• Title/Summary/Keyword: rheological properties

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Maleic Anhydride Effect on the Properties of Poly(ethrlene terephthalate)/Maleic Anhydride-Grafted PP/Poly(styrene-co-maleic anhydride) Ternary Blends (Poly(ethylene terephthalate)/Maleic anhydride-grafted PP/Poly(styrene-co-maleic anhydride) 삼상블렌드의 성질에 있어서의 무수말레인산의 효과)

  • 윤관한;이형욱;박오옥
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.226-232
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    • 2001
  • The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

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Effect of Alum on the Rheological Properties of Gelatinized Solutions of Nonwaxy and Waxy Rice Starches (멥쌀 및 찹쌀전분 호화용액의 리올로지 특성에 미치는 Alum 첨가의 영향)

  • Lee, Shin-Young;Lee, Sang-Gui;Kwon, Ik-Boo
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.776-782
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    • 1995
  • The effects of alum$(Al{\cdot}K(SO_4)_2{\cdot}12H_{2}O)$ on the rheological properties of $3{\sim}9%(w/v)$ gelatinized solutions of nonwaxy and waxy rice starches were investigated to evaluate the possibility of utilizing a starch modifying agent. Gelatinized non-waxy and waxy rice starch solutions showed a pseudoplastic flow behavior with yield stress. Pseudoplasticity of two rice starch solutions increased by the addition of alum$(0.05{\sim}1.0%,\;w/w)$. Alum increased the yield stresses and consistency indexes of two rice starches and these values decreased with increasing starch concentration. Also, alum(0.5%, w/w) increased the flow activation energy of gelatinized waxy rice starch solution and activation energy decreased with increasing waxy rice starch concentration in the range of $3{\sim}7%(w/v)$, but for the nonwaxy rice starch, activation energy decreased at starch concentration of 7%(w/v). From the above results, it was found that alum had the possibility of utilizing a modifying agent for the rheological property of gelatinized starch solution.

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Sensory Characteristics and Rheological Change of Kongdduk (soybean rice cake) depending on Cooking, and Packaging Method (콩떡의 제조 및 저장과 포장에 따른 물성 변화와 관능적 특성)

  • 정혜숙
    • Korean Journal of Human Ecology
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    • v.5 no.2
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    • pp.55-74
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    • 2002
  • This study, observing each respectively packaged Kongdduk during 12-day storing period and comparing it with unpackaged Kongdduk, through a cross-sectional view of its fiber and temperament, through a sensory evaluation rheometer measurement of rheological change depending on storing period and packaging type and through the organic acid content, micro-organic change, and retrogressive process. The results are as follows: 1. Kongdduk made of bean oil shows better chewiness, cohesiveness, and moistness than Kongdduk made of bean flour while Kongdduk made of bean flour shows better rheological properties as to roasted nutty taste or roasted nutty order. 2. The test of the cutted loaves of Kongdduk shows that adding oil of proper proportion to the dough of steamed rice cake in accordance with the amount of rice flour has a good influence on rheological properties of softness. 3. Rice cakes were prepared by addition of yellow soybean flour or peanut flour and packaged with CMP or VP, and their physical characteristics were monitored by sensory evaluation and mechanical measurement while storing for 6 days. For VP samples, yellow soybean rice cake showed little changes in cohesiveness, moistness and chewiness for 6 days of storage, while pure rice cake and peanut rice cake showed an increase in strength and hardness from the 4th day of storage. In case of CMP, yellow soybean rice cake hardly showed a difference in cohesiveness, moistness and chewiness for 6 days, while pure rice cake and peanut rice cake showed a significant difference from the 4th day in sensory evaluation. 4. For rheometer measurement, yellow soybean rice cake with CMP or VP showed little changes in strength or hardness for 6 days, while peanut rice cake and pure rice cake showed a drastic decrease in cohesiveness, from the End day and adhesiveness from the 4th day of storage. As there was no remarkable difference or deterioration for 6 days of storage in yellow soybean rice cake between CMP and VP, the ingredients of rice cakeappeared to be more important than the type of packaging in terms of quality deterioration of rice cake. 5. As the storing period passed by, organic acid is detected less at CMP-packaged Knngdduk than at wrapped. and its increasing speed proves to be slower as well. 6. The one wrapped with plyethylene film began to get moldy from pure rice cake or Kongdduk (rice cake mixed with yellow soybean or peanut) after 6 days, and more and more modly after 9 daysor after 12 days, but the CMP-packaged ones didn't get modly until 12 days or more. 7. CMP-packaged Kongdduk showed higher enthalpy of retrogradation than PE-wrapped one. As storing Period Passed by, Kongdduk,s enthalpy grew high. That is to say, it shows that Kongdduk got retrograded.

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Rheological Properties of Cement Paste Mixed with Aqueously Dispersed Single-Walled Carbon Nanotubes (Single-Walled 탄소나노튜브 수용액 혼입 시멘트 페이스트의 유변학적 특성)

  • Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.2
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    • pp.113-121
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    • 2019
  • Single walled carbon nanotube (SWCNT) has been used as a material for reinforcing various advanced materials because it has superior mechanical properties. However, pure SWCNT that does not have any functional group has a hydrophobic character, and exists as bundles due to the strong Van der Waals attraction between each SWCNT. Due to these reasons, it is very difficult to disperse SWCNTs in the water. In this work, in order to use SWCNT for production of cementitious composites, SWCNT was first dispersed in water to make an aqueous solution. Sodium deoxycholate (DOC) and Sodium dodecyl sulfate (SDS) were chosen as surfactants, and the dosage of DOC and SDS were 2wt% and 1wt%, respectively. Sonication and ultracentrifugation were applied to separate each SWCNT and impurities. Using such processed SWCNT solutions, cement paste was prepared and its shear stress vs. strain rate relationship was studied. The yield stress and plastic viscosity of cement paste were obtained using Bingham model. According to the results in this work, cement pastes made with DOC and SDS showed similar rheological behavior to that of air entrained cement paste. While cement paste made with DOC 2 wt.% SWCNT solution showed similar rheological behavior to that of plain cement paste, cement paste made with SDS 1 wt.% SWCNT solution showed different rheological behavior showing much less yield stress than plain cement paste.

Applied-Mineralogical Characterization and Assessment of Some Domestic Bentonites (II): Mineralogical Characteristics, Surface Area, Rheological Properties, and Their Relationships (국내산 벤토나이트에 대한 응용광물학적 특성 평가 (II): 광물학적 특징, 체표면적 및 유변학적 특성과 그 연계성)

  • 노진환;유재영;최우진
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.33-47
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    • 2003
  • Various applied-mineralogical characterization including measurements of surface area, size distribution, swelling index, and viscosity were done for some domestic bentonites in order to decipher the rheological properties and their controlling factors. The bentonites, which are Ca-type and relatively low-grade (rnontmorillonite contents: 30 ∼ 75 wt%), occur mostly as subhedral lamellas with the size range of 2 ∼ 4 $\mu\textrm{m}$. The size distribution of mineral fractions in bentonite suspension is dominant in the range of 10 ∼ 100 $\mu\textrm{m}$, and though rather complicated, exhibits roughly bimodal patterns. The feature is more conspicuous in the case of zeolitic bentonite. The bentonites have surface areas ranging 269 ∼ 735 $\m^2$/g, which are measured by EGME adsorption method. The EGME surface areas are nearly proportional to the rnontmorillonite contents, moisture contents, or total CEC. In the surface area measurements, zeolitic bentonites have slightly higher values than those zeolite- free types. The measured swelling index and viscosity of domestic bentonites are comparatively low in values. The swelling values of bentonites were measured to be 250∼500% at maximum by progressively mixing amounts of 2 ∼ 5 wt% Na$_2$CO$_3$, which varies depending on the contents of rnontmorillonite and other impurities, especially zeolite. Much amount of sodium carbonate is required for optimum swelling property of zeolitic bentonited which has usually strong Na- exchanged capacity. The bentonites, which are comparatively feldspar-rich and low in size and crystallinity, tend to be higher in viscosity values. Tn addition, the viscosity is largely higher in case of the bentonites with higher pH in suspension. However, the rheological properties of bentonites such as swelling index and viscosity do not show any obvious relationships with rnontmorillonite contents and mean particle size in suspension. In contrast, roughly speaking, the swelling index of bentonites is reversely proportional to the values of surface area which can be regarded as a collective physico-chemical parameter encompassing all the effects caused by mineral composition, surface charge, particle size, morphological farm, and etc. in bentonites. Thus, the rheological properties in bentonite suspension appear to be rather complicated characteristics which mainly depend on the flocculation of clay particles and the mode of particle association, i.e. quasicrystals, controlled by surface charge, morphology, size, and texture of rnon-tmorillonite, and which partly affected by the finer impurities such as zeolite.

Bread Properties Utilizing Extracts of Mume (매실(Prumus mume Sieb. et. Zucc)추출물을 이용한 제빵 적성)

  • 이연화;신두호
    • The Korean Journal of Food And Nutrition
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    • v.14 no.4
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    • pp.305-310
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    • 2001
  • In order to study bread properties utilizing extracts of fume, mume bread was baked, adding 0, 0.5, 1.0. 1.5 and 2.0 brix of mume extract to wheat flour. The rheological properties, dough pH, dough volume, bread volume, bread color. bread texture and sensory evaluation were tested to examine bread properties baked adding extracts of mume. The results are as follows: The maximum viscosity measured by amylograph decreased gradually with increasing fume extract concentration, while the gelatinization temperature was going up. The development time measured by farinograph increased with use of mime extract, but stability time decreased. After the first fermentation, dough volume decreased greatly under pH 4.0, and there was same tendency in loaf volume. Lightness and redness of the crumb decreased but yellowness increased. Hardness and fracturability of mume bread were lower than control. In sensory evaluation, fume bread with 0.5 brix muse extract was evaluated as the best in taste, texture, flavor and overall acceptability.

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Effects of Various Gelling Agents on Textural Properties of Omija Pyon (젤화제를 달리한 오미자(五味子) 편(片)의 질감특성(質感特性) 연구(硏究))

  • Song, Eun-Seung;Chung, Hae-Kyung;Kang, Myung-Hwa
    • Journal of the Korean Society of Food Culture
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    • v.8 no.3
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    • pp.289-293
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    • 1993
  • This study was done to evaluate the effects of various gelling agents on textural properties of omija pyon. As a gelling agent, mungbean starch had been used in traditional omija pyon. In this experiment, gelatin and pectin were also tried for better texture. The results of this study were as follows; 1) One percent pectin addition showed desirable textural properties in both starch and gelatin jelly. 2) No significant effect on rheological values was found according to various sugar concentration(10, 15, 20%). 3) There was a saving effect of sugar concentration when adding 1% pectin to starch jelly, comparing textual properties as sensory scores.

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The Experimental Study on the Influence of Relation between Cement Paste and Aggregate Volume to Effect the High Folwing and Engineering Properties of High Flowing Concrete (고유동콘크리트의 유동특성 및 공학적 특성에 미치는 시멘트페이스트용적 및 골재용적과의 관계에 관한 실험적 연구)

  • 김규용;최희용;강희관;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.301-307
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    • 1996
  • High flowing concrete has been made using a combination of much amount cementitious materials and addition of SP agents, so that it makes possible to high flowing properties of fresh concrete. In the fluid mechanical and rheological point of view, high flowing concrete is affected on the relation between cement paste and aggregate of volume. In this experimental study, it is measured high flowing concrete of slump-flow about 65$\pm$5cm according to 0.54~0.80 of volume ratio and to analysed the properties of high flowing concrete in fresh and hardened concrete. It is the aim of this study to consider the affection of high flowing properties accoring to cement paste to aggregate ratio of volume on the combination of concrete.

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Preparation and Properties of in situ Polymerized Poly(ethylene terephthalate)/Fumed Silica Nanocomposites

  • Hahm, Wan-Gyu;Myung, Hee-Soo;Im, Seung-Soon
    • Macromolecular Research
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    • v.12 no.1
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    • pp.85-93
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    • 2004
  • We have prepared poly(ethylene terephthalate) (PET) nanocomposites filled with two different types of fumed silicas, hydrophilic (FS) and hydrophobic (MFS) silicas of 7-nm diameter, by in situ polymerization. We then investigated the morphological changes, rheological properties, crystallization behavior, and mechanical properties of the PET nanocomposites. Transmission electron microscopy (TEM) images indicate that the dispersibility of the fumed silica was improved effectively by in situ polymerization; in particular, MFS had better dispersibility than FS on the non-polar PET polymer. The crystallization behavior of the nanocomposites revealed a peculiar tendency: all the fillers acted as retarding agents for the crystallization of the PET nanocomposites. The incorporation of fumed silicas increased the intrinsic viscosities (IV) of the PET matrix, and the strong particleparticle interactions of the filler led to an increased melt viscosity. Additionally, the mechanical properties, toughness, and modules of the nano-composites all increased, even at low filler content.

Improvements in the Physical Properties of Agglomerated Milk Protein Isolate/Skim Milk Powder Mixtures Via Fluidized Bed Agglomeration

  • Seo, Chan Won
    • Journal of Dairy Science and Biotechnology
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    • v.40 no.3
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    • pp.134-142
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    • 2022
  • Protein-enriched dairy powder is widely consumed to promote muscle synthesis. Recently, in Korea, elderly people have also begun consuming protein powder products to prevent muscle loss. However, these protein-enriched powders have poor flowability and hydration properties because of the fine particles of spray-dried milk protein powder. Therefore, in this study, the fluidized bed agglomeration process was used to solve these problems. The rheological and physical properties of milk protein isolate (MPI)/skim milk powder (SMP) mixtures were effectively improved via fluidized bed agglomeration. The particle size of the MPI/SMP mixtures significantly increased from 35.7-58 ㎛ to 118-136 ㎛, the flowability level improved from fair (21.4-26.3) to good (15.7-16.3), and the cohesiveness level changed from intermediate (1.27-1.36) to low (1.18-1.19) after fluidized bed agglomeration. In addition, the wetting time of the agglomerated MPI/SMP mixtures was effectively reduced to 4.67-58.3 s by fluidized bed agglomeration. These findings may be useful for manufacturing protein-enriched dairy powders with good instant properties.