• 한국건축시공학회지
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• 제20권5호
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• pp.399-407
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• 2020

본 연구에서는 중유동 콘크리트 제조를 위해 기존의 재료분리 판정법과 레올로지 정수를 활용하여 콘크리트 재료분리 상황을 정의하고자 하였다. 중유동 콘크리트는 일반강도 범위의 비교적 높은 물시멘트비 조건에서 높은 유동성을 발현하는 조건으로 고성능 감수제를 사용하면서 재료분리를 제어하는 것이 매우 중요하다. 이에 본 연구조건에서는 고형분량이 다른 두 가지 고성능 감수제를 사용하여 일반강도 콘크리트 배합의 유동성을 증진시키면서 재료분리가 발생하기 시작하는 범위의 유동특성과 레올로지 정수의 변화에 대해 관찰하였다. 기존의 레올로지를 이용한 유동성 측정연구는 고유동성을 확보한 조건에서 측정되어야 했기 때문에 재료분리가 발생하는 조건은 측정의 대상에서 제외되었던 경우가 많았다. 본 연구에서는 재료분리가 발생하기 시작하는 상태의 콘크리트 배합조건에서 기존의 재료분리 판정법이나 관찰에 의한 방법으로는 아직 재료분리에 이르르지 않았다고 판단되더라도 레올로지 측정 정수인 소성점도와 정적 항복응력 측정값에서 이상측정값이 관찰되는 것을 확인하였다. 이러한 결과가 콘크리트에 있어서 재료분리가 발생하는 조건을 레올로지적으로 정의할 수 있는 기초적인 자료를 제공할 것으로 판단한다.

• 한국전산유체공학회지
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• 제16권2호
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• pp.81-87
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• 2011

The importance of shear thinning non-Newtonian blood rheology on the hemodynamic characteristics of idealized cerebral saccular aneurysms were investigated by carrying out CFD simulations assuming two different non-Newtonian rheology models (Carreau and Ballyk models). To explore effects of vessel curvature, a straight and a curved vessel geometry were considered. The wall shear stress(WSS), relative residence time(RRT) and velocity distribution were compared at the different phases of cardiac cycle. As expected, blood entered the aneurysm at the distal neck and created large vortex in both aneurysms, but with higher momentum on the curved vessel. Hemodynamic characteristics such as WSS, and RRT exhibited only minor effects by choice of different rheological models although Ballyk model produced relatively higher effects. We conclude that the assumption of Newtonian fluid is reasonable for studies aimed at quantifying the hemodynamic characteristics, in particular, WSS-based parameters, considering the current accuracy level of medical image of cerebral aneurysm.

• Computers and Concrete
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• 제15권6호
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• pp.903-919
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• 2015

The flow of freshly mixed cement-based material shows thixotropy, which implies some difficulties on robust measurement of its rheological properties: The flow curve of thixotropic materials depends on the used protocol. For examples, higher viscosity is obtained when the rate of shear strain is more quickly increased. Even though precise measurement and modelling of the concrete rheology needs to consider the thixotropic effect, engineers in the concrete field prefer considering as a non-thixotropic Herschel-Bulkley fluid, even more simply Bingham fluid. That is due to robustness of the measurement and application in casting process. In the aspect of simplification, this papers attempts to mimic the thixoropic flow by the non-thixotropic Herschel-Bulkley model. Disregarding the thixotropy of cement based materials allows us to adopt the rheological concept in the field. An optimized protocol to measure the Bingham parameters was finally found based on the accuracy and reproducibility test of cement paste samples, which minimizes the error of simulation stemming from the assumption of non-thixotropy.

• Korea-Australia Rheology Journal
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• 제14권1호
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• pp.11-16
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• 2002

Cephalosporium acremonium is a filamentous microorganism producing cephalosporin C. The morphological differentiation of C. acremonium in submerged culture is closely related with the rheological properties of culture broth and production of cephalosporin C. In this study, the rheological and morphological properties of culture broth of C. acremonium were investigated. In the seed broths of shake-flask and fermenter culture, the Herschel-Berkley equation was in excellent agreement with experimental results in the whole range of shear rate. In the seed broths of shake-flask culture, morphological differentiation into arthrospores affected to changes of apparent viscosity. But results in the fermenter culture, morphological factors such as mean hyphal thickness and the number of tips gave more effect on changes of apparent vitacosity than differentiation into arthrospores. Overall, it suggested that the morphological parameters measured by image analysis can be used as a good parameter to indicate the rheological properties of culture broth of C. acremonium M25.

• 유변학
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• 제2권1호
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• pp.46-52
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• 1990

배추의 조직감 특성을 기계적으로 측정하는 방법을 수립하기 위하여 여러 가지 형 태의 탐침에 의한 침투 및 절단시험에서 나타난는 힘-거리 곡선을 비교분석하였으며 그 결 과를 배추잎의 미세구조와 관능적특성과 연관하여 해석하였다. 배추잎의 침투심험에서 탐침 의 선단각, 선단면적 및 둘레에 따라 힘-거리 곡선의 형태는 크게 달라지며 선단면적과 둘 레가 커질수록 파열력이 크게 증대되었다. 절단시험에서는 표피와 내부유관속 조직을 절단 하는 세 개의 특징적인 피크를-나타내었다. 배추잎의 염장에 의하여 침투시험의 최대 변형 력은 크게 감소된 반면 파열력은 크게 증대되어 최대 변형력에 대한 파열력의 비(a/c) 는 증가되었으며 이것은 탐침의 선단면적과 둘레가 큰경우에 더욱 두드러지게 나타났다. 염장 에 의하여 탄성한계까지의 변형거리가 커졌으며 최초 변형에서의 탄성치(a/l)는 감소하는 경 향을 나타내었다. 절단시험에서는 염장에의하여 외피의 절단력이 상대적으로 증가하였다. 배 추 및 절인배추의 아삭아삭한 정도는 침투시험의 최대변형력과 a/l의 변화와 밀접한 관계가 있으며 질긴 정도는 침투시험의 파열력과 a/c 절단시험의 절단력과 관계가 있으며 아작아작 한 정도는 침투시험의 a/c와 관계가 있는 것으로 판단되었다.

• Korea-Australia Rheology Journal
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• 제14권2호
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• pp.63-70
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• 2002

Chemical mechanical planarization (CMP) is the polishing process enabled by both chemical and mechanical actions. CMP is used in the fabrication process of the integrated circuits to achieve adequate planarity necessary for stringent photolithography depth of focus requirements. And recently copper is preferred in the metallization process because of its low resistivity. We have studied the effects of chemical reaction on the polishing rate and surface planarity in copper CMP by means of numerical simulation solving Navier-Stokes equation and copper diffusion equation. We have performed pore-scale simulation and integrated the results over all the pores underneath the wafer surface to calculate the macroscopic material removal rate. The mechanical abrasion effect was not included in our study and we concentrated our focus on the transport phenomena occurring in a single pore. We have observed the effects of several parameters such as concentration of chemical additives, relative velocity of the wafer, slurry film thickness or ash)tract ratio of the pore on the copper removal rate and the surface planarity. We observed that when the chemical reaction was rate-limiting step, the results of simulation matched well with the experimental data.

• Korea-Australia Rheology Journal
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• 제14권2호
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• pp.49-55
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• 2002

To understand the large amplitude oscillatory shear (LAOS) behavior of complex fluids, we have investigated the flow behavior of a network model in the LAOS environment. We applied the LAOS flow to the model proposed by Vaccaro and Marrucci (2000), which was originally developed to describe the system of associating telechelic polymers. The model was found to predict at least three different types of LAOS behavior; strain thinning (G' and G" decreasing), strong strain overshoot (G' and G" increasing followed by decreasing), and weak strain overshoot (G' decreasing, G" increasing followed by decreasing). The overshoot behavior in the strain sweep test, which il often observed in some complex fluid systems with little explanation, could be explained in terms of the model parameters, or in terms of the overall balance between the creation and loss rates of the network junctions, which are continually created and destroyed due to thermal and flow energy. This model does not predict strain hardening behavior because of the finitely extensible nonlinear elastic (FENE) type nonlinear effect of loss rate. However, the model predicts the LAOS behavior of most of the complex fluids observed in the experiments.he experiments.

• Korea-Australia Rheology Journal
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• 제20권1호
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• pp.27-34
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• 2008

Clay suspensions in liquid polymers exhibit a time-dependent behaviour that includes viscoelastic as well as thixotropic features. Because of the presence of interacting clay platelets, particulate networks can develop, which are broken down during flow and rebuild upon cessation of the flow. Here, the use of thixotropic techniques in probing flow-induced structures in nanocomposites is explored with data on a hectorite-poly(isobutylene) model system. By means of fast stress jump measurements the hydrodynamic contributions to the steady state stresses are determined as well as those caused by the stretching of the clay floes. Flow reversal measurements do not provide a clear indication of flow-induced anisotropy in the present case. The recovery of the clay microstructure upon cessation of flow is followed by means of overshoot and dynamic measurements. The development of a particulate network is detected by the appearance and growth of a low frequency plateau of the storage moduli. The modulus-frequency curves after various rest times collapse onto universal master curves, regardless of the pre-shear history or temperature. The scaling factors for this master curve are the crossover parameters. The crossover moduli are nearly a linear function of the crossover frequency, the relation being identical for recovery after shearing at different shear rates. This function depends, however, on temperature.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2005년도 추계 학술논문 발표대회
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• pp.71-74
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• 2005

The viscosity of high-flowability paste is very high compared to normal concrete for the low water-binder ratio(W/B). Therefore, high-flowability concrete is positively necessary to high-range water reducing agent. High-Flowability paste can make much higher fluidity with no occurrence of segregation, by its higher viscosity and lower yield value than normal concrete. The flowability of high-flowability paste must be evaluated not only by convention consistency test such as slump test but also by the base of the rheological properties of the fresh concrete. The purpose of this study is to analyze the fluidity of high-flowability paste according to the addition ratio of the Melamine Sulphonate high-range water reducing agent.; high-flowability paste is considered as Bingham plastic fluid with the rheology parameters of the plaste viscosity and yield value.

• Macromolecular Research
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• 제17권2호
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• pp.121-127
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• 2009

The cure kinetics of the epoxy-layered, silicate nanocomposites were studied by differential scanning calorimetry under isothermal and dynamic conditions. The materials used in this study were o-cresol novolac epoxy resin and phenol novolac hardener, with organically modified layered silicates. Various kinetic parameters, including the reaction order, activation energy, and kinetic rate constants, were investigated, and the storage stability of the epoxy-layered silicate nanocomposites was measured. To synthesize the epoxy-layered silicate nanocomposites, the phenolic hardener underwent pre-intercalation by layered silicate. From the cure kinetics analyses, the organically modified layered silicate decreased the activation energy during cure reaction in the epoxy/phenolic hardener system. In addition, the storage stability of the nanocomposite with the pre-intercalated phenolic hardener was significantly increased compared to that of the nanocomposite with direct mixing of epoxy, phenolic hardener, and layered silicate. This was due to the protective effect of the reaction between onium ions and epoxide groups.