• Proceedings of the KIEE Conference
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• 1984.07a
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• pp.306-307
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• 1984

• Bulletin of the Korean Chemical Society
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• v.10 no.2
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• pp.158-161
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• 1989

The hydrophobic interaction occurring between rhodamine 6G and tetraphenylborate anions has been investigated with surfactants by absorption and fluorescence studies. In the order of tetraphenylborate, tetrakis(4-fluorophenyl)borate, and tetrakis[3,5-bis(trifluoromethyl)phenyl]borate the hydrophobicity is found to be increased.

• Journal of the Korean Chemical Society
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• v.37 no.2
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• pp.213-219
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• 1993

The electrochemical spectral sensitization of $SnO_2$ electrodes with rhodamine B was studied. Photocurrent was measured in the presence of a variety of supersensitizers including ascorbic acid and KI. In the presence of ascorbic acid, the increase in the concentration of ascorbic acid, pH of the solution, or the potential applied to $SnO_2$ up to 0.6 V vs. SCE enhanced the photocurrent. However, ascorbic acid produced considerably high dark current due to its low reduction potential. On the other hand, KI produced low but stable photocurrent. The results, together with the solvent effect on the photocurrent, were taken into account to elucidate the mechanism of photosensitization in the presence of ascorbic acid or KI.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.11
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• pp.731-736
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• 2015

Rhodamine B (RhB) was utilized as a dye sensitizer for dye-sensitized solar cells (DSSCs) and its photovoltaic property was examined under the illumination of AM 1.5 G, $100mWcm^{-2}$. DSSCs based on RhB exhibited typical photovoltaic properties with an open-circuit voltage ($V_{OC}$) of 0.34 V, a short-circuit current ($J_{SC}$) of $1.55mA{\cdot}cm^{-2}$, a fill factor (FF) of 50%, and a conversion efficiency (PCE) of 0.26%. In order to further improve the photovoltaic properties of RhB-based DSSCs, the effect of (i) incorporating a strong electron-donating NCS unit into the RhB molecular backbone, (ii) combining a bis-negatively charged zinc complex anion ($Zn-dmit_2$, dmit=di-mercapto-dithiol-thione) with the amine cation of RhB, (iii) co-adsorbing RhB dyes with chenodeoxycholic acid (CDCA) molecules onto porous $TiO_2$ electrodes, was investigated and discussed.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.29-29
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• 2012

Rhodamine chromophore/fluorophore have been attracted to many researchers due to its excellent photophysical properties. In this study, we have designed and synthesized a strong emissive fluorescent dye chemosensor for toxic elements. A rhodamine-based sensor was prepared by incorporation the rhodamine fluorophore and several functional host groups with high affinity to hazardous metal and anion. This sensor shows a high selectivity and an excellent sensitivity and is a dual-responsive colorimetric and fluorescent metal/anion-specific sensor. In addition, the 1:1 binding mode was proposed based on Job's plot method. Finally, computational calculation was simulated and calculated to approach for HOMO/LUMO of this dye chemosensor.

• Korean Journal of Materials Research
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• v.29 no.12
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• pp.747-752
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• 2019

Environmental pollution remains a considerable health risk source all over the world; however, hazards are usually higher in developing countries. Iraq has long been suffering from the problem of pollution and how to treat pollution. Photocatalytic degradation has turned out to be most productive process for dye degradation. In this investigation, Rhodamine B (RhB), dye has been selected for degradation under visible light illumination. To address this issue, we fabricate erbium trioxide nanoparticles (Er₂O₃/NPs). Erbium trioxide nanoparticles are prepared and utilized for photo-catalytic degradation. The characterization of Er₂O₃/NPs is described and confirmed by utilizing of XRD (X-ray diffraction) and SEM (Scanning Electron Microscopy). The average size of Er₂O₃ nanoparticles is observed to be 16.00 nm. Er₂O₃/NPs is investigated for its ability of photo-catalytic degradation through certain selected parameters such as concentration and time. The methodological results show that the synthesized Er₂O₃/NPs is a good photo-catalytic for Rhodamine degradation.

• Journal of Environmental Health Sciences
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• v.35 no.4
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• pp.295-303
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• 2009

A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.

• Journal of the Korean Geotechnical Society
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• v.20 no.4
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• pp.49-56
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• 2004

Tracer tests were conducted to investigate leachate outflow through damaged parts on HDPE liner subject to puncture loads in a closed landfill. Natural gradient tracer test was used with two different types of tracers, iodide and Rhodamine WT. Tracers were selected under careful consideration of chemical components of leachate. Five injection wells with fourteen detection points were installed and operated throughout the test site. In this study, it is found that Iodide and Rhodamine WT are applicable and effective for leachate leakage investigation on waste landfills. Also, it is concluded that considerable amount of leachate was leaked through the rain water drain box and side wall of drain box.

• Journal of Sensor Science and Technology
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• v.23 no.3
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• pp.173-177
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• 2014

A Rhodamine-based fiber-optic sensor has been developed to detect mercury ions in aqueous environments. The fiber-optic sensor was composed of a mercury-sensing thin film, plastic optical fibers, and a spectrometer. The mercury-sensing thin film with the synthesized Rhodamine derivatives was fabricated with Sol-Gel process. A light emitted by a light source is guided by plastic optical fibers into the thin film in an aqueous solution and a reflected light is analyzed with the spectrometer. The experiment exhibits that an absorbance in the thin film is increased as mercury concentration is increased in the solution and the absorbance by mercury is higher than that by other heavy metals. The fiber-optic sensor exhibits high chromogenic phenomenon of mercury ions among various heavy metals and the correlation between absorbance and mercury concentration in the aqueous environments.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3212-3216
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• 2010

A new rhodamine-based sensor 1 was designed and synthesized by incorporating rhodamine B and benzimidazole moieties. Sensor 1 exhibits high selectivity and sensitivity to $Cu^{2+}$ in $CH_3CN$-water solution (HEPES buffer, pH = 7.0) with an obvious color change from colorless to pink. Other metal ions such as $Hg^{2+}$, $Ag^+$, $Pb^{2+}$, $Sr^{2+}$, $Ba^{2+}$, $Cd^{2+}$, $Ni^{2+}$, $Co^{2+}$, $Fe^{2+}$, $Mn^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Ce^{3+}$, $Mg^{2+}$, $K^+$ and $Na^+$ had no such color change and have no significant influence on $Cu^{2+}$ recognition process. The interaction of $Cu^{2+}$ and sensor 1 was proven to adopt a 1:1 binding stoichiometry and the recognition process is reversible.