• Title/Summary/Keyword: rosin

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Studies on the Physical Properties of Molded Packaging Material Using Rice-Straw Pulp (볏짚펄프를 이용한 성형포장재의 물성에 관한 연구)

  • Oh, Seung-Won;Kang, Chin-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.1
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    • pp.79-87
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    • 1999
  • To use the agricultural residues as the raw material of molded packaging material, the packaging trays were manufactured from rice-straw pulp. The physical properties were measured to compare non-treated trays with the addition trays, such as the addition of starch, rosin size, carboxymethyl cellulose(CMC), polyethylene glycol(PEG), alkylketene dimer(AKD), polyacryl amide(PAM). The results were as follows : 1. In the addition of starch, air permeability at addition of 5% was highest. Bursting strength and tensile strength were smaller than non-treated trays. 2. In the addition of rosin size, air permeability, bursting strength and tensile strength were smaller than non-treated trays. 3. In the addition of CMC, air permeability was higher than non-treated trays. Bursting strength and tensile strength were similar to non-treated trays. 4. In the addition of PEG, air permeability was higher than non-treated trays. Bursting strength at addition of 3% was the highest and tensile strength was smaller than non-treated trays. 5. In the addition of AKD, air permeability at addition of 1% and 5% was higher than non-treated trays. Bursting strength and tensile strength were smaller than non-treated trays. 6. In the addition of PAM, air permeability at addition of 0.01% was the highest. Tensile strength at addition of 0.01% were higher than non-treated trays. 7. The water absorption of the trays decreased with increasing adding of natural additives.

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The Effect of Solvents on the Synthesis of Polyamideimides from Rosin-Maleic Anhydride Adduct and Diisocyanate (로진-말레산 부가물과 디이소시아네이트로부터 폴리아미드이미드의 합성시 용제의 효과)

  • Kim, Jum-Sik;Choi, Byung-Oh;Choi, Hyeong-Ki
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.73-82
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    • 1990
  • Rosin-maleic anhydride adduct (RMA) was synthesized from rosin and maleic anhydride. The polyamideimides were obtained by reacting the adduct with two aromatic diisocyanates using sodium methoxide as catalyst. The yield and the inherent viscosity of polymers obtained by the reaction in NMP solvent were low because of the possible reaction of NMP solvent with diisocyanate monomer. The polymers were synthesized in solvent mixture of NMP and cosolvents such as xylene, acetophenone, benzonitrile, and nitrobenzene in order to minimize the side reaction of NMP with diisocyanates. The yield of polymer obtained by the reaction in NMP-nonpolar cosolvent mixtures was about 70% and that obtained by the reaction in NMP-polar cosolvent mixtures was over 90%, respectively. The polymers were either amorphous or poorly cystalline, and soluble only in highly polar solvents. The inherent viscosity of polymers ranges from 0.12-0.26dl/g. The results of thermal analysis showed that the polymer had good thermal stability with initial decomposition temperature over $330^{\circ}C$.

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A Study on the Calculation Formulae for the Required Air and Combustion Gas of the Domestic Anthracites (국산무연탄의 소유공기량과 발생연소가스량의 산식에 관한 연구)

  • 이우환
    • Journal of Advanced Marine Engineering and Technology
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    • v.5 no.1
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    • pp.28-33
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    • 1981
  • The characteristics of typical 35 kinds of domestic anthracites among 155 kinds are studied to find the calculation formula for the required quantity of air and the combustion gas quantity. 1) The author's calculation formulae are as follows: ${A_0}={\frac{1, 000}{1, 064}}{H_1}+0.086(Nm^3/kg)$ ${G_0}={\frac{1, 000}{1, 110}}{H_1}+0.234(Nm^3/kg)$(1) Theoretically required quantity of air (2) Theoretical quantity of combustion gas 2) Theoretical quantity of air in combustion of domestic anthracite is always estimated more with Rosin's formula than author's one in the typical domestic anthracites which have the lower calorific value between 3, 000-8, 000 Kcal/kg and the difference of the calculated quantity of air becomes small, as the calorific value increases. 3) Theoretical quantity of combustion gas is estimated more by author's formula than by Rosin's one with the domestic anthracites which have more calorific value than 6, 700 Kcal/kg and is estimated less in the under range of the above calorific value. 4) Theoretical quantity of required air and quantity of combustion gas of domestic anthracite show ${\pm}$4% difference by Rosin's formulae in comparison with results of actual analysis, and about ${\pm}$1.5% by the author's one.

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A Study on the Color Reproduction of Halftone Image by used Factor N and Process Ink Characteristics (Factor N와 잉크특성을 고려한 망점화상의 색재현예측에 관한 연구)

  • 김성근
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.13-27
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printablility of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular weight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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The Rheological Properties of Printing Ink and its printability with the Molecular Weight of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 인쇄 잉크의 유변학적 특성과 인쇄적성에 관한 연구)

  • Lee, Kyu-Il;Kim, Sung-Bin
    • Proceedings of the Korean Printing Society Conference
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    • 2007.11a
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    • pp.1-12
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    • 2007
  • The rheological properties of an ink relate to its performance on the press and to the printing quality. So it is necessary to analyze the relationship between printability and the rheological properties of ink. Transfer rate of ink is one of the important factor deciding print quality. And it is concerned with rheological properties of ink. Thus, in this study, according to the molecular weight of rosin modified phenolic resin the rheological properties of ink were measured by rotational rheometer and then transfer equation of ink, density and gloss were mesured in order to examine the printability of ink.

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Rheology of Emulsified Ink and Printability With Different Molecular Weights of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 유화 평형잉크의 유변학적 특성과 인쇄적성)

  • Lee, Kyu-Il;Kim, Tae-Hwan;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.1
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    • pp.1-16
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    • 2008
  • The rheological properties of emulsified ink must be maintained adequately at various shear rates or shear stress. So it is necessary to understand its rheological properties in order to regulate the printability of eumulsified ink on the performance. In this study, the rheological properities and printability of emulsified ink are investigated according to the molecular weights of rosin-modified phenolic resin.

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Renewable Monomer Based on Rosin in Photoinitiated Radical Polymerization

  • Shim, Sang-Yeon;Hong, Young-Taik
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.192-197
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    • 2000
  • Rosin moeity-containing monomer was prepared by the reaction of abietic acid with 2-hydroxyethyl methacrylate in tetrahydrofuran(THF) using diethyl azodicarboxylate as a catalyst. This new monomer was photo-polymerized to give thin films in the presence of a radical type initiator. The rate of photo-polymerization and amount of cured polymer were determined using the residual yield method. A thermogravimetric analysis of the cured polymer showed that the film was stable up to 170oC, at which point the polymer film has lost 10 wt % of its weight.

A Study on the Calculation Formulae of Required Air and Burning Gas Amount of Heavy Fuel Oil (중유의 연소에 필요한 소요공기량과 발생가스량의 산식에 관한 연구)

  • 이우환
    • Journal of Advanced Marine Engineering and Technology
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    • v.6 no.1
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    • pp.34-40
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    • 1982
  • The characteristics of typical 17 kinds of fuel oils are studied to fine the calculation formulae for the required amount of air and the combustion gas amount. 1) The author's calculation formulae are as follows; (1) Theoretically required amount of air (2) Theoretical amount of combustion gas 2) Theoretical amount of the required air in combustion and combustion gas of fuel oils are always estimated less with Rosin's formula than with author's one. 3) Theoretical amount of the required air and the amount of combustion gas of fuel oils are more reasonable with author's formula than Rosin's one in comparison with results of actual analysis.

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The Rheological Properties of Printing Ink and its printability with the Molecular Weight of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 인쇄 잉크의 유변학적 특성과 인쇄적성에 관한 연구)

  • Lee, Kyu-Il;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.25 no.2
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    • pp.1-13
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    • 2007
  • The rheological properties of an ink relate to its performance on the press and to the printing quality. So it is necessary to analyze the relationship between printability and the rheological properties of ink. Transfer rate of ink is one of the important factor deciding print quality. And it is concerned with rheological properties of ink. Thus, in this study, according to the molecular weight of rosin modified phenolic resin the rheological properties of ink were measured by rotational rheometer and then transfer equation of ink, density and gloss were measured in order to examine the printability of ink.

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A Study on the Physical Properties according to Varnish Cooking Conditions of Phenolic Modified Rosin Ester (로진변성 페놀수지의 Varnish 제조조건에 따른 물성 변화에 관한 연구)

  • Jung, Soon-Kie;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.24 no.2
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    • pp.11-24
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    • 2006
  • The Lithographic ink is composed of pigment, vehicle and additives. In especially, the vehicle is the most important element and consist of vegetable oils, mineral oils and resins. Varnishes have to resist certain forms of chemical and physical attack during ink manufacturing process and printing process So this varnish cooking is very important. In this paper, effects of cooking conditions of varnish using phenolic modified rosin ester on physical properties of the vehicle were studied. The varnish cooked according to temperature and time were compared in order of average molecular weight by the GPC method. and the rheological properties were found by rotational rheometer. And the emulsion behavior were compared by high speed emulsification tester which were set on 1200 rpm and $40^{\circ}C$ temperature (Novomatics Lithotronic). We displayed viscosity against tack(Inkometer Thwing-Albert M-106) by diagram.

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