• Title/Summary/Keyword: rubber latex

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An Experimental Study on the Mechanical Properties of Fiber Reinforced Fly Ash.Lime.Gypsum Composites (섬유보강 플라이애쉬.석고.복합체의 역학적특성에 관한 실험적 연구)

  • 박승범
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.145-155
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of fiber reinforced fly ash$\cdot$lime$\cdot$gypsum composites are presented in this paper. 'The composites using fly ash, lime, and gypsum were prepared with various fibers (PAN-derived and Pitch-derived carbon fiber, alkali-resistance glass fiber) and a small amount of polymer emulsion-styrene butadiene rubber latex (SBR). As the test results show, the manufacturing process technology of fly ash$\cdot$lime$\cdot$gypsum composites was developed and its optimum mix proportions were successfully proposed. And the flexural strength and toughness of fiber reinforced fly ash$\cdot$lime $\cdot$gypsum composites were increased remarkably by fiber contents, but the compressive strength of the composites were influenced by the kinds fiber more than by the fiber contents. Also, the addition of a polymer emulsion to the composites decreased the bulk specific gravity, but the compressive and flexural strength, and the toughness of the composites were not influenced by it, but were considerably improved by increasing fiber contents.

Synthesis and Characterization of Silica/Polystyrene Composite Nanoparticles by in situ Miniemulsion Polymerization (In situ 미니에멀젼중합에 의한 실리카/폴리스타이렌 복합체 나노입자의 합성과 특성)

  • Patole, Archana S.;Patole, S.P.;Song, Mi-Hyang;Yoon, Joo-Young;Kim, Jin-Hwan;Kim, Tae-Ho
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.34-40
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    • 2009
  • New coupling agent or surface modified agent (9-decenoic acid) was used to enhance the compatibility between silica and polystyrene in silica/polystyrene hybrid nanocomposite, synthesized by in situ miniemulsion polymerization. Composites contain well dispersed nanosize silica particles. Related tests and analyses confirmed the success of synthesis. Functionalization of silica by 9-decenoic acid and silica on the polystyrene was confirmed by FTIR. TGA showed presence and amount of silica in final latex. The glass transition temperature of the hybrid nanocomposite was increased with the silica amount. SEM and TEM analysis showed the spherical morphology of PS and composite with an average diameter of 55 nm. The presence of silica within composite was confirmed by EDS attached to the existing TEM.

Evaluation of Hot Mix Asphalt Properties using Complex Modifiers (복합개질제를 이용한 아스팔트 혼합물의 물성 평가)

  • Lee, Kwan-Ho;Kim, Seong-Kyum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.5
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    • pp.146-152
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    • 2018
  • In this study, to improve the performance of asphalt mixtures for plastic deformation occurring mainly in Korea, complex modifiers were prepared by mixing powders and liquid type modifiers. The main constituents were powdery diatomaceous earth, mica and carbon black, and liquid type solid 70% SBR latex. The tensile strength ratios for the two asphalt mixtures used in the test were above 0.80 for the Ministry of Land Transportation (2017) asphalt mixture production and construction guidelines. The effects of increasing the tensile strength in the dry state was more than 14% when the composite modifier was added. The deformation rate per minute by the wheel tracking test load was an average of 0.07 to 0.147 for each mixture. The strain rate per minute was improved by the modifier, and the dynamic stability was improved by almost 100% from 295 to 590. In addition, the final settling was reduced from 11.38 mm to 9.57 mm. A plastic deformation test using the triaxial compression test showed that the amount of deformation entering the plastic deformation failure zone at the end of the second stage section and in the third stage plastic deformation section was 1.76 mm for the conventional mixture and 1.50 mm for the complex modifier mixture. The average slope of the complex modifier asphalt mixture mixed with the multi-functional modifier was 0.005 mm/sec. The plastic deformation rate is relatively small in the section where the road pavement exhibits stable common performance, i.e. the traffic load.

Preparation and Characterization of $CaCO_3$ Encapsulation by PMMA Core-Shell latex (PMMA와 캡슐화된 $CaCO_3$ Core-Shell 라텍스 제조와 물성연구)

  • Lim, Jong-Min;Seul, Soo-Duk
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.303-315
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    • 2003
  • Inorganic/organic composite particles were also synthesized by changing an initiator an it's concentration, concentration of an adsorbed surfactant, reaction temperature, and agitation speed in the presence of $CaCO_3$ adsorbed SDBS. The polymerization conditions were optimized according to the conversion of the core-shell composite particles. In the inorganic/organic core-shell composite particle polymerization, $CaCO_3$ absorbed surfactant SDBS of 0.5 wt % was prepared first and then core $CaCO_3$ was encapsulated by sequential emulsion polymerization using MMA, concentration of APS $3.16{\times}10^{-3}mol/L$ to minimize the formation of new PMMA particle during MMA shell polymerization. The structure characterization of the inorganic/organic core-shell particles was verified by measuring the decomposition degree of $CaCO_3$ using HCl solution. It was found that $CaCO_3$ was encapsulated by shell PMMA due to having excellent dispersion in the epoxy resin, smooth surface distinctly from spindle shape, and broad particle distribution after the capsulation.