I, Acid Red 57 and C.I. Acid Blue 62. FT-IR and XPS have been used to prove the chemical composition of wool fiber surfaces. The mechanical property and colorfastness were also studied. The intencities of the peaks of C=O group at $1700^cm^{-1}$ were increased with increasing irradiation time. Relative $O_{1s},\; N_{1s}\; and\; S_{2p}$ intensities increased considerably and oxygen was incorporated in the form of CO and COO on the fiber surface. The dye uptakes of wool fabrics dyed with three acid dyes were proportional to irradiation times and in inversely proportional to irradiation distances. It was found that the tensile strength of wool fabrics were gradually deteriorated with the UV irradiation times. The colorfastness, such as washing, light and rubbing, of UV irradiated wool fabrics dyed with acid dyes were good.

Effect of Particle Sizes of Polymer Binders for Pigment Inks on Touch of Fabrics (안료 잉크용 바인더의 입자 크기가 직물의 태에 미치는 영향)

  • Park, Seongmin;Han, Minwoo;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.32 no.4
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    • pp.226-231
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    • 2020
  • This study investigated effect of particle sizes of polymer binders for digital textile printing(DTP) pigment inks on touch of fabrics. The polymer binders were synthesized via miniemulsion polymerization of methyl methacrylate(MMA), butyl acrylate(BA), N-ethylolacrylamide(NEA) and methacrylic acid(MAA). The prepared binders were applied to black pigment inks and those black pigment inks were used to dye cotton fabrics. Then, color strength, rubbing fastness, stiffness, surface and bending properties of the dyed fabrics were investigated. Depending on the particle size of the polymer binder used, color strength, friction fastness, stiffness, surface and bending properties change. Generally, the larger the particle size of the polymer binder, the softer properties.

Dyeability and Functionality of Silk Fabrics Dyed with Buckwheat Extracts (메밀 추출물에 의한 견직물의 염색성 및 기능성)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.22 no.4
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    • pp.106-117
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    • 2018
  • The present study was conducted to investigate dyeing properties and functionality of silk fabrics dyed with extracts from buckwheat skin. Comparative results of color strength(K/S) values of dyed silk fabrics were studied to quantify the effects of dye concentrations, dyeing temperatures, dyeing time and the pH; the effect of mordants; and color changes. And also evaluated the fastness, antimicrobial property, ultraviolet protection properties of the dyed and mordanted silk fabrics. The color strength(K/S) values of silk generally increased depending on the increasing dye concentration, dyeing temperature, and dyeing time. And the highest color strength values were obtained at a dye concentration of 100%(v/v), a dyeing temperature of $90^{\circ}C$, a dyeing of time 80 minutes, and a dyebath of pH 2. The color fastness to light of dyed and mordanted silk fabrics were found to be good, and the drycleaning and rubbing fastness were excellent. The fade of washing fastness was not good, however, the stain of washing fastness and perspiration fastness showed relatively good grade. The Al, Cu, Fe mordanted silk fabrics(except Fe for Klebsiella pneumoniae) showed 99.9% reduction rate. The ultraviolet protection properties of the mordanted fabrics were generally improved. Moreover, the Cu and Fe mordnared fabrics showed very exceptional ultraviolet protection factors.

The Bond Characteristics of Ultra Rapid Hardening Mortar for Repair using Magnesia-Phosphate Cement (마그네시아 인산염 시멘트를 이용한 초속경 보수 모르타르의 접착특성)

  • Lee, Sun-Ho;Kwon, Hee-Sung;Paik, Min-Su;Ahn, Moo-Young;Lee, Young-Do;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.609-612
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    • 2008
  • Ultra Super Early Strength Cement is a material that satisfies these requirements. early hydration heat however, is significant over regular concrete, thus discretion is advised for thermal cracks in accordance with heat generation when constructing a large-scale structures. In addition, the negative point that it is difficult to achieve required strength in a short period of time following rubbing process while retaining workability, the cement is being used conditionally for engineering material and Ultra Super Early Strength Cement for maintenance material for construction doesn't exist. Magnesia Phosphate Cement, which is currently under studies in overseas uses no extra admixture and has strong points of Ultra Super Early Strength as well as favorable construction-ability and adhesive stability to the prototype concrete. These factors stem recognition that it could be used as maintenance material for construction of diverse applicability. In order to provide necessary data to increase practicality of the magnesia phosphate cement for Ultra Super Early Strength Mortar, the study carried out simulate experiment on member of framework to review field applicability.

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