• The Journal of the Petrological Society of Korea
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• v.28 no.4
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• pp.237-249
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• 2019

The volcanic rocks around the Jayang caldera are classified in an order such as Jukjang Volcanics, Doil Rhyolite, Unjusan Tuff and Rhyolite intrusions. By the SHRIMP U-Pb zircon datings from zircons, eruption ages of the Unjusan Tuff are constrained as 66.65±0.96 Ma in the intracaldera, and 66.08±0.62 Ma in the extracaldera outflow, and intrusion age of the ring dike is investigated as 60.74±0.66 Ma. The age data indicate that the caldera was collapsed between 66.08 Ma and 60.74 Ma, just before the dike intruded after the explosive eruption of the Unjusan Tuff. The Jayang caldera shows the composite igneous process of a perfect volcanic cycle passing from ash-flow tuffs through caldera collapse into ring dikes in the Jayang area.

• Bulletin of the Korean Chemical Society
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• v.20 no.5
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• pp.531-534
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• 1999

Irradiation (300 nm UV light) of dibenzoylmethane and 1,4-naphthoquinone in dichloromethane gave 1,5-dike-tone as the major product, along with β-hydroxyketone as the minor product. Anthraquinone and anthrone also added photochemically to dibenzoylmethane to give 1,5-diketones as the major products. In contrast, tetrahalo-1,4-benzoquinones added to dibenzoylmethane to give two types of 1,5-diketones via oxetane and cyclobutane intermediates. Comparison of the potential energy values of the photoproducts reveals that the 1,5-diketones are more stable than the corresponding oxetanes or cyclobutanes due to the ring-strain of the bicyclic compounds.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.35-48
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• 2021

The Gumi basin, situated in the mid-southeastern Yeongnam Massif, has the Cretaceous stratigraphy that is divided into Gumi Formation, andesitic rocks (Yeongamsan Tuff, Busangni Andesite), rhyolitic rocks (Obongni Tuff, Doseongul Rhyolite, Geumosan Tuff) and Intrusives (ring dikes, other dikes) in ascending order. The Geumosan Tuff is composed mostly of many ash-flow tuffs which are associated with Geumosan caldera along with the ring dikes. The caldera is outlined by ring faults and dikes and has about 3.5 × 5.6 km in diameters. The intracaldera volcanics show a downsag structure that is dipped inward in their flow and welding foliations. The caldera block represent an asymmetric subsidence, which drops 350 m in the northern margin and 600 m in the southern one. Based on these data, the Geumosan caldera is geometrically classified as an asymmetric piston subsidence caldera that suggests a single caldera cycle. The caldera reflects the piston subsidence of the caldera block bounded by the outward-dipping ring faults following a voluminous eruption of magma from the chamber. The downsag in the caldera block refers to the downsagging during the initial subsidence at the same time as the full development of the bound fault. In the ring fissures following the sagging, magma was injected due to the overpressure of magma chamber caused by subsidence.

• The Journal of the Petrological Society of Korea
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• v.7 no.3
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• pp.147-160
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• 1998

The Samrangjin Caldera, a trapdoor-type, formed by the voluminous eruption of the silicic ash-flows of the Samrangjin Tuff which is above 630m thick at the northern inside of the caldera and thinnerly 80m at the southern inside. The caldera volcanism eviscerated the magma chamber by a series of explosive eruptions during which silicic magma was ejected to form the Samrangjin Tuff. The explosive eruptions began with phreatoplinian eruption, progressed through small plinian eruption and transmitted with ash-flow eruption. During the ash-flow eruption, contemporaneous collapse of the roof of the chamber resulted in the formation of the Samrangjin caldera, a subcircular depression subsiding above 550m deep. During postcaldera volcanism after the collapse, flow-banded rhyolite was emplaced as cental plug along the central vent and ring dikes along the caldera margins. Subsequently rhyodacite porphyry and dacite porphyry were emplaced along the inner side of the ring dike. After their emplacement, residual magma was emplaced as a hornblende biotite granite stock into the southwestern caldera margin. In the northeastern part, the eastern dikes were cut final intrusions of granodioritic to granitic composition along the fault zone of $^{\circ}$W trend.

• The Journal of the Petrological Society of Korea
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• v.22 no.3
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• pp.219-233
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• 2013

Spherulitic rhyolite occur as part of ring dyke which showing a vertical flowage of $60^{\circ}{\sim}90^{\circ}$, of the Jangsan cauldron was studied. The spherulites range in diameter from a few millimeters to 2.8 centimeters or more, and average 5~10 millimeters. It belongs to radiated simple spherulite type. They consist of a core of moderate brown dense material encased by a thin crust, a few millimeters thick at most of white grey material. The spherulites frequently have a radiating fibrous structure, which are thought to have formed as a consequence of rapid mineral growth caused by very fast cooling of the dykes in shallow depth near the surface. EPMA examination of the concentric-zoned core of spherulites show that they are mainly composed of cryptocrystalline-fibrous intergrowth of silica minerals and alkali feldspars which have $SiO_2$ 82% or more, $Al_2O_3$ 7~10%, $Na_2O+K_2O$ less than 8%. The feldspar compositions of the spherulites lie essentially within the sanidine field. XRD examination show that spherulites are mainly composed of quartz, sanidine, albite with minor mica, kaolinite and chlorite. According to X-ray mapping, the spherulites are enriched in $SiO_2$ in the core and partly enriched $Na_2O$ or $K_2O$, $Al_2O_3$ in the shell that reflect in compositional zoning with increasing spherulitic devitrification. The feathery and non-equant crystal shapes of spherulites from rhyolite dyke of Jangsan cauldron suggest that they may have formed during the rapid cooling of dyke under the static state, or faster velocity of devitrification from glassy materials than movement velocity of the magma intrusion. The spherulitic rhyolite originated from high-silica(75.4~75.7 wt.%) rhyolite magma.