• Title/Summary/Keyword: rods

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A Study of Photoelectrolysis of Water by Use of Titanium Oxide Films (산화티타늄 피막의 광 전기분해 특성에 관한 연구)

  • Park, Seong-Young;Cho, Byung-Won;Ju, Jeh-Beck;Yun, Kyung-Suk;Lee, Eung-Cho
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.88-99
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    • 1992
  • For the development of semiconducting photoelectrode to be more stable and efficient in the process of photoelectrolysis of the water, pure titanium rods were oxidized by anodic oxidation, furance oxidation and flame oxidation and used as electrodes. The Indium islands were formed by electrodeposition of "In" thin film on $TiO_2$ and Ti by electrodeposition. Also $A1_2O_3$ and NiO islands were coated on Ti by the electron-beam evaporation technique. The maximum photoelectrochemical conversion efficiency(${\eta}$) was 0.98% for flame oxidized electrode($1200^{\circ}C$ for 2min in air). Anodically oxidized electrodes have photoelectrochemical conversion efficiency of 0.14%. Furnace oxidized electrode($800^{\circ}C$ for 10min in air) has 0.57% of photoelectrochemical efficiency and shows a band-gap energy of about 2.9eV. The $In_2O_3$ coated $TiO_2$ exhibits 0.8% of photoelectrochemical efficiency but much higher value of ${\eta}$ was obtained with the Increase of applied blas voltage. However, $Al_2O_3$ or NiO coated $TiO_2$ shows much low value of ${\eta}$. The efficiency was dependent on the presence of the metallic interstitial compound $TiO_{0+x}$(x<0.33) at the metal-semiconductor interface and the thickness of the suboxide layer and the external rutile scale.

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A Preliminary Study on Measuring Void Fraction in a Fuel Rod Assembly by using an X-ray Imaging System (X선 영상 장치를 이용한 핵연료 집합체 내 기포율 측정을 위한 선행 연구)

  • Lee, Sun-Young;Oh, Oh-Sung;Lee, Se-Ho;Lee, Seung-Wook
    • Journal of the Korean Society of Radiology
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    • v.11 no.7
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    • pp.571-578
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    • 2017
  • Bubbles are generated by the boiling of the cooling water when an accident occurs in the reactor and then in order to measure the void fraction, the Optical Fiber Probe(OFP) and optical camera are used in thermal hydraulic safety research. However, such an optical method is not suitable for measuring the void fraction in a $17{\times}17$ array of fuel rods due to the geometrical limitations. This study was conducted as a preliminary study using x-ray system and various phantoms before applying to rod bundles. Through radiographic and tomographic experiments, the tube voltage of the x-ray generator was 130 kVp and the tube current was 1 mA. In addition, it is possible to measure the hole of 1mm in size visually through the bubble resolution phantom, and it is confirmed that the contrast is relatively decreased in the inside of the freon in the case of the contrast evaluation using the road phantom. However, we could obtain good image without distortion when reconstructing the image. Bubble generation phantom experiments were used to confirm the flow direction of the bubbles and to acquire tomography images. The image J tool was used to measure the void fraction of 18 % for a single tomography image. This study has carried out previous researches for the measurement of the bubble rate around the nuclear fuel and could be used as a basic research for continuous research.

A Study on the Pile Behaviour Adjacent to Tunnel Using Photo Imaging Process and Numerical Analysis (Photo Imaging Process 기법 및 수치해석을 이용한 터널주변 파일기초거동에 대한 연구)

  • Lee Yong-Joo
    • Journal of the Korean Geotechnical Society
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    • v.21 no.9
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    • pp.87-102
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    • 2005
  • In the congested urban areas, tunnelling close to existing structures or services often occurs due to the lack of surface space so that tunnelling-induced ground movements may cause a serious damage to the adjacent structures. This study focused on the two dimensional laboratory model pile-soil-tunnelling interaction tests using a close range photogrammetric technique. Testing equipments and procedures were Introduced, particularly features of aluminium rods regarded as the frictional granular material. The experimental result showed that the photo imaging process by the VMS and EngVis programs proved to be a useful tool in measuring the pile tip movements during the tunnelling. Consequently, the normalised pile tip movement data for the influence zones can be generated by the laboratory model tests using the Photogrammetric technique. This study presents influence zones associated with the normalized pile tip settlements due to tunnelling in the cohesionless material. The influence zones were Identified by both a laboratory model test and a numerical analysis. The normalized pile tip movements from the model test were in good agreement with the numerical analysis result. The influence zones proposed in this study could be used to decide the reasonable location of tunnel construction in the planning stage. However, the scale of model pile and model tunnel sizes must be carefully adjusted as real ones for practical application considering the ground conditions at a given site.

INFLUENCE OF COOLING RATE ON THERMAL EXPANSION BEHAVIOR AND FLEXURAL FAILURE OF PFM SYSTEMS (도재 냉각방법의 차이가 금속-도재간 열팽창 양상과 결합력에 미치는 영향)

  • Lim, Ae-Ran;Lim, Ho-Nam;Park, Nam-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.28 no.1
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    • pp.165-191
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    • 1990
  • Although a number of studies have been performed to assure that residual stress caused by a mismatch of alloy porcelain thermal expansion can contribute to clinical failure of a ceramometal restoration, the interactive influence of cooling rate on the magnitude of thermal expansion difference and on bond strength between them have not been extensively analyzed. The objective of this study was to determine the influence of cooling rate and the number of firing cycles on the expansion mismatch and the flexural failure resistance of metal porcelain strip. Tested alloys included one Pd-Ag alloy, one Ni-Cr-Be alloy with two kinds of porcelain, Vita and Ceramco. Metal specimens were cast into rods with a height of 13mm and a diameter of 5mm. Subsequently, the castings were subjected to scheduled firing cycles without porcelain. And the porcelain specimens after being fired were trimmed into a bar with a final dimension of $5{\times}5{\times}25mm$. Thermal expansions of the alloys and porcelains were measured by using a push rod or a differential dialometer respecitvely. Porcelain glass transition temperatures and expansion values were derived alloy-porcelain pairs were assessed by comparing expansion values of the components at a porcelain glass transition temperature. Calculations were made using combinations of a Ni-Cr alloy or Pd-Ag alloy with each of two porcelain products. Metal-porcelain strip specimens were subjected to four point loading in an Instron testing machine until crack occured at the metal-cramic interface at the time of sharp decrease of load on recorder. On the basis of this study, the following conclusions may be stated: 1. Regardless of the kinds of ceramometal combinations, both of calculated and experimental data revealed that the double fired specimens exhibited a significantly lower flexural strength. 2. By the rise of the amount of mismatch, bond strength were decreased. 3. Thermal expansion value of Pd-Ag alloys were higher than that of Ni-Cr alloys. 4. Expansion curves of metal were proportional to the increase of temperature and were not affected by the experimental conditions, however porcelains did not show the same magnitude of metal, and a shift of the glass transition temperature to higher temperatures was observed when cooled rapidly 5. Alloy-porcelain thermal compatibility appeared more dependent on the porcelain than the alloy.

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Passive autocatalytic recombiner guide structure considering ambient flow (분위기 유동을 고려한 PAR 가이드 구조에 관한 연구)

  • Ryu, Myeong-Rok;Park, Kweon-Ha
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.4
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    • pp.302-309
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    • 2017
  • If a hydrogen explosion occurs in a containment building, its multiplex defense wall may be destroyed and a large amount of radioactive material may be released. The hydrogen occurred interacting with melting fuel rods must be effectively controlled and removed. however, the countermeasures for reducing explosion risk are difficult to carry out, due owing to the various variety of accident scenarios causes and the irregularity of hydrogen distribution and behavior. In this study, We examine the guide structures while considering the ambient flows, in order to improve the efficiency of PAR the widely used Passive Autocatalytic Recombiner(PAR). We simulate the fluid behavior and the hydrogen reduction rate were simulated when a guide is attached to the two-step catalyst PAR. For an upward flow, the consisting of a height of 150mm, a gap of 0mm, and a performs $60^{\circ}$ showed the best. In contrast, for a sideways flow, a consisting of the height of 150mm, a gap of 100mm, and a performs $60^{\circ}$ showed the best in the case of side ward flow. for a downward flow, a consisting of the height of 50mm and a directly attached guide produce the best in the case of down ward flow results.

A Study on the Development of a Non-supporting Form for Basement Wall and the Analysis on Its Economical Efficiency (지하옹벽 무지주 거푸집 개발 및 경제성 분석에 관한 연구)

  • Kim, Jae-Yeob;Lee, Sang-Woo;Sohn, Young-Jin;Kim, Gwang-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.6
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    • pp.161-168
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    • 2009
  • In an architectural construction, underground construction is a critical path forming a major part of the total construction period and cost, and particularly in big cities, its size has been increasing every year. A basement wall currently constructed in the field needs a large functional work force, and the construction is under progress by the Euroform and Soldier system, which is disadvantageous in terms of the construction period. Therefore, in this research, non-supporting forms which are applicable to the buildings construction were developed, based on the non-supporting forms partly used in some civil engineering works. In addition, the size of a form was assumed and its economical efficiency was compared to that of the Euroform and Soldier system which is used most in construction fields, and the results were analyzed. The study results showed that the construction cost of composite non-supporting forms was higher than that of the Euroform and Soldier system by about 8%, and the construction cost of non-composite non-supporting forms were lower than that of the Euroform and Soldier system by about 9%. However, in the case of composite non-supporting forms, the amount of concrete and reinforcing rods remarkably decreased in structural construction, so it has the effect of an economical cost reduction compared to the construction cost of existing walls by about 35%

Derivation of Optimum Operating Conditions for Electrical Resistance Heating to Enhance the Flushing Effect of Heavy Oil Contaminated Soil (중질유 오염토양의 세정효과를 증진시키기 위한 전기저항가열의 최적 운전조건 도출)

  • Lee, Hwan;Jung, Jaeyun;Kang, Doore;Lee, Cheolhyo
    • Journal of Environmental Impact Assessment
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    • v.29 no.3
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    • pp.219-229
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    • 2020
  • This study evaluated the applicability of the convergence technology by deriving the optimum conditions about operating factors of electrical resistance heating to enhance the soil flushing effect on soil contaminated with bunker C oil in the coastal landfill area. As a result of the batch scale experiment, the flushing efficiency of the VG-2020 was higherthan that of the Tween-80, and the flushing efficiency increased by about 1.4 times at 60℃ compared to room temperature. As a result of the electrical resistance heating box experiment, soil temperature rose to 100℃ in about 40~80 minutes in soil with water content of 20~40%, and it was found that the heat transfer efficiency is excellent when the pipe-shaped electrode rod with STS 316 material is located in a triangular arrangement in saturated soil. In addition, it was confirmed that the interval between the electrode rods to maintain the soil temperature above 60℃ under the optimum conditions was 1.5 m, and the soil flushing box experiment accompanying electrical resistance heating showed TPH reduction efficiency of about 55% at 5 Pore Volume, and satisfied the Korean standard for the conservation of soil (less than TPH 2,000 mg/kg) at 10 Pore Volume.

Evaluation of Fermentation Ability of Microbes for Corn Silage Inoculant (옥수수 사일리지용 미생물의 발효능력 평가)

  • Kim, Jong-Geun;Ham, Jun-Sang;Chung, Eui-Soo;Seo, Sung;Park, Hyung-Soo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.30 no.4
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    • pp.333-342
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    • 2010
  • Corn is very important forage in Korea. The great part of them is utilized as silage. Generally, it contains a lot of grains that is feed of animal. This experiment was conducted to evaluation of fermentation ability of microbes for corn silage inoculant. Good lactic acid bacteria were isolated from good corn silage by plating MRS agar containing 0.02% sodium azide, and assessed by growing and acid producing ability in MRS broth. Six lactic acid bacteria were selected, and were found to be Gram positive, rods and catalase negative and were identified to be lactobacillus plantarum (C3-2, B13-1, CC9-1), Lactobacillus fermentum (C11-4), Lactobacillus paracasei (B14-1), and Leuconostoc lactis (A3-1) on the basis of the biochemical characteristics and utilization of substrates. Corn was ensiled at ripen stage following treatment with selected five lactic acid bacteria, two commercial inoculant, and no additive (control). After 2 month, B13-1 and CC9-1 bacteria inoculated silage were lower pH and higher lactic acid content than others treatments. The Flieg's score and grade of B13-1 and CC9-1 bacteria treated silage were higher than commercial inoculant. According to this experiment, lactobacillus plantarum B13-1 and CC9-1 strain were recommendable for good inoculant of corn silage.

Physiological and Ecological Characteristis of Hemolytic Vibrios and Development of Sanitary Countermeasure of Raw Fisheries Foods. 2. Physiological and Psychrotrophic Characteristics of Vibrio mimicus SM-9 Isolated from sea Water (용혈독소를 생산하는 기수성 비브리오균의 생리.생태적 특성과 수산식품의 위생대책 2. 해수에서 분리된 vibrio mimicus SM-9의 생리적 특성 및 저온내성)

  • 장동석;김신명;박욱연;박미연;김영만
    • Journal of Food Hygiene and Safety
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    • v.12 no.1
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    • pp.9-14
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    • 1997
  • Vibrio mimicus is a closely related species with V. cholerae, and has been reported to be associated with gastrointestinal infections. Although extraintestinal infections of these vibrios have also been reported in Japan and Southeast Asia. But little research papers on V. mimicus was reported in Korea. Therefore, we tried to isolate V. mimicus from the environmental sea water from April to July in Pusan, Korea. Among the isolated strains, we selected the strongest hemolytic strain and then named V. mimicus SM-9. In this paper, we checked the antibiotic susceptibility and psychrotrophic characteristics of the isolated strain. Hemolytic activity of the hemolysin produced by the isolated strain was also measured. V. mimicus was not detected from the sea water samples in April and May, but its detection rate was relatively high in June and July in Pusan, Korea. The bacteriological characteristics of V. mimicus SM-9 were Gram-negative rods, motile, oxidase positive, Voges-Proskauer negative and sucrose negative. In 23 kinds of antibiotics susceptibility test, V. mimicus SM-9 showed susceptibility to the most of antibiotics submitted while it was resistive against lincomycin, oxacillin, rifampin and vancomycin. Hemolytic activity of the hemolysin produced by V. mimicus SM-9 was highest in stationary phase of the growth curve in BHI broth at 37$^{\circ}C$ and its activity was reached 18 HU per $m\ell$ of culture supernatant. For checking the psychrotrophic property of V. mimicus SM-9, the decreasing rate of the strain in phosphate buffer solution and yellowtail flesh homogenate was examined during the storage at 4, 0, -4 and -2$0^{\circ}C$. The decreasing rates of the selected strain stored in phosphate buffer solution were greater than those in fish homogenate. Decreasing rates of V. mimicus SM-9 stored in phosphate buffer solution were not significantly different by the storage temperatures. The viable cell counts of the strain were decreased as 5 log cycles after 120 hours at all the tested temperatures. While decreasing numbers of the strain in fish homogenates were 2*4 log cycles after 120 hours. The decreasing pattern of the strain numbers were very slow after 200 hours at all the stored temperatures.

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Comparative analysis of two methods of laser induced boron isotopes separation

  • K.A., Lyakhov;Lee, H.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.407-408
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    • 2011
  • Natural boron consists of two stable isotopes 10B and 11B with natural abundance of 18.8 atom percent of 10B and 81.2 atom percent of 11B. The thermal neutron absorption cross-section for 10B and 11B are 3837 barn and 0.005 barn respectively. 10B enriched specific compounds are used for control rods and as a reactor coolant additives. In this work 2 methods for boron enrichment were analysed: 1) Gas irradiation in static conditions. Dissociation occurs due to multiphoton absorption by specific isotopes in appropriately tuned laser field. IR shifted laser pulses are usually used in combination with increasing the laser intensity also improves selectivity up to some degree. In order to prevent recombination of dissociated molecules BCl3 is mixed with H2S 2) SILARC method. Advantages of this method: a) Gas cooling is helpful to split and shrink boron isotopes absorption bands. In order to achieve better selectivity BCl3 gas has to be substantially rarefied (~0.01%-5%) in mixture with carrier gas. b) Laser intensity is lower than in the first method. Some preliminary calculations of dissociation and recombination with carrier gas molecules energetics for both methods will be demonstrated Boron separation in SILARC method can be represented as multistage process: 1) Mixture of BCl3 with carrier gas is putted in reservoir 2) Gas overcooling due to expansion through Laval nozzle 3) IR multiphoton absorption by gas irradiated by specifically tuned laser field with subsequent gradual gas condensation in outlet chamber It is planned to develop software which includes these stages. This software will rely on the following available software based on quantum molecular dynamics in external quantized field: 1) WavePacket: Each particle is treated semiclassicaly based on Wigner transform method 2) Turbomole: It is based on local density methods like density of functional methods (DFT) and its improvement- coupled clusters approach (CC) to take into account quantum correlation. These models will be used to extract information concerning kinetic coefficients, and their dependence on applied external field. Information on radiative corrections to equation of state induced by laser field which take into account possible phase transition (or crossover?) can be also revealed. This mixed phase equation of state with quantum corrections will be further used in hydrodynamical simulations. Moreover results of these hydrodynamical simulations can be compared with results of CFD calculations. The first reasonable question to ask before starting the CFD simulations is whether turbulent effects are significant or not, and how to model turbulence? The questions of laser beam parameters and outlet chamber geometry which are most optimal to make all gas volume irradiated is also discussed. Relationship between enrichment factor and stagnation pressure and temperature based on experimental data is also reported.

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