• Composites Research
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• v.23 no.6
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• pp.32-38
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• 2010

The effect of the atmospheric pressure plasma(APP) treatments is experimentally investigated to ascertain the optimum condition to yield the best adhesive properties between a polyamide woven fabric and acrylonitrile butadiene rubber(NBR). For the atmospheric pressure flame plasma(APFP) treatment, the optimum number of treatment at given conditions is 2 times. The thermal deformation of the fabric is more serious with increasing the number of APFP treatment. The adhesive strength of the case with APFP treated fabric is increased about 35% when compare to the case with non-APFP treated one for the interface(bonding agent one or two coatings). When the surface is coated twice with the bonding agent, the adhesive energy with APFP treated fabric is increased about 4 times. It was found that the surface modification of polyamide woven fabric by APFP treatment is a fast, economic and applicable method to improve the adhesive properties between woven fabric and rubber when compared to other APP treatments.

• Steel and Composite Structures
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• v.27 no.6
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• pp.717-725
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• 2018

One of the most important design criteria in military tunnels and armoured doors is to resist the blast loads with minimum structural weight. This can be achieved by using steel sandwich panels. In this paper, the nonlinear behaviour of steel sandwich panels, with different core materials: (1) Hollow (no core material); (2) Rigid Polyurethane Foam (RPF); and (3) Vulcanized Rubber (VR) under free air blast loads, was investigated using detailed 3D nonlinear finite element models in Ansys Autodyn. The accuracy of the finite element model proposed was verified using available experimental test data of a similar steel sandwich panel tested. The results show the developed finite element model can be reliably used to simulate the nonlinear behaviour of the steel sandwich panels under free air blast loads. The verified finite element model was used to examine the different parameters of the steel sandwich panel with different core materials. The result shows that the sandwich panel with RPF core material is more efficient than the VR sandwich panel followed by the Hollow sandwich panels. The average maximum displacement of RPF sandwich panel under different ranges of TNT charge (1 kg to 10 kg at a standoff distance of 1 m) is 49% and 53% less than the VR and Hollow sandwich panels, respectively. Detailed empirical design equations were provided to quantify the maximum deformation of the steel sandwich panels with different core materials and core thickness under a different range of blast loads. The developed equations can be used as a guide for engineer to design steel sandwich panels with RPF and VR core material under a different range of free air blast loads.

• Elastomers and Composites
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• v.41 no.3
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• pp.164-171
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• 2006

Stress softening behaviors of SBR vulcanizates reinforced with silica or carbon black were studied. Two types of SBR with different 1,2-unit contents of 18 and 60 wt% were used and three filler systems of carbon black and silica with/without silane coupling agent were employed. Stress softening behaviors of the SBR vulcanizates were varied with the SBR types as well as the filler systems. The silica-filled rubber specimens had higher residual strains than the carbon black-filled ones. The residual strains of silica-filled vulcanizates were remarkably reduced by adding a silane coupling agent. The maximum loads at 50% maximum stretch of the carbon black-filled vulcanizates were lower than those of the silica-filled ones. On the contrary, the maximum loads at 200% maximum stretch of the carbon black-filled vulcanizates were higher than those of the silica-filled ones. The maximum loads of the specimens with the 1,2-unit content of 60 wt% are higher than those with the 1,2-unit content of 18 wt% irrespective of the filler systems.

• Magazine of the Korea Concrete Institute
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• v.3 no.3
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• pp.101-110
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• 1991

Results of an experimental study on the manufacture, the mechanical properties and watertightness of pitch - based carbon fiber reinforced fly ash. cement composites are presented in this paper. The carbon fiber reinforced fly ash. cement composites using early strength cement silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and physical properties such as compressive , tensile and flexural strengths, watertightness and drying shrinkage of lightweight carbon fiber reinforced fly ash cement composites are Improved by using a samll amount of stylene butadiene rubber latex. Also, the manufacturing pnx:ess technology of carbon fiber reinforced fly ash . cement composItes is developed. The development and applications of precast products of lightweight carbon fiber remforced cement composites are expected in the near future.

• Textile Coloration and Finishing
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• v.29 no.2
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• pp.97-103
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• 2017

Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the p-aramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber for technical textiles. For this purpose, dyed polyketone fabric is prepared, mechanical properties of coated and uncoated polyketone fabrics such as tensile strength, elongation and tear strength were examined before and after weather resistance test(temperature $63{\pm}3^{\circ}C$, humidity 60%, amount of power $0.35w/m^2$). The differences of mechanical properties between uncoated and coated fabrics for high functional technical textiles and composite materials are estimated through this study. The UV-stability of polyketone fabric showed obvious improvement after coating. After 168h(7day) of UV exposure, the coated fabric showed less deterioration in mechanical properties with the retained tensile strength and elongation at break greater than 22 and 17% of the uncoated polyketone fabrics values, respectively.

• Journal of Dental Rehabilitation and Applied Science
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• v.25 no.1
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• pp.13-22
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• 2009

The composite resin, due to its esthetic quality, is considered the material of choice for restoration of anterior teeth. To get a satisfactory result in the composite resin restorations, it is necessary to choose right shade. At present, most of the commercial composite resins are based on the Vita Lumin shade guides or shade guides that are provided by their company, but color differences among them might be expected even using the same shade in various materials. This study is to measure color differences between various light-cured composite resins and shade guides and to provide the clinicians with information which may aid in improved color match of esthetic restoration. Four kinds of light-cured composite resins (Gradia Direct (GD), Z250 (Z250), Clearfil AP-X (AP-X), Esthet X (E X)) and shade guides with A2 and A3 shade were used. Three specimens of each material and one specimen of each shade guide were made. Each composite resin was filled into the Teflon mold (1.35 mm depth, 8 mm diameter), followed by compression, polymerization and polishing with wet sandpaper. Shade guides were grinded with polishing stones and rubber points to a thickness of approximately 1.35 mm. Color characteristics were performed with a spectrophotometer(color i5, GretagMacbeth, USA). A computer-controlled spectrophotometer was used to determine CIELAB coordinates ($L^*$, $a^*$, $b^*$) of each specimen and shade guide. The CIELAB measurements made it possible to evaluate the amount of the color difference values (${\Delta}E^*ab$) between composite resins and shade guides. CIE standard D65 was used as the light source. The results were as follows : 1. Among the $L^*$, $a^*$, $b^*$ values of most of 4 kinds of composite resin specimens which are produced by same shade, there were significant differences(p<0.05). 2. Among all 4 kinds of composite resin specimens which are produced by same shade, there were color differences that is perceptible to human eye(${\Delta}E^*>3.3$). 3. Between most of composite resin specimens investigated and their corresponding shade guides, there were color differences that is perceptible to human eye(${\Delta}E^*>3.3$). 4. In the clinical environment, it is recommended that custom shade guides be made from resin material itself for better color matching. Shade guides supplied by manufacturers or Vita Lumin shade guide may not provide clinicians a accurate standard in matching color of composite resins, and there are perceptible color differences in most of products. Therefore, it is recommended that custom shade guides be made from resin material itself and used for better color matching.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.357-363
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• 2015

The development of the environment-friendly tire that meets the standard requirements according to tire labeling system can be improved through using highly homogeneous silica immobilized zinc oxide nanoparticles. In this study, a considerable amount of nanoporous silica was essentially added into nano zinc oxide to improve the physiochemical properties of the formed composite. The introduction of nanoporous silica materials in the composite facilitates the improvement of the wear-resistance and increases the elasticity of the tread. Therefore, the introduction of nanoporous silica can replace carbon black as filler in the formation of composites with desirable properties for conventional green tire. Herein, mesoporous silica immobilized zinc oxide nanoparticle with desirable properties for rubber compounds was investigated. Composites with homogeneous dispersion were obtained in the absence of dispersants. The dispersion stability was controlled through varying the molar ratio, ageing time and mixing order of the reactants. A superior dispersion was achieved in the sample obtained using 0.03 mol of zinc precursor as it had the smallest grain size (50.5 nm) and then immobilized in silica aged for 10 days. Moreover, the specific surface area of this sample was the highest ($649m^2/g$).

• Elastomers and Composites
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• v.48 no.2
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• pp.172-179
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• 2013

Impact modifier reinforced polymers are frequently used. In this study, Izod impact test has been simulated to analyze the mechanism of impact reinforcement of Nylon6 which contains impact modifier. The modeling of rubber particles added to Nylon6 as an impact modifier has been attempted. Based on the modeling, simulation of Izod impact test has been performed to observe the distribution and direction of stress at the cross-section of impact specimen. Three computer simulation models for Nylon6 were investigated. Those were without impact modifier, containing impact modifier without surface treatment, and containing impact modifier with surface treatment in the Nylon6. Simulation results showed that the stress which originated at the notch surface propergated to the inside of specimen round a impact modifier. In addition to that, impact modifier reinforced Nylon6 specimen showed low stress ditribution in the cross-section specially at notch surface. Principal stress in perpendicular direction to crack was also lowered in impact modifier reinforced Nylon6. These enhanced impact resistance reduced and crack propergations. Through this study it was realized that the computer simulation can be utilized to investigate the property enhacement of composite materials.

• Elastomers and Composites
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• v.48 no.2
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• pp.94-102
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• 2013

Characteristics of rubber mixture were evaluated in order to find the optimum mixing conditions of compounds containing silica and silane at various temperatures. With different mixing temperatures of 105, 120, 130, 140 and $160^{\circ}C$, the viscosity of the compound mixed at $105^{\circ}C$ showed a very high viscosity value. Compounds mixed the temperature range from at $120^{\circ}C$ to $140^{\circ}C$ showed lower viscosity than the compound mixed at $105^{\circ}C$. However, the difference was found to be small in those temperature ranges. On the contrary, at the mixing temperature of $160^{\circ}C$, the viscosity of compound increased again. Through the physical and dynamic observations, it was verified that at the mixing temperature below $120^{\circ}C$ only insufficient silica-silane reaction has been obtained. In addition, with the elevated mixing temperature of $160^{\circ}C$, Cross-linking occurred during mixing by the sulfur contained in coupling agent. In the temperature ranges from $120^{\circ}C$ to $140^{\circ}C$, because of the fast coupling reaction at higher temperature, it was thought to be more advantageous during reaction even though the trend of viscosity and dynamic mechanical property was not clear.

• Resources Recycling
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• v.24 no.2
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• pp.36-45
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• 2015

In this study, various sizes of waste ground rubber tire (WGRT) were devulcanized by a single screw extruder equipped with a sonicator in front of the die, and waste PP and devulcanized waste ground rubber tire (DWGRT) composites were prepared by an intermeshing co-rotating twin screw extruder. The crosslink density and percent devulcanization of WGRT and DWGRT for 40, 80 and 140 meshes were calculated. The mechanical properties of the composites were compared with each other. The effect of SEBS-g-MA as a compatibilizer was investigated on mechanical properties of both waste PP/WGRT and waste PP/DWGRT composites. The crosslink density was decreased with decreasing the WGRT size. On the other hand, the percent devulcanization was increased by adding the smaller size of WGRT. Also, tensile strength, impact strength and elongation at break of the composite with DWGRT were higher than those with WGRT. Especially, mechanical properties of the composites were significantly increased by adding the smaller size of WGRT and DWGRT. Addition of SEBS-g-MA into both waste PP/(D)WGRT composites exhibited better impact strength and elongation at break than the composites themselves.