• Composites Research
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• 제22권4호
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• pp.33-40
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• 2009

유리섬유/에폭시 복합재료로 피막한 판유리의 표변파괴거동에 대한 섬유방향효과를 미소강구 충격실험을 통해 연구했다. 본 연구에서는 단순소다유리판(soda-lime glass plates), 일방향 유리섬유/에폭시박막 (glass/epoxy lamina ply)을 1층 및 2층 접착, 직교형 유리섬유/에폭시 박막 (2층)을 접착한 4종류의 시편을 사용하였다. 유리판 배면에 스트레인게이지를 부착하여 충격중의 최대 응력과 흡수파괴에너지를 측정하였다. 피막없는 판유리의 경우 충격속도 증가에 따라 링균열, 콘균열, 레이디얼 균열이 충격표면부에서 발생하였다. 복합재료 박막으로 피막한 결과, 소다유리판의 균열은 현저히 감소하였으며 섬유층과 판유리사이의 박리 및 소성변형영역의 방향은 섬유방향으로 진행했다. 최대응력과 흡수파괴에너지를 이용하여 구한 충격 표면파괴지수는 표면저항의 효과적인 평가지수로서 사용될 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.815-818
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• 2010

Free base meso-tetraarylporphyrins ($H_2T(X)PP$) react with tellurium(IV) chloride ($TeCl_4$) in mild conditions for formation sandwich intermediate sitting-atop (i-SAT) complexes, [$TeCl_4(H_2T(X)PP)_2$]. $^1H$ NMR, $^{13}C$ NMR, UV-vis, FT-IR and elemental analysis were used for characterization of the products. In the proposed structure of the i-SAT complexes, four pyrroles of each porphyrin ring are tilted alternatively up and down and this appropriates suitable orientation of lone pairs of two pyrrolenine nitrogens for electron donation to a tellurium center. $^1H$ NMR and FT-IR results showed that in the produced complex, hydrogen atoms of porphyrin macrocycles remained on the pyrrole nitrogens.

• 대한화학회지
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• 제29권3호
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• pp.213-219
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• 1985

고정된 사이크로 프로판환을 가진 양이온계에서 구조적 변화에 따른 상대적 안정도를 불소 19-핵자기공명분광기로 분석 검토했다. 이를 위해 8-파라-불화벤젠트리사이크로 옥탄 양이온과 9-파라불화벤젠 트리사이크로 노난 및 10-파라불화벤젠 트리사이크로데칸 양이온을 해당알코올과 불화황산과의 반응에서 얻었다. 풀루오르 19-NMR 스펙트럼에서 얻어진 결론은 사이크로프로판환이 양이온 탄소의 궤도와 ${\sigma}$ 컨쥬게이션을 위해 대칭적이며 바이섹트 구조의 유지가 하전의 안정화에 매우 중요한 요인인 반면, 사이크로 프로판기의 면과 양하전을 띈 탄소와 연결되는 결합각도(${\theta}$)의 변화는 하전의 안정화에 영향이 없음을 보여주었다.

• Smart Structures and Systems
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• 제30권3호
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• pp.327-332
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• 2022

In building envelope, transparent components play an important role. The structural glazing systems are the weak element of the casing in terms of mechanical resistance, thermal and acoustic insulation. In the present work, new structural glass panels with granular aerogel in interspace were investigated from different points of view. In particular, the mechanical characterization was carried out in order to assess the resistance to bending of the single glazing pane. To this end, a special instrument system was built to define an alternative configuration of the coaxial double ring test, able to predict the fracture strength of glass large samples (400 × 400 mm) without overpressure. The thermal and lighting performance of an innovative double-glazing façade with granular aerogel was evaluated. An experimental campaign at pilot scale was developed: it is composed of two boxes of about 1.60 × 2 m² and 2 m high together with an external weather station. The rooms, identical in terms of size, construction materials, and orientation, are equipped with a two-wing window in the south wall surface: the first one has a standard glazing solution (double glazing with air in interspace), the second room is equipped with the innovative double-glazing system with aerogel. The indoor mean air temperature and the surface temperature of the glass panes were monitored together with the illuminance data for the lighting characterization. Finally, a brief energy characterization of the performance of the material was carried out by means of dynamic simulation models when the proposed solution is applied to real case studies.

• 한국산업융합학회 논문집
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• 제1권1호
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• pp.43-49
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• 1998

The SS-phpm 4HCl(N,N'-bis-[2(S)-pyrrolidinylmethyl]phenylene-l,2-diamine-4-Hydrochloride) ligand having stereospecificity has been prepared and reacted with trans-[$Co(pyridine)_4Cl_2]$Cl. The resultants are purple crystals, which are identified to be ${\Delta}$-cis-${\beta}$-[$Co(SS-phpm)Cl_2$]Cl by elemental analysis and UV/Vis- and CD-absorption spectra, The conformation of SS-phpm in ${\Delta}$-cis-${\beta}$ complex is ${\delta}$ ${\varepsilon}$ ${\lambda}$ (SSSS) for each of the five-membered chelated ring. Futhermore, according to orientation of secondary amine, total strain energy on each isomers was calculated by molecular mechanics(MM) to verify structural characterization and spectral data. As the result, the most stabilized isomer was ${\Delta}$-cis-${\beta}$(SSSS). The value of total strain energy(U) of ${\Delta}$-cis-${\beta}$(SSSS) isomer was 63.21 kcal/mol, respectively.

• 한국음향학회지
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• 제34권5호
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• pp.351-359
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• 2015

통상의 수중 음향 트랜스듀서는 음압의 크기만 측정할 뿐, 외부에서 들어오는 음향 신호의 방향은 파악할 수 없는 한계가 있다. 이에 본 논문의 저자들은 Tonpilz 트랜스듀서를 바탕으로 단일체로서 음압의 크기와 방향을 동시에 탐지해 낼 수 있는 새로운 벡터 센서구조를 제안하였다. 제안된 구조에는 압전세라믹 링이 4등분되어 있으며, 외부 음압에 대한 각 세라믹 조각의 출력전압을 적절히 조합하면 음원의 방향을 파악할 수 있는 특징을 가진다. 본 논문에서는 이러한 구조를 가지는 Tonpilz 벡터센서를 제작하고 그 특성을 실험적으로 측정하여, 제안된 구조의 타당성을 확인하였다.

• 한국생물정보학회:학술대회논문집
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• 한국생물정보시스템생물학회 2005년도 BIOINFO 2005
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• pp.249-255
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• 2005

Angiotensin-converting enzyme (ACE) is primarily responsible for human hypertension. Current ACE drugs show serious cough and angiodema health problems due to the un-specific activity of the drug to ACE protein. The availability of ACE crystal structure (1UZF) provided the plausible biological orientation of inhibitors to ACE active site (C-domain). Three-dimensional quantitative structure-activity relationship (3D-QSAR) models have been constructed using the comparative molecula. field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA) for a series of 28 ACE inhibitors. Alignment for CoMFA obtained by docking ligands to 1UZF protein using FlexX program showed better statistical model as compared to superposition of corresponding atoms. The statistical parameters indicate reasonable models for both CoMFA (q$^2$ = 0.530, r$^2$ = 0.998) and CoMSIA (q$^2$= 0.518, r$^2$ = 0.990). The 3D-QSAR analyses provide valuable information for the design of ACE inhibitors with potent activity towards C-domain of ACE. The group substitutions involving the phenyl ring and carbon chain at the propionyl and sulfonyl moieties of captopril are essential for specific activity to ACE.

• 한국터널지하공간학회 논문집
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• 제17권3호
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• pp.363-382
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• 2015

본 연구는 수치해석을 통하여 TBM 세그먼트의 분할 수와 인접한 링의 이격각도가 라이닝의 부재력에 어떤 영향을 미치는 살펴보았다. 수치해석은 Midas civil 2012+ 프로그램을 사용하였고, 모델링은 2링빔 스프링 모델을 이용하였다. TBM 세그먼드 부재력은 다양한 요소에 의해 결정된다. 본 논문에서는 세그먼트 분할 수와 분포를 제외한 다른 요소인 이음부 스프링 계수, 지반반력계수를 통제하고 특정한 분할 수와 분할 특성을 통해 case를 선정함으로써 분할 수와 분포와 같은 분할 특성이 부재력에 미치는 영향을 분석하였다. 이로써 TBM 세그먼트 시공 설계시 구조적으로 유리하거나 불리한 이음부 특성을 확인할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제31권1호
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• pp.116-119
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• 2010

Adsorption structures of the self-assembled thin films of $\alpha$-cyano-4-hydroxycinnamic acid (CHCA) anchoring on $TiO_2$ surfaces have been studied by using temperature-dependent diffuse reflectance infrared Fourier-transform (DRIFT) spectroscopy. From the presence of the strong $\nu(COO^-)$ band at ~1390 $cm^{-1}$ along with the disappearance of the OH bands in the carboxylic acid group in the DRIFT spectra at room temperature, CHCA appeared to adsorb onto $TiO_2$ surfaces as a carboxylate form. The absence of the out-of-plane benzene ring modes of CHCA in the DRIFT spectra suggests a rather vertical orientation of CHCA on $TiO_2$. Above ~220$ ^{\circ}C$, CHCA seemed to start to thermally degrade on $TiO_2$ surfaces referring from the disappearance of most vibrational modes in the DRIFT spectra, whereas the $\nu$(C ≡ N) bands were found to remain relatively conspicuous as the temperature increased even up to ~460$^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• 제26권6호
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• pp.952-958
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• 2005

Angiotensin-converting enzyme (ACE) is known to be primarily responsible for hypertension. Threedimensional quantitative structure-activity relationship (3D-QSAR) models have been constructed using the comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA) for a series of 28 ACE inhibitors. The availability of ACE crystal structure (1UZF) provided the plausible biological orientation of inhibitors to ACE active site (C-domain). Alignment for CoMFA obtained by docking ligands to 1UZF protein using FlexX program showed better statistical model as compared to superposition of corresponding atoms. The statistical parameters indicate reasonable models for both CoMFA ($q^2$ = 0.530, $r^2$ = 0.998) and CoMSIA ($q^2$ = 0.518, $r^2$ = 0.990). The 3D-QSAR analyses provide valuable information for the design of ACE inhibitors with potent activity towards C-domain of ACE. The group substitutions involving the phenyl ring and carbon chain at the propionyl and sulfonyl moieties of captopril are essential for better activity against ACE.