• Title/Summary/Keyword: rubber waste

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Removal of Impurities from Waste Carbon Sludge for the Recycling (폐 카본슬러지의 재활용을 위한 不純物 분리 제거)

  • 이성오;국남표;오치정;김선태;신방섭
    • Resources Recycling
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    • v.10 no.3
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    • pp.51-59
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    • 2001
  • Impurities removal from waste carbon black was carried out to produce high-grade carbon black. A large amount of hydrophilic carbon black is produced as a byproduct of the hydrogen production process by flame decomposition of water. Due to its impurities content such as sulphur, iron, ash, etc., it can only be used as low-grade carbon or burnt out. High-grade hydrophilic carbon black is 3~5 times more expensive than oil-based carbon black because of high production cost associated with process complexly and pollutant treatment. Hydrophilic carbon is normally used for conductive materials for batteries, pigment for plastics, electric wire covering, additives for rubber, etc. In these applications, impurity content must be blow 1 fe. In this study, magnetic separation, froth flotation and ultrasonic treatment were employed to remove impurities from the low-grade hydrophilic carbon black. Results showed that the ash, iron and sulphur content of product decreased to less than 0.01 wt.%, 0.01 wt.% and 0.3 wt % respectively and the surface area of product was about 930 $m^2$/g for conductive materials.

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A Study on the Mechanical Properties of Surface Activated Waste EPDM and The Analysis of Odor Materials (표면 활성화된 폐 EPDM 분말의 물성과 냄새 성분 분석 연구)

  • Choi, J.;Kim, S.;Chung, K.;Chung, J.;Yoo, T.;Yang, J.
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.249-258
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    • 2007
  • In this study, the EPDM powder which was surface activated by high temperature and shear pulverization process was prepared and the mechanical properties and odor material analysis were investigated. Analysis for particle size and size distribution of waste of the EPDM powder has been performed. The waste EPDMs used in this study were 4 types of solid, sponge, solid+sponge, and solid+metal. According to the results, the solid type showed the smallest particle size among the 4 types of EPDM powder. Effective surface devulcanization of EPDM powder could be obtained by the addition of the reclaiming agent. The dicumyl peroxide was considered as the best crosslink agent for dynamic vulcanization when the surface activated EPDM powder was blended with polyolefin in order to make TPE. Also, the optimum amounts of DCP was 6 phr in terms of surface crosslink reaction and mechanical properties of EPDM powder. The processes of water adsorption and rose oil addition were employed to remove the odor of EPDM powder caused by reclaiming agent. The GC/MS was used to analyze the odor compounds.

A study on the implementation of infection control at dental offices (치과 진료실 감염방지 실천에 관한 연구)

  • Woo, Seung-Hee;Kwag, Jung-Suk;Ju, On-Ju;Lim, Kun-Ok
    • Journal of Korean society of Dental Hygiene
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    • v.9 no.3
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    • pp.282-293
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    • 2009
  • The purpose of this study was to examine the degree of infection control implemented at dental offices and factors affecting it in an attempt to help promote the health of dental health care workers. The subjects in this study were 180 medical personnels who worked at dental offices in the region of South Jeolla Province. A self-administered survey was conducted from April 1 to May 30, 2008, and the collected data were analyzed. The findings of the study were as follows: 1. As for the implementation of infection control at the dental offices, what the health care workers investigated did the most was post-treatment hand washing(95.0), a constant separation of infectious wastes(94.4), wearing rubber gloves all the time during medical instrument cleansing(92.8) and pre-treatment hand washing(91.7). 2. In regard to the implementation of infection control at the dental offices, what the dental personnels did the least was drying their hands with air(5.0), wearing goggles in times of treatment(23.3), receiving regular education on infection control(26.7) and putting sterilizers to a performance test on a regular basis(43.9). 3. The dental health care workers were significantly different according to age in the management of contagious diseases(p=0.005). Their career made a significant difference to the management of contagious diseases(p=0.000) and instrument cleansing/sterilization(p=0.043). The service area made a significant difference to wearing and managing personal protective clothes (p=0.040) and waste management(p=0.040). 4. Concerning the relationship between the acquisition of dental hygienist certificate and the practice of infection control, whether the dental health care workers were certified or not made no significant difference to that. 5. As to the correlation among the factors affecting the prevention and management of contagious diseases, there was a positive correlation among hand washing(r=0.379), wearing and managing personal protective clothes(r=0.349), instrument cleansing/sterilization(r=0.323) and waste management(r=0.388). All the factors made a statistically significant difference to the prevention and management of contagious diseases(p<0.01).

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Investigation on Material Flow Diagram for PVC(poly vinyl Chloride) Profile Based Production, Generation, Recycling and Treatment (PVC재질 프로파일의 생산, 발생 및 재활용, 처리에 기반한 물질흐름도 검토)

  • Phae, Chae-Gun;Jung, Oh-Jin
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.129-140
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    • 2012
  • The objective of this study was to estimate the practical recycling rate of plastic products, so that the study was conducted to build material flow diagram for PVC profile. For this objective, product generation, waste generation and recycling status were investigated. Using collected and analyzed status data, analysis of material flow by product and building material flow diagram were conducted. As result of estimating the recycling rate by product, The sum of domestic demand was 525,448 ton and waste generation was 105,853ton in PVC flooring and profile. The sum of generation of recycling product and raw material was investigated to be 76,004ton(14.46%), which is higher compared to recycling obligation(8.5%) in 2009. To build the material flow diagram in the years(5~20years) ahead, prediction of future demand was based on the assumption that there will be no difference in annual generation of current and future. As the recycling rate of flooring and profile increases, it is estimated to reach 20% in 2013 according to the material flow diagram.

Study on the Correlation between Quality of Cement and Amount of Alternative Fuels used in Clinker Sintering Process (시멘트 클링커 소성공정 대체연료 사용량과 시멘트 품질간 상관관계 연구)

  • Choi, Jaewon;Koo, Kyung-Mo;You, Byeong-Know;Cha, Wan-Ho;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.75-84
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    • 2021
  • In this study, the correlation between cement quality(chemical composition, mineral composition, and compressive strength) and amount of waste alternative fuels used in the cement manufacturing process and was investigated. Cement manufacturing facility using coal, soft plastics(plastics that are easily scattered by wind power, such as vinyls), hard plastics(plastics that do not contain foreign substances, waste rubber, PP, etc.) and reclaimed oil was analised. Data was collected for 3 years from 2017 to 2019 and let the amount of fuels used as an independent variable and cement quality data as a dependent variable. As a result, depending on the type and quality of the alternative fuel has not a significant effect on the chemical composition(Cl and LSF) and mineral composition(f-CaO, C3S contents). Contrary to the concern that the compressive strength of cement would decrease, there was a significant positive correlation between amount of alternative fuel used and cement compressive strength.

Adsorption Characteristics of Nickel and Zinc Ion on Domestic Activated Carbon (활성탄에 의한 니켈 및 아연 이온의 흡착특성)

  • Chan-Kuk Kim;Tae-Won Min
    • Journal of the Korean Chemical Society
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    • v.28 no.2
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    • pp.121-129
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    • 1984
  • The adsorption characteristics of heavy metal ions $(Ni^{2+}$, $Zn^{2+}$) on domestic activated carbon which manufactured from the wood, waste rubber and coal has been studied. The following conclusions were obtained by investigating the effect of pH, halides, cyanide and temperature on the absorption of heavy metal ions and by determining absorption rate and absorption isotherms. When heavy metal ions were adsorbed on activated carbon in the pH range from 6 to 7, treated heavy metal ions were almost come to the equilibrium and recovered in the form of complex anions such as $MX_4^{2- }$and $M(CN)_4^{2-}$ in an hour. The absorption isotherms of heavy matel ions were well fitted in Freundlich's equation. Heavy metal complex anions on activated carbon were easily eluted by using 0.1N HCl solution. These results suggest that the complex anions have unexpectedly strong affinity for the surface of activated carbon.

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Synthesis and Lubricant Properties of Vegetable Oil based on Estolides (식물유 기반 에스토라이드 합성 및 윤활 특성)

  • Son, Jeong-Mae;Kim, Nam-Kyun;Shin, Jihoon;Chung, Kunwo;Yoon, Byung-Tae;Kim, Young-Wun
    • Tribology and Lubricants
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    • v.31 no.5
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    • pp.195-204
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    • 2015
  • Several researches are focused on improving the value of fine chemicals based on biomass resources due to environmental and other concerns associated with the use of petroleum-based products. Therefore, the synthesis and application of estolides derived from plant-based waste oil materials and their application as lubricants and as processing oil for butyl rubber products have been studied. Four kinds of estolide were prepared with conversions of 71~92% over 24h using various vegetable oils, as determined by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. FT-IR spectroscopy determines the esterification of estolides using 2-ethylhexyl alcohol. The estolides have iodine values of 35~90, α-ester/α-acid ratios of 0.45~0.55, and total acid number of 114~134 mg KOH g–1. Four ball wear tests show that the wear scar diameters (WSDs) of estolides as base oil significantly decreased to 0.328~0.494 mm, compared to WSDs of 0.735 and 0.810 mm of WSD for 150N and Yubase 6, respectively, as general base oil. Thus, the estolides have better wear resistance and satisfying design objectives for the engineering of a variety of lubricant base oils.

Mechanical Properties of Composites of HDPE and Recycled Tire Crumb (폐타이어 분말과 고밀도 폴리에틸렌 복합재료의 기계적 물성)

  • Kwak, Sung-Bok;Choi, Mi-Ae;Lee, Seong-Jae
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.22-29
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    • 2001
  • For a purpose of recycling of waste tires, composites of 10-60wt% recycled tire crumb blended with high density polyethylene(HDPE) were prepared, and their mechanical properties such as tensile strength, elongation at break, tensile modulus and impact strength were investigated as a function of tire crumb content. Ethylene-acrylic acid(EAA) copolymer was introduced by 10phr as a compatibilizer and the mechanical properties of the composites were measured. For the blend composition of 40wt% tire crumb content showing improved impact strength, the mechanical properties were measured by varying the EAA content of 5-15phr. All blends, whether modified or unmodified, showed a gradual improvement in impact strength as the tire crumb content increased, but the other properties decreased compared with the pure HDPE. In particular, the addition of EAA copolymer to the tire crumb content over 30wt% showed substantial improvement in impact strength. There was no significant effect of tire crumb size on impact strength of the composites.

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Current Status of Tire Recycling in Taiwan

  • Shanshin Ton;Taipau Chia;Lee, Ming-Huang;Chien, Yeh-Chung;Shu, Hung-Yee
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.230-235
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    • 2001
  • There are more than 15 millions cars or motors in Taiwan. According to the statistics from Environmental Protection Administration, the number of resulting scrap tires are near 110 thousand tons each year. The tire recycle programs in Taiwan were first conducted in 1989 and executed by ROC Scrap Tire Foundation. However, the current efficiency of the tire recycling industry still needs to be improved to minimize the environmental problem or fire hazards caused by scrap tires storage. Ten major tire-recycling factories are surveyed in this study. The investigations include the source of scrap tire, the shredding process, the market of products, the management of wastes disposal, and the difficulties of these sectors. As the varieties of the shredding machines of the recycle factories, there are three kinds of final products which include powder, granular, and chips. The wastes, wires and fibers, produced by the shredding process are the major problems fur all the factories. The percentage of the wire and fiber removal from rubbers still needs to be increased. The best approaches found in this study to increase the efficiency of scrap tire recycling processes are proposed which include the improvement of magnetic separation system fiber/rubber separation system and the minimization of waste disposal. A categorized standard of the processing outputs is suggested as a reference for the decision-making of the tire-recycling factories.

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System Improvement Research for Commercial Propulsion about Government R&D Product(In Case of LRT) (국가 R&D 성과품 상용화 추진을 위한 제도개선방안 연구 (경량전철을 중심으로))

  • Hong, Jai-Sung;Park, Kwang-Bok;Rhy, Sang-Whan;Lee, An-Ho
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.322-330
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    • 2009
  • Traffic congestions in local cities have been getting worse since 1990s, so many local governments have considered the introduction of an LRT system. So far, there is no city operating the LRT due to social environments, financial reasons, feasibility and so on. But still many cities have examined LRT or started the construction. Until now, more than 30 cities are constructing LRT or planning the introduction of LRT and it becomes 96 routes, approximately 700km. With the support of MLTM, KRRI has developed automatic LRT system with rubber-wheels, K-AGT as a result of "LRT system technology development project" from 1999 to 2005 by investing 50.32 billion wons(the public 37, the private 13.32) and finished running durability test of 100,000km at Kyeong-san test line. Currently, two trains, coupled two cars respectively have running and signaling tested. K-AGT was appointed to supply for an extension line at Busan Subway Line 3(Minam-Anpyeong section) with 17 trains(six-unit car) 102 cars. However, except for Minam-Anpyeong section, other cities such as Uijeongbu, Yongin, Daegu(Line 3) and Kwangmyeong decided to use the foreign systems, not to use the product, a result of national R&D project. This results in a huge waste of foreign currency and it is expected to require much additional cost for maintenance. If local governments use the products of national R&D projects, many national benefits such as reducing imports and protecting home industries could be expected, therefore in this paper, some plans to encourage to use products of national R&D projects were dealt with.

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