• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.8
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• pp.678-686
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• 2002

This paper presents the effects of accumulation of surface charges on hydrophobic level and the changes of surface potential decay with various artificial environment treatments on high temperature vulcanized (HTV) silicone rubber used for outdoor insulating material. For this study, the charging apparatus by corona discharge, in which grid electrode was installed between the main corona and ground electrode, was used. From this study, it was found that the accumulation of surface charges above a critical surface potential on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addition, corona stress and water absorption stress increase the decay rate of surface charges of HTV silicone rubber, while ultraviolet (UV) stress causes longer decay time. We could conclude that the effects of surface charges on hydrophobicity level and the changes of surface state by various artificial treatments were found through a trend of surface potential decay.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1497-1499
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• 1997

This paper dealt with the surface aging characteristics of silicone rubber used as the surface material of outdoor polymer insulators under accelerated aging condition. There are many aging factors in natural environment. In this paper, the silicone rubber were accelerated to evaluate their performance against salt fog, that is, they were dipped in pure water and salt water under boiling condition. Then, contact angle and SEM(Scanning Electron Microscope) were used to estimate surface hydrophobicity, and dielectric loss($tan{\delta}$) and surface leakage current were measured to observe the electrical characteristics.

• KIEE International Transactions on Electrophysics and Applications
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• v.12C no.4
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• pp.214-219
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• 2002

The influence of ultraviolet (UV) irradiation and corona on the surface degradation of high temperature vulcanized (HTV) silicone rubber used for outdoor insulation through measuring surface voltage decay after corona charging, surface resistivity, contact angle and X-ray photoelectron spectroscopy (XPS) analysis was studied. The surface resistivity calculated by the surface voltage decay was compared with a value directly obtained from the three electrode method having the guard ring electrode. A good agreement between the two methods for surface resistivity was obtained. UV treated specimens showed the slower decrease of surface voltage decay, while the corona exposed specimens showed a dramatically faster decrease. Although both artificial treatments cause the same oxidative products, which was confirmed with XPS, we could distinguish the difference between the reactions of the two treatments by monitoring the surface voltage decay on corona-charged specimen. In addition, we could derive the specific surface states of the silicone rubber treated by accelerated artificial aging factors and the degradation process.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.5
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• pp.125-133
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• 2011

The wear of rubber track being in contact with the road surface is an important subject because it decreases the traction performance and the operating efficiency of tracked vehicle. For the above reasons, many attempts have been made to quantitatively calculate the rubber track. However, it depends on the experimental methods which are highly time- and cost-consuming. Therefore, the numerical simulation approach is highly desirable, but it needs to model the complex geometry and the material behavior in details as well as the interaction with the road surface. In this study, the rubber track and its material behavior are elaborately modeled since these factors are very important in the prediction of the wear rate of the rubber track. Accordingly to the studies on the rubber wear by previous investigations, it has been found that the wear is greatly influenced by the frictional energy. The frictional energy of rubber track is computed by utilizing the 3D finite element analysis of the rubber track, and the wear rate is evaluated making use of the frictional energy and a wear model.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.121-124
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• 2001

Surface-modified silica holds considerable promise in the development of advanced materials for good mechanical properties and stability. In this work, the surface and mechanical interfacial properties of silicas treated with silane coupling agents, such as Y-methacryloxy propyl trimethoxy silane (MPS). Y-glycidoxy propyl trimethoxy silane (GPS), and Y-mercapto propyl trimethoxy silane (MCPS), are investigated. The effect of silane surface treatments of silica on the surface properties and surface energetics are studied in terms of surface functional values and contact angle measurements. And their mechanical interfacial properties of the silica/rubber composites are studied by the composite tearing energy ($G_{IIIC}$). As a result. the mechanical interfacial properties are improved in the case of silane-treated composites compared with untreated one. It reveals that the functional groups on silica surface by silane surface treatments play an important role in improving the degree of adhesion at interfaces in a silica-filled rubber system.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.4
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• pp.105-110
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• 2014

This paper presents the hysteresis friction of a sliding elastomer on various types of surfaces. The hysteresis friction is calculated by means of an analytical model which considers the energy spent by the local deformation of the rubber due to surface asperities. By establishing the fractal character of the surfaces, the contribution to rubber friction of roughness at different length scales is accounted for. High resolution surface profilometer is used in order to calculate the main three surface descriptors and the minimal length scale that can contribute to hysteresis friction. The results show that this friction prediction can be used in order to characterize in an elegant manner the surface morphology of various surfaces and to quantify the friction coefficient of sliding rubber as a function of surface roughness, load and speed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.78-81
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• 2004

In this paper, the effect of adhesion properties of semiconductive-insulating interface layer of silicone rubber on electrical properties was investigated. Surface structure and adhesion of semiconductive silicon rubber by surface asperity was obtained from SEM and T-peel test. In addition, ac breakdown test was carried out for elucidating the change of electrical property by roughness treatment. From the results, Adhesive strength of semiconductive-insulation interface was increased with surface asperity. Dielectric breakdown strength by surface asperity decreased than initial Specimen, but increased from Sand Paper #1200. According to the adhesional strength data unevenness and void formed on the silicone rubber interface expand the surface area and result in improvement of adhesion. Before treatment Sand Paper #1200, dielectric breakdown strength was decreased by unevenness and void which are causing to have electric field mitigation small. After the treatment, the effect of adhesion increased dielectric breakdown strength. It is found that ac dielectric breakdown strength was increased with improving the adhesion between the semiconductive and insulating interface.

• Elastomers and Composites
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• v.51 no.2
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• pp.113-121
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• 2016

Magneto-rheological elastomer (MRE) is a material which shows reversible and various modulus under magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, silicone rubber was used as a matrix of MREs. Carbonyl iron particle (CIP) was used to give magnetic field reactive modulus of MRE. The surface of the CIP was modified with chemical reactants such as silane coupling agent and poly(glycidyl methacrylate), to improve interfacial adhesion between matrix and CIP. The mechanical properties of MREs were measured without the application of magnetic field. The results showed that the tensile strength was decreased while the hardness was increased with the addition of CIP. Also, surface modification of CIP resulted in the improvement of physical properties of MRE, but the degree of orientation of CIP became decreased. The analysis of MR effect was carried out using electromagnetic equipment with various magnetic flux. As the addition of CIP and magnetic flux increased, increment of MR effect was observed. Even though the surface modification of CIP gave positive effect on the mechanical properties of MRE, MR effect was decreased with the surface modification of CIP due to decrease of CIP orientation. Throughout this study, it was found that the loading amounts of CIP affected the mechanical properties of MRE, and surface property of CIP was an important factor on MR effect of MRE.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.581-585
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• 2010

The surface of Alnico, one of the industrial dust waste, was treated with 1,3,5-trivinyl-1,3,5-trimethylcyclotrisilazane (VMS) as a surface treating agent and used as the filler for vibration isolator rubber. Maleated EPDM prepared from bulk polymerization of EPDM with maleic anhydride was copolymerized with ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane to obtain maleated EPDM-polydimethylsiloxane copolymer (MEPDM-PDMS). EPDM/Alnico/MEPDM-PDMS vibration isolator rubber was prepared from compounding with Alnico treated with surface treating agent, 25 and 50 phrs to EPDM, respectvely based on 1 to 10 wt% of MEPDM-PDMS to EPDM. From the measurement of the thermal properties to the rubber, the glass transition temperatures (Tg) for the rubber containing maleated EPDM-PDMS copolymer was slightly lower temperature, $33^{\circ}C$ than EPDM rubber, and also DMA results showed higher tan ${\delta}$ peak to the rubber prepared from compounding with EPDM-PDMS copolymer. From the results, rubber prepared using EPDM-PDMS copolymer had better vibration isolator property.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1651-1653
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• 1999

Room Temperature Vulcanizing (RTV) Silicone Rubber has been widely used to coat porcelain insulator to prevent formation water filming on insulator surface. and RTV silicone rubber has water repellency to suppress leakage current and consequent flashover. RTV silicone rubber's surface has been degradated by outdoor condition such as dust, salt, and water. etc. ESDD(Equivalent Salt Deposit Density) and leakage currents are increased by polymer surface toughness and degradation. In this paper, we investigated relations of surface toughness, ESDD, and leakage currents.