• Elastomers and Composites
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• v.55 no.4
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• pp.289-299
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• 2020

Highly aromatic (HA) oils are common processing aids used in tire tread compounds. However, they often bleed and evaporate from the vulcanizates during tire use. Thus, the mechanical and dynamical properties of the tire decrease. To overcome this problem, we investigated nonfunctionalized liquid butadiene rubber (LBR-305, Kuraray) and center-functionalized liquid butadiene rubber (C-LqBR), polymerized by anionic polymerization. In addition to the liquid butadiene rubbers, p-tert-octylphenol (P-Resin) and C5 hydrocarbon (H-Resin) tackifier resins, which can induce entanglement of rubber compounds, were researched as a processing aid to solve the bleeding problem. Liquid butadiene rubbers have significantly reduced extraction loss by crosslinking with the main rubber chain. They have also increased the abrasion resistance and showed similar or better mechanical and dynamical properties against HA oils. However, resin compounds did not show differences in extraction loss compared to HA oil compounds; instead, they showed increased wet traction.

• Journal of the Korean Vacuum Society
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• v.4 no.S2
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• pp.131-138
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• 1995

The broad beam ion sources of hot filament plasma type have widely used for modifications of materials and thin films, and the new type intensive current broad beam metal ion source including reactive gaseous ion beams is needed for preparing the hard coating films such as DLC, $\beta-C_3N_4$ Carbides, Nitrides, Borides etc. Now a electorn beam evaporation(EBE) broad beam metal ion source has been developed for this purpose in our lab. CN film has been formed by the EBE ion source. Study of the CN film shows that it has high hardness(HK=5800kgf/$\textrm {mm}^2$)and good adhesion. This method can widely changes the ratio of C/N atom's concentrations from 0.14 to 0.6 and has high coating rate. The low energy pocket ion source which was specially designed for surface texturing of medical silicon rubber was also developed. It has high efficiency and large uniform working zone. Both nature texturing and mesh masked texturing of silicon rubbers were performed. The biocompatibility was tested by culture of monocytes, and the results showed improved biocompatibility for the treated silicon rubbers. In addition, the TiB2 film synthesized by IBED is being studied recently in our lab. In this paper, the results which include the hardness, thickness of the films and the AES, XRD analysis as well as the tests of the oxidation of high temperature and erosion will be presented.

• Elastomers and Composites
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• v.37 no.4
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• pp.234-243
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• 2002

A general scheme of a rubber structure is proposed. Using the thermomechanical method(TMA), some changes in the molecular and topological structures for uncured and cured, and unfilled and filled rubbers during processing are shown. In our investigations as region it is understood a complex structure, which is expressed at the thermomechanical curve(TMC) as a zone differed from others in thermal expansion properties. This zone is between the noticed temperatures of relaxation transitions, usually on the level like those determined by DMTA at 1Hz. These regions, which shares, are not stable, and differ in molecular-weight distribution(MWD) of chain fragments between the junctions. Differences in dynamics of the formation of the molecular and topological structures of a vulcanizate are dependent on the rubber formulation, mixing technology and curing time. Some of characteristics of these regions correlate with mechanical properties of vulcanizates what is shown for NR rubbers containing ENR or CPE as a polymeric additive. It is well known that the state of order influences diffusivity of low-molecular substances into the polymer matrix. Because of this, the two topological amorphous regions should influence the distribution of the ingredients and resulting in rubber compounds' heterogeneity, and related properties of cured rubber. Investigation of this problem is expected to be, in the future, one of the essential factors in determining further improvement of polymeric materials properties by compounding with additives and in reprocessing of rubber scrap.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.6
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• pp.226-234
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• 2021

The objective of this study is to establish the fundamental design data for axial load-displacement relationship under axial monotonic or cyclic responses of seismic damping·isolation (SDI) units developed for ceiling structures. The main parameters include the installation of a spring, the number of rubber layer, prestress stress of bolts for connector between the spring and rubbers, and loading type. Test results showed that SDI units with a spring in the core and higher prestress stress of bolts tended to be higher stiffness at the ascending branch and more ductile behavior at the descending branch. This trends more notable for the specimens under monotonic load rather than cyclic loads. Consequently, the energy dissipation of SDI unit can be optimally designed with the following conditions: installation of a spring within 3-layer rubbers and prestress applied to the bolts at 10% of their yielding strength . When compared with the experimental tension capacity of the developed SDI units, the predictions by JIS B 2704-1 and KDS 31 00 are conservative under monotonic loading but higher by approximately 10% under cyclic loading.

• Earthquakes and Structures
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• v.23 no.4
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• pp.373-384
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• 2022

To improve the seismic performance of suspended ceiling structures, various vibration-damping devices have been developed. However, the devices made of metals have a limit in that they cause large deformation and seriously damages the exterior of the suspended ceiling structure from the wall. As a results, their strengthening effect of the suspended ceiling structure was minimal. Thus, this study employed a spring and vibration-proof rubber effectively controlled vibrations without increasing horizontal seismic loads on the ceiling to enhance the seismic resistance of suspended ceiling structures. The objective of the study is to examine the dynamic properties of a seismic damping-isolation unit (SDI) with various details developed. The developed SDI was composed of a spring, embossed rubbers, and prestressed bolts, which were the main factors enhancing the damping effect. The shaking table tests were performed on eight SDI specimens produced with the number of layers of embossed rubber (n_s), presence or absence of a spring, prestressed force magnitude introduced in bolts (f_ps), and mass weight (W_m) as the main parameters. To identify the enhancement effect of the SDI, the dynamic properties of the control specimen with a conventional hanger bolt were compared to those of the SDI specimens. The SDI specimens were effective in reducing the maximum acceleration (A_{c max}), acceleration amplification factor (α_p), relative displacement (δ_R), and increasing the damping ratio (ξ) when compared to the control specimen. The A_{c max}, α_p, and δ_R of the SDI specimens with two rubbers, spring, and f_ps of 0.1f_by, where f_by is the yielding strength of the screw bolt were 57.8%, 58.0%, and 61.9% lower than those of the conventional hanger bolt specimens, respectively, resulting in the highest ξ (=0.127). In addition, the α_p of the SDI specimens was 50.8% lower than those specified in ASCE 7 and FEMA 356. Consequently, to accurately estimate the α_p of the SDI specimens, a simple model was proposed based on the functions of f_ps, stiffness constant of the spring (K), W_m, and n_s.

• Macromolecular Research
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• v.9 no.1
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• pp.45-50
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• 2001

Formation of bound rubber depends on the filler-polymer interactions including physical adsorption, chemisorption, and mechanical interaction. Bound rubbers consist of tightly and loosely bound ones. Styrene-butadiene rubber (SBR) is composed of styrene, 1,2-, cis-1,4-, and trans-1,4-units. Filler-polymer interactions of each components of SBR with fillers, carbon black and silica, were studied by analysis of microstructure of the bound rubber. Filler-polymer interaction of the 1,2-unit with the fillers was found to be stronger than those of the other components and this phenomenon was shown more clearly in the tightly bound rubber.

• Elastomers and Composites
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• v.28 no.1
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• pp.13-21
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• 1993

Polyurethane resin was especially mixed with polybutadiene rubbers which had each other different molecular structures and functional groups. Liquid and cure properties were tested experimentally for mixtures. Viscosity of mixtures and drying time were influenced by solubility of thinner and reactivity of rubber. Adhesive strength represented maxium at rubber content $15{\times}22%$ (Wt. % ), and rapidly decreased over 25%. DBTDL(di-n-butyltindilaurate) showed the longest stroage stability.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 1999.10a
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• pp.367-374
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• 1999

this paper focuses on the dynamic characteristics of full-scale viscoelastic dampers through the experimental study. Viscoelastic dampers which dissipate the response energy of a building under earthquake excitation make a role of increasing damping capacity of the building. Therefore it is important to recognize the damping behavior of viscoelastic dampers. Full-scale viscoelastic dampers are made of three types of rubbers for experimental test. The hysteretic behavior is obtained through the load-deformation experiment over the various loading frequencies and damper strains The experimental results show the good performance of viscoelastic dampers under earthquake excitations,

• Journal of the Korean Society for Nondestructive Testing
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• v.25 no.5
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• pp.368-376
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• 2005

Coolant rubber hoses for automobile radiators can be degraded and thus failed due to the influence of contacting stresses of air and coolant liquid under thermal and mechanical loadings. In this study, for EPDM(ethylene-propylene diene monomer) rubber conventionally used as a radiator hose material the aging behaviors of the skin part due to thermo-oxidative and electro-chemical stresses were nondestructively evaluated. Through the thermo-oxidative aging test, it was shown that the surface hardness IRHD(International Rubber Hardness Degrees) of the rubber increased with a considerable reduction of failure strain. On account of the penetration of coolant liquid into the skin part the weight of rubber specimens degraded by electro-chemical degradation(ECD) test increased, whereas their. failure strain and IRHD hardness decreased largely. The penetration of coolant liquid seemed to induce some changes in inner structure and micro hardness distribution of the rubbers. Consequently, EPDM rubbers degraded by thermo-oxidative aging and ECD could be characterized nondestructively by micro-hardness and chemical structure analysis methods.

• Elastomers and Composites
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• v.24 no.4
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• pp.276-289
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• 1989

This study deals with both effects of inorganic fillers to vulcanized rubbers such as NR, CR, EPDM, NBR & SBR and inorganic characteristics of domestic fillers in comparision with hard clay produced in the USA. The results were as follows. 1. Main ingredient of domestic clay "Ha-dong clay" was Halloysite, "No-ha Island" was Pyrophyllite with $\alpha$-Quartz, and both of "Hard clay" & "Hwa-soon clay" were proved to be Kaolinite by XRD, DT-TGA and chemical analysis by XRF. 2. Tensile strength value of SBR compounded with these fillers, was Hard clay $146kg\;f/cm^2$, Kaolinite $123kg\;f/cm^2$, Pyrophyllite $82kg\;f/cm^2$, Halloysite $80kg\;f/cm^2$, precipitated $CaCO_3\;27kg\;f/cm^2$, and ground $CaCO_3$ was $21kg\;f/cm^2$. These results showed the increase of seven times according to filler species. 3. The physical properties of non-crystalline rubbers, such as SBR, NBR & EPDM, compared with NR & CR, have been considerably changed according to crystalline phase, particle size, shape and surface structure of fillers. Especially, tensile strength value in case of SBR & EPDM, was differentiated about 1.5 times by the particle size of fillers. 4. In SBR, physical properties of rubber compounded with Kaolinite which was surface treated with fatty acid and silane, almost approach to the value of hard clay. 5. Delayed cure time of Kaolinite and decrease of rubber properties by $CaCO_3$ can be improved by blending kaolinite & $CaCO_3$ in the ratio of 2:1.