• 제목/요약/키워드: rotational magnetization

검색결과 24건 처리시간 0.035초

An NMR Study on Dynamics of$ AX_3$ Spin System as Illustrated By Methyl Group in 2,6-Dichlorotoluene

  • 노정래;현남궁;이조웅
    • Bulletin of the Korean Chemical Society
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    • 제19권12호
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    • pp.1326-1333
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    • 1998
  • The study of coupled relaxation for methyl spin system in 2,6-dichlorotoluene was performed on the basis of the magnetization mode formalism. Using five initial perturbing pulse sequences, eight experimntal data sets were obtained, which were fitted with theoretical expressions with nine spectral density parameters. The same experiment was carried out at both 50.3 MHz and 125.6 MHz in carbon frequency. The measured spectral densities at both fields are similar in the exception of that related with carbon random field term. Furthermore, from the dipolar spectral density, the physical values may be extracted depending on the model of molecular reorientation. For example, it was assumed that the molecular framework undergoes asymmetric diffusive rotational process and methyl group reorients by either diffusive rotation about its symmetry axis or jump among internal rotational potential minima.

A Study on Spin-Lattice Relaxation of $^{19}$F Spins in Benzotrifluoride: Contributions from Dipole-Dipole Interaction and Spin-Rotation Interaction

  • Hyun Namgoong;Jo Woong Lee
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.91-95
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    • 1993
  • In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

An NMR Study on Molecular Motions of $\alpha$,2,6-Trichlorotoluene in Solution State

  • Ahn, Sang-Doo;Lee, Jo-Woong
    • Bulletin of the Korean Chemical Society
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    • 제15권7호
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    • pp.553-559
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    • 1994
  • Dynamics of $CH_2CI$ group in ${\alpha},2,6$-trichlorotoluene dissolved in $CDCl_3$ was studied by observing various relaxation modes for $^{13}C$ under proton undecoupled condition. Partially relaxed $^{13}C$ spectra were obtained at $34^{\circ}C$ as a function of evolution time after applying various designed pulse sequences to this $AX_2$ spin system. It was found that nonlinear regression analysis of the relaxation data for these magnetization modes could provide the information about dipolar and spin-rotational auto-correlation and cross-correlation spectral densities for fluctuation of the $^{13}C-^1H$ internuclear vector in $CH_2Cl$ group. The results show that the effect of cross-correlation is comparable in magnitude to that of auto-correlation and the relaxation in this spin system is dominated by dipolar mechanism rather than spin-rotational one. From the resulting spectral density data we could calculate the bond angle ${\angle}HCH\;(105.1$^{\circ}$) and elements of the rotational diffusion tensor for $CH_2Cl$ group.

반경방향 착자형과 Halbach 배열형 영구자석 회전자를 갖는 고속 슬롯리스 기기의 공극자속밀도 특성 비교 (Comparison on the Airgap Flux Density of High-Speed Slotless Machines with Radial Magnetization and Halbach Array PM Rotor)

  • 장석명;정상섭;류동완
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제50권7호
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    • pp.315-322
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    • 2001
  • High speed brushless permanent magnet(PM) machines need a key technology to minimize the iron core losses in stator and the eddy current losses in the retained sleeve and magnets caused by slotting harmonics. Thus, slotless or iron-coreless brushless PM machines have been applied for a very high rotational speed and/or the ripple-free torque. Unfortunately, slotless or coreless PM machines have lower open-circuit field than slotted and/or iron-cored types, which cause to reduce power density. Fortunately, Halbach array can generate the strong magnetic field systems without additional magnetic materials. In this paper, the 4-pole Halbach array is applied to the high speed machine and is compared with the radial magnetized PM array in field system. The iron-/air-cored stator of PM machine is constructed with/without winding slots. Open circuit magnetic fields of each type are presented from the analytical method and finite element method. Consequently, it is confirmed that the Halbach array field system with slotless stator is more suitable to the high speed motor because it has high flux density, sinusoidal flux distribution than others.

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초 연자성 박막에서의 동적 자화 거동 (Dynamic Responses in Ultra-Soft Magnetic Thin Films)

  • 정인섭
    • 한국자기학회지
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    • 제4권1호
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    • pp.1-6
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    • 1994
  • 본 연구에서는 초 연자성(ultra-soft magnetic) 비정질 박막에서 관찰되는 감쇄가 큰(overdamped) 고주파 자기특성의 원인을 이해함으로써 자기 스핀의 동적 자화거동을 확인하고자한다. 고주파에서의 자화율(susceptibility) 특성곡선에 대한 실험결과와 Gilbert의 운동방정식으로 부터의 계산 결과를 비교하여 초 연자성 박막의 겨우 $\alpha=20$ 정도의 큰 감쇄상수와 무시할 정도로 작은 $D_{x}{\approx}D_{y}{\approx}D_{z}{\approx}0$의 반자장 계수를 구하였다. 이 결과로 부터 불균일 박막의 자화율 특성곡선과 자기 스핀의 동적 자화거동을 설 명하기 위해 vortex 형상의 자화분포를 제안하였다. Vortex형 자화분포는 초 연자성 박막 내의 미세한 자성입자들에서의 안정된 스핀 분포로 형성되며, vortex의 불균일한 스핀운동은 스핀파로 부터의 에너지와 박막내 결함구조와의 상호작용에 의해 큰 감쇄를 갖는 것으로 설명되었다.

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평행방향/할박 자화 영구자석을 갖는 마그네틱 기어의 설계변수에 따른 토크특성 해석 및 비교 (Comparison and Torque Analysis for Magnetic Gear with Parallel/Halbach Magnetized PMs according to Design Parameters)

  • 홍상아;최장영
    • 한국자기학회지
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    • 제24권5호
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    • pp.152-159
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    • 2014
  • 마그네틱 기어는 두 개 이상의 분리된 장치들 사이에서 기계적인 접촉 없이 토크를 전송한다. 특히, 희토류계 영구자석을 사용한 마그네틱 기어는 고 출력으로 인해 다양한 산업에 적용된다. 따라서 마그네틱 기어는 일반적인 기어를 대체할 수 있다. 본 논문에서는 이차원 유한요소해석을 이용해 평행방향과 할박 자화 마그네틱 기어의 기어비를 선정하고, 내측과 외측 영구자석 두께, 철심 각도, 할박 세그먼트 개수, 내측과 외측 영구자석 자화 패턴과 같은 설계 변수에 따라 토크 해석을 수행하였다. 해석 결과, 개선된 설계변수를 갖는 모델이 초기 설계 모델과 비교해 더 높은 토크를 가짐을 확인하였다.

$Co_{89}Nb{8.5}Zr{2.5}$ 비정질 박막의 이방성에 미치는 열처리 효과 (Effect of Annealing on the Magnetic Anisotropy of Amorphous $Co_{89}Nb{8.5}Zr{2.5}$Thin Films)

  • 김현식;민복기;송재성;오영우
    • 한국전기전자재료학회논문지
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    • 제11권6호
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    • pp.486-492
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    • 1998
  • The amorphous Co-based magnetic films have a large saturation flux density, a low coercive force, and a zero magnetostriction constant. Therefore, they have been studied for application to magnetic recoding heads and micro magnetic devices. However, it was found that the magnetic anisotropy was changed for each film fabrication processes. In this study, we investigated how to control the anisotropy of sputtered amorphous $Co_{89}Nb{8.5}Zr{2.5}$ films. After deposition, the rotational field annealing ant the uniaxial field annealing were performed under the magnetic field of 1.5 kOe. the annealing was done at the temperature range from 400 to $600^{\circ}C$ for one hour. As-deposited amorphous $Co_{89}Nb{8.5}Zr{2.5}$ thin film had saturation magnetization ($4\piM_5$) of 0.8 T, coercive force($_IH_C$) of 1.5 Oe, and anisotropy field($H_k$) of 11 Oe. The amorphous $Co_{89}Nb{8.5}Zr{2.5}$ thin films annealed by rotational field annealing at $500^{\circ}C$ for one hour was found to be isotropy, and $4\piM_5$ of 0.9 T was obtained from these films, Also, the magnetic anisotropy of as-deposited films could be controlled by uniaxial field annealing at $400^{\circ}C$ for one hour. Anisotropy field($H_k$) of 17 Oe and $4\piM_5$ of 1.0 T were obtained by this method.

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플라이휠 에너지 저장 시스템용 양측식 영구자석 동기 전동/발전기의 착자 형태에 따른 특성 비교 (Characteristic comparison of double-side PMSM/G according to magnetization pattern for flywheel energy storage system)

  • 장석명;최지환;유대준;성소영;한상철;이정필
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1021-1022
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    • 2011
  • This paper presents the double side PM synchronous motor/generator for core loss reduction in flywheel energy storage system. The use of double PM rotor causes the elimination of core loss in no-load state of machine. Because flywheel rotational speed is reduced by core loss, double PM rotor is very effective in flywheel system. This paper suggests two types of double side PM rotor, Halbach magnetized array and parallel magnetized array. And characteristic comparison according to thickness of rotor back core is performed.

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Analysis of the Thickness Effect for Hysteresis Ring of Hysteresis Motor with Vector Hysteresis Model

  • Hong, Sun-Ki
    • 조명전기설비학회논문지
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    • 제20권9호
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    • pp.84-89
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    • 2006
  • This paper presents the thickness effect of hysteresis ring of hysteresis motor using finite element method combined with a vector hysteresis model. From the magnitude and direction of the magnetic field intensity, the magnetization of each ring element is calculated by a vector hysteresis model. The developed torque can be obtained with the vector sum of individual torque of each element on the hysteresis ring. From these calculations, it can be found that the motor torque is not in proportion to the thickness of the ring. As a result, there exists a proper point of thickness and that can be determined using the proposed methoㅇ in this paper.

Annealing Effect of Local Anisotropy Field in Amorphous Co66Fe4Ni1B14Si15 Ribbon

  • Kim, C.G.;Jeong, M.H.;Jeong, M.H.;Yoon, S.S.;Yu, S.C.
    • Journal of Magnetics
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    • 제3권4호
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    • pp.123-126
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    • 1998
  • The magneto-impedance (MI) has been measured in the annealed Co66Fe4Ni1B14Si15 amorphous ribbon for the evaluation of anisotropy field. MI at the frequency of 10 MHz is related to the transverse permeability from rotational magnetization depending on the local anisotropy field. MI varies sensitively with the annealing temperature, reflecting the change of anisotropy field distribution. The local anisotropy fields evaluated from MI Profiles are discussed in terms of the magnetic softness and microstructural change by the annealing.

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