• 대한기계학회논문집A
• /
• 제38권5호
• /
• pp.505-511
• /
• 2014

내연기관의 냉각기 고무호스에 사용되는 EPDM 고무는 열과 기계적 하중을 받는 동시에 국부적으로 형성된 전기적 스트레스를 받아 복합적인 노화가 발생한다. 본 연구에서는 EPDM 고무의 전기화학적 복합노화 시험을 하고, 아레니우스 관계식을 이용하여 노화온도($60^{\circ}C$, $80^{\circ}C$, $100^{\circ}C$)에 따른 가속수명 예측식을 구하였다. 수명에 영향을 미치는 인장변형률(5%, 10%)을 반영하여 예측식의 기울기($E_a/R$) 및 아레니우스 상수(C)를 고려한 수정된 수명예측 식을 제안하였다. 이를 통해 노화온도와 인장변형률에 영향을 받은 EPDM 고무의 수명을 예측하였고, 수정된 수명예측 시간이 실제 실험결과의 편차 범위 이내에서 일치함을 확인하였다.

• Elastomers and Composites
• /
• 제34권1호
• /
• pp.11-19
• /
• 1999

카본블랙 첨가량, 촉진제에 대한 황 함량비에 따른 가황고무의 점탄성 특성을 반발탄성, 저장 및 손실 모듈러스, tan ${\delta}$를 통하여 고찰하였다. 반발탄성은 촉진제에 대한 황 함량비가 낮을수록, 배합고무중 카본-블랙의 체적분율이 낮을수록 높게 나타났다. 저장 모듈러스는 카본블랙 첨가량과 변형이 증가할수록 감소하였으나, 가황시스템과는 무관하게 나타났다. 특히 카본블랙 첨가량이 낮은 수준 ($40{\sim}50phr$)에서는 변형이 3% 이상에서, 첨가량이 높은 수준(60phr 이상)에서는 변형이 6% 이상에서 일정한 저장 모듈러스를 보이고 있어 입자간에 형성되는 망상구조는 6% 이상의 변형에서 파괴됨을 알 수 있다. 손실 모듈러스는 카본블랙 첨가량이 낮은 수준에서는 별다른 영향이 없으나, 높은 수준에서는 1% 변형에서 최대값을 보인 후 완만히 감소하였다. Tan ${\delta}$는 가황시스템에 대한 의존성은 약하나 카본블랙 첨가량 및 변형이 증가함에 따라 증가하였으나, 카본블랙 첨가량에 관계없이 2% 변형에서 최대값을 나타내었다.

• 접착 및 계면
• /
• 제2권4호
• /
• pp.32-38
• /
• 2001

본 실험에서는 공가류와 내오존성을 동시에 만족하는 고무 조성비의 영향에 대하여 검토하였다. 사용한 시편은 NR, SBR, BR, IIR 및 EPDM을 다양한 비율로 블렌딩 한 고무 조성물(시편 A), NR/BR/SBR로 구성된 불포화 고무 조성물(시편B)와 NR/IIR/EPDM로 구성된 포화 고무 조성물(시편C)이다. 시편A와 시편B, 시편A와 시편C를 각각 공가류시켜 PAD 접착 시편을 제작하여 박리강도를 측정하였다. 또한 시편A에 대해서 내오존성을 평가하였다. 시편 A의 불포화 고무 조성중(NR/BR Blend)에 BR보다 NR의 비율이 높을수록 시편B와 시편C와의 접착 강도가 높았고, 또다른 불포화 고무 조성(NR/SBR)에서는 NR보다 SBR 함량이 높을수록 접착 강도는 높았다. 또한 시편A의 조성중에서 NR/BR/IIR/EPDM 조성물 보다 NR/SBR/IIR/EPDM 조성물이 접착성이 우수하였다. 고무 조성중 불포화 고무가 많을수록 접착 강도는 우수하였으나, 내오존성은 다소 열세였다. 불포화 고무와 포화 고무의 비율이 60/40 정도 일 때 접착 강도와 내오존성이 모두 양호하였다.

• Elastomers and Composites
• /
• 제32권5호
• /
• pp.302-308
• /
• 1997

Over 1953/54 Karl Ziegler and Giulio Natta independently discovered new types of catalyst. Thus it was able to produce synthetic cis-polyisoprene rubber which has same properties like natural rubber, since then the amount of consumption was increased rapidly. The problem of disposing of used rubbers has become acute in recent years. cis-Polyisoprene was degraded in supercritical tetrahydrofuran and degree of degradation and product were observed by GPC, FT-IR, GC-MS analyses. As a result, degradation of cis-polyisoprene had small dependency upon the operating pressure, and was inhibited in concentration increase. And cis-polyisoprene was degraded into narrow molecular weight distribution oligomer in 3 hours, and more than 10 organic compounds were produced.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
• /
• pp.196-201
• /
• 2006

Silica(SiO2) nanoparticles are used as additives in plastics and rubbers to improve mechanical, electrical, magnetic properties and optical material. Silica nanoparticles were synthesized by the gas phase thermal oxidation of several kinds of precursors in many types of reactor. Diffusion flame reactor has some advantages compared with other types of reactors. In this study, we investigated the generation of silica nanoparticles on the effect of residence time by tetraethylothosilicate(TEOS) in a turbulent diffusion flame reactor controlled by providing reactant flowrate and reactor geometry affect particle morphology, particle size and particle size distribution. To determine the flame residence time, flame length should be determined which was examined by ICCD image. Particle size, distribution and morphology were performed with TEM.

• 동력기계공학회지
• /
• 제5권3호
• /
• pp.48-55
• /
• 2001

In many applications. rubber components undergo dynamic stresses or deformations of fairly large magnitude. Since rubbers are not fully elastic, a part of the mechanical energy is converted into heat due to the hysteresis loss. Heat generation without adequate heat dissipation leads to heat build up. i. e. internal temperature rise. The purpose of this paper is to predict temperature rise caused by the hysteresis loss, in a rubber pad subjected to complex dynamic deformation. In this unsteady thermal analysis, the temperature distributions of track components are displayed in contour shapes and the temperature variations of some important nodes are represented graphically with respect to the running time of the tank.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
• /
• pp.19-22
• /
• 2001

This paper proposes a double cantilever sandwich-beam method for evaluating the frequency dependence of material dynamic characteristics. The flexural vibration of a double cantilever sandwich-beam specimen with a partially inserted rubber layer was studied using a finite element simulation in combination with the sine-sweep test. Quadratic relationships of dynamic elastic modulus and material loss factor of rubbers with frequency were quantitatively suggested employing the least square error method.

• Macromolecular Research
• /
• 제9권1호
• /
• pp.37-44
• /
• 2001

A premixing effect for the properties of carbon black-filled rubber compounds was investigated using biblends of natural rubber (NR), styrene-butadiene rubber (SBR), and butadiene rubber (BR). Degree of mixing of the biblends was controlled by preblending time of 0.0, 2.5, and 5.0 min. Mooney viscosities of the compounds decreased by increasing the preblending time. Of three carbon black-filled compounds of NR/SBR, NR/BR, and SBR/BR compounds, only the SBR/BR blends showed a specific cure characteristics depending on the preblending time. For the bound rubber composition, the NR content was higher than SBR and BR. The difference in the rubber composition ratio of the bound rubber became smaller with increasing the preblending time. Physical properties of the vulcanizates such as hardness, modulus, tensile property, abrasion loss, and tans were also compared. Differences in properties of the compounds were discussed with miscibility of the dissimilar rubbers and degree of mixing.

• 대한전기학회논문지:전기기기및에너지변환시스템부문B
• /
• 제53권5호
• /
• pp.338-343
• /
• 2004

In general, the insulation and protective sheaths on electrical conductors are made of combustible substances like PVC, natural or synthetic rubbers, and other organic or synthetic materials. When an electrical fire starts due to overheating of conductors/joints or sparking/arcing, the first thing to ignite is usually the insulation on the cables. When the insulation bums, the produced fumes are very toxic. To solve the problem, we have surely need the fire resistance cable that doesn't bum in a high temperature and emit toxic fume for operating a disaster prevention installation. In this paper, we have simulated the thermal analysis for the fire resistance cable according to the values of current in a overload and a short, and the values of outside flame with the fire resistance cable of the L's company product(600 V, FR-8 : Four Core) using the finite element method(Flux2D).

• 대한기계학회논문집B
• /
• 제33권4호
• /
• pp.272-277
• /
• 2009

The liquid phase LPG injection (LPLi) system (the 3rd generation technology) has been considered as one of the most promising fuel supply systems for LPG vehicles. To investigate the reaction characteristics of LPG with rubber parts in LPLi system, various rubbers were tested. The results showed that the amount of residue from the cover rubber of a fuel pump was increased about 10 times after testing. Furthermore, the amount of sulfur and nitrogen species which are considered as main sources of deposit formation in LPLi fuel injectors were also found to be higher than those in original LPG fuel. In addition, these residues made the core parts of LPLi injector such as needle and nozzle, partially worn, which eventually causes leakage in LPLi injectors.