• Title/Summary/Keyword: rheology characteristics

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Study on Rheological Properties of Mortar for the Application of 3D Printing Method (3D 프린팅 공법 적용을 위한 모르타르 구성성분 변화에 따른 레올로지 특성 연구)

  • Lee, Hojae;Kim, Won-Woo;Moon, Jae-Heum
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.16-24
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    • 2018
  • In this study, an experiment was conducted to analyze mortar based rheology for 3D printing method application. The tendency of rheological properties due to the change of W/B, binder type, replacement ratio, and super plasticizer which have a great influence on the flow characteristics of concrete was experimentally analyzed. Experiments were carried out by dividing into paste and mortar. In the paste experiment, rheology was analyzed by setting W/B, binder type, replacement ratio, and super plasticizer dosage as main variables. In the mortar experiment, the rheological properties of W/B and sand ratio were analyzed. As a result, as the W/B was increased, the viscosity decreased and the FA ratio to replace FA increased and the viscosity increased. In order to increase the fluidity, substitution of only 5% of SF reduces the shear stress and the viscosity is reduced by about 83%. Mortar rheological evaluation shows that there is a critical section where a large change occurs in the W/B 30 to 40% section. Also, in the same W/B, it is analyzed that there is a critical section where the shear stress increases more than twice in the sand ratio of 50~60%.

Role of ChE and ChErs in the 21st century civilization: conceptual understanding of macroeconomic connections embedded in ChE discipline as related to the central theme (paradigm) of the 21st century civilization

  • Hyun, Jae-Chun
    • Korea-Australia Rheology Journal
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    • v.20 no.3
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    • pp.175-184
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    • 2008
  • Chemical engineering (ChE) was conceived at the close of the 19th century as a new discipline which was designed to support then the newly-emerging industries, oil and petrochemical, by supplying the competent engineers equipped with the pertinent engineering fundamentals and skills. It helped the said industries meet the various demands and ramifications of the new pattern of the human civilization spurred by the advent of automobile transportation at the turn of the 20th century. Now ChE once again is ready to fulfill its societal responsibility as probably the most important discipline and profession in sustaining the $21^{st}$ century human civilization providing the needed engineers (ChErs) and technologies. In this study, it is attempted to analyze the role of ChE and ChErs in this context, focusing on the macroeconomic connections embedded in the discipline that allow us to envision the big pictures of the 21st century civilization where the wellbeing of the mankind invariably hinges on five essential industries, i.e., medical, pharmaceutical, energy, environment and materials. It can be argued that ChE is the only discipline that can encompass simultaneously all those five industries indispensable to sustain the 21 st century human civilization that can be termed the era of "enjoy-healthy-living-longer". It is also believed that the historical mission ChE and ChErs are supposed to fulfill now is even bigger than that they took on a hundred years ago and subsequently accomplished with remarkable success in food, clothing, shelter and entertainment industries introducing various technological innovations. The macroeconomic viewpoints are called upon in this study as were in the 2006 article (Hyun, 2006) but focusing on ChE and ChErs this time to view the connections embedded in ChE as the essential components in understanding the historical nature of the role and responsibility of ChE and ChErs. The new paradigm for ChE is also pondered over together with the frequently-cited technology concepts such as IT, BT, NT, ET and ST which are regarded intimately germane to the characteristics and perspectives of the $21^{st}$ century civilization.

Rheological Characteristics of ER Fluids at High Pressure-Driven Flow Mode (높은 압력차의 유동모드 하에서 ER유체의 유변특성)

  • 이호근;최승복;정재천;강윤수;서문석
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.1-8
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    • 1999
  • This paper experimentally investigates the steady shear behaviors of electro-rheological(ER) fluids under flow mode at high pressure level. As for the ER fluid to be tested, two types of ER fluids are employed; water-based ER fluids (ERF 1, ERF 2) and water-free ER fluid(ERF 3). The water-based ER fluids are composed inhousingly, and the concentrations of dispersed particles are 20 wt% and 30 wt% for ERF 1 and ERF 2, respectively. To generate the flow mode at high pressure, an experimental apparatus operated by two-way hydraulic cylinder is constructed and utilized. The pressure difference is measured by the pressure sensor, while the flow rate is calculated using the measured data of the displacement sensor(LVDT). Consequently, the shear stress and shear rate are distilled by incorporating the measured data; the pressure difference and the flow rate.

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A Viscoelastic Study of Glass Transition and Degradation Processes of Phenolic Resin/Carbon Fiber Composites (페놀수지/탄소섬유 열경화성 복합재료의 유리전이와 고온 분해과정에서 관찰되는 점탄성 특성 연구)

  • ;J. C. Seferis
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.9-17
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    • 1999
  • Viscoelastic characteristics of cured phenolic resin/carbon fiber composite materials were investigated through glass transition and degradation reaction processes in the high temperature region up to $400^{\circ}C$. A typical glass transition of the cross-linked thermoset polymer was followed by irreversible degradation reactions, which were exhibited by the increasing storage modulus and loss modulus peak. A degradation master curve was constructed by using the vertical and horizontal shift factors, both of which complied well with the Arrhenius equation in light of the kinetic expression of degradation rate constants. Using an analogy to the Havriliak-Negami equation in dielectric relaxation phenomena, a viscoelastic modeling methodology was developed to characterize the frequency- and temperature-dependent complex moduli of the degrading thermoset polymer composite systems. The temperature-dependent relaxation time of the degrading composites was determined in a continuous fashion and showed a minimum relaxation time between the glass transition and degradation reaction regions. The capability of the developed modeling methodology was demonstrated by describing the complex behavior of the viscoelastic complex moduli of reacting phenolic resin composite systems.

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Rheological Characteristics of Magnetic $\gamma$-$Fe_{2}O_{3}$ and $CrO_2$ Particle Suspension (자성 $\gamma$-$Fe_{2}O_{3}$$CrO_2$ 입자 분산액의 유변특성 연구)

  • 김철암;이준석;최형진
    • The Korean Journal of Rheology
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    • v.11 no.2
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    • pp.128-134
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    • 1999
  • Rheological characterization was examined for two different types of magenetic particle (rod-like $\gamma$-$Fe_{2}O_{3}$, $CrO_2$ )suspension in this study. The measured suspension viscosity (viscosity vs. concentration or shear rate) is used to obtain the dependence of viscous energy dissipation on the microstructural states of magnetic particle dispersions as well as the microstructural shape effects which are related to magnetic particle orientation. The empirical formulas from mean field theory and the Mooney equation are used to relate suspension viscosity to particle concentration. Intrinsic viscosities of these two different types of rod-like magnetic particle suspensions are found to exceed the prediction of hydrodynamic theory for dilute suspensions and support the existence of flocs containing significant amounts of immobilized suspending medium due to native attraction forces among particles in the microstructures.

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Preparation of Cellulose Nanofibril/Regenerated Silk Fibroin Composite Fibers

  • Lee, Ji Hye;Bae, Chang Hyun;Park, Byung-Dae;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.26 no.2
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    • pp.81-88
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    • 2013
  • Wet-spun silk fibers have attracted the attention of many researchers because of 1) the unique properties of silk as a biomaterial, including good biocompatibility and cyto-compatability and 2) the various methods available to control the structure and properties of the fiber. Cellulose nanofibrils (CNFs) have typically been used as a reinforcing material for natural and synthetic polymers. In this study, CNF-embedded silk fibroin (SF) nanocomposite fibers were prepared for the first time. The effects of CNF content on the rheology of the dope solution and the characteristics of wet-spun CNF/SF composite fibers were also examined. A 5% SF formic acid solution that contained no CNFs showed nearly Newtonian fluid behavior, with slight shear thinning. However, after the addition of 1% CNFs, the viscosity of the dope solution increased significantly, and apparent shear thinning was observed. The maximum draw ratio of the CNF/SF composite fibers decreased as the CNF content increased. Interestingly, the crystallinity index for the silk in the CNF/SF fibers was sequentially reduced as the CNF content was increased. This phenomenon may be due to the fact that the CNFs prevent ${\beta}$-sheet crystallization of the SF by elimination of formic acid from the dope solution during the coagulation process. The CNF/SF composite fibers displayed a relatively smooth surface with stripes, at low magnification (${\times}500$). However, a rugged nanoscale surface was observed at high magnification (${\times}10,000$), and the surface roughness increased with the CNF content.

Guideline for Filling Performance of Concrete for Modular LNG Storage Tanks (모듈형 LNG 저장탱크용 콘크리트 충전성능 가이드라인 제시)

  • Lee, Dong Kyu;Lee, Keon Woo;Park, Gi Joon;Kim, Sung Wook;Park, Jung Jun;Kim, Young Jin;Choi, Myoung Sung
    • Journal of the Korean Society of Safety
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    • v.33 no.2
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    • pp.86-93
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    • 2018
  • Recently, the use of composite steel plate concrete structural modules filled with concrete between steel plates of complex internal structure, in which a large amount of studs are installed, is increasing in order to reduce the weight and to increase workability of structures such as LNG storage tanks. However, in Korea, there is no systematic criterion for evaluating the construction performance of composite steel plate concrete structural modules. Therefore, in this study, we propose a filling guideline of concrete for composite steel plate structural module. For this purpose, high filling performance concrete with general strength range was formulated and tested for filling ability and permeability for each formulation. Rheology analysis was performed to quantitatively evaluate the flow characteristics of concrete. The reliability of $T_{500}$ and plastic viscosity was evaluated to reflect the results of each test, and a guideline for high filling concrete satisfying the reliability of 0.9 or more was derived by reflecting the results of the study on the relationship between the $T_{500}$ and plastic viscosity. Through final fill-box test, filling performance was verified and guidelines were suggested.

Rheological Studies on Barley Starch-Water Systems (보리전분 수용액계의 리올로지적 연구)

  • Lee, Shin-Young;Choi, Jun-Bok;Chun, Byong-Ik
    • Korean Journal of Food Science and Technology
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    • v.17 no.3
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    • pp.131-135
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    • 1985
  • The rheological studies on dilute and concentrate solutions of naked and covered barley starches were carried out with various viscosimeters. The rheology of dilute solutions (0.05-0.3%) were characterized by intrinsic viscosity and related parameter according to Huggins equation. Also, the rheology of the solutions of higher concentrations (1-5%) were characterized by time dependent characteristics and pseudoplastic behaviors. The values of consistency index according to the power equation were exponen tially dependent upon concentration and temperature. The results showed that the rheological properties could differ greatly due to difference in varieties. The naked barley starch exhibited higher intrinsic viscosity, more thixotropic behavior and more dependence of consistency index on concentration and temperature than the covered barley starch.

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Characteristics of Wax Gourd Juice-added Dry Noodles (동아즙을 첨가한 국수의 품질 특성)

  • Hong, Sun-Pyo;Jun, Hyun-Il;Song, Geun-Seoup;Kwon, Kyoung-Soohn;Kwon, Yong-Ju;Kim, Young-Soo
    • Korean Journal of Food Science and Technology
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    • v.36 no.5
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    • pp.795-799
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    • 2004
  • Noodles were prepared by adding 25, 50, 75, and 100% wax gourd juice to wheat flour, and effects of added wax gourd juice on dough rheology and cooking and noodle qualities were examined. Initial pasting temperature, and peak and final viscosities increased with addition of wax gourd juice. Water absorption and dough weakness, and cooked weight, moisture absorption, cooked volume, and cooking loss of noodleincreased, but dough development time and dough stability decreased with increase in wax gourd juice content. Hardness, cohesiveness, and gumminess of cooked noodles increased significantly with increase in war gourd juice content. Sensory evaluation results reveal noodles containing 25 and 50% wax gourd juices have higher qualities than other types.

Quality improving effect of dries noodle according to treatment of pine needle seasoning oil (솔잎향미유 처리에 의한 건면의 품질개선 효과)

  • 손무호
    • Culinary science and hospitality research
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    • v.7 no.2
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    • pp.181-194
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    • 2001
  • Dried noodles was manufactured by wheat flour and saline solution mixture. At this time, saline solution mixture was used for simple saline solution and mixture(blending ratio of PNSO and emulsifier=2:1, w/w) of both pine needle seasoning oil (PNSO) manufactured by autoclaving method and food emulsifier. Water absorption ratio, volume expansion ratio and water soluble solid matters content were decreased, but cooking time was prolonged, respectively. According to, suitable treating amount of PNSO was 2-3%(w/w) level. On organoleptic test, the peculiar green color was appeared in cooked noodles of PNSO treating groups. The surface was slickly, chewy rheology and texture were improved at PNSO treating cooked noodle. During 20-30 minutes after cooking, chewy characteristics was maintained the treating groups more than PNSO 2%(w/w). At the result, this PNSO treatin dried noodle samples were suitable at the institutional food service as well as dining hal1 for the case of large scale's kitchen work.

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