• Title/Summary/Keyword: rheological properties

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Preparation and Rheological Characterization of Coal-Water Mixture (석탄-물 혼합연료의 제조와 유변학적 특성화)

  • 김도현
    • The Korean Journal of Rheology
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    • v.10 no.3
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    • pp.131-136
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    • 1998
  • 아역청탄을 이용하여 제조된 CWM(Coal-Water Mixture)연료의 유변학적 특성을 측 정함으로써 음이온 계면활성제 Temol-N, 안정제 Xanthan 및 전해질 등의 첨가제에 대한 성능을 평가하고 최적첨가조성을 결정하였다. 계면확성제의 흡착으로 인해 석탄입자는 음전 하를 띠게 되었고 표면에 전기이중층이 생성되었다. 전기 이중층의 전기적 반발력이 입자의 응집을 막았고 CWA 슬러리의 점도를 감소시켰다. 또한 Xanthan과 NaOH의 첨가로 인해 분산안정성 및 침강안정성이 향상되는 것을 관찰하였다. CWM에서 석탄입자가 차지하는 부 피비를 무게비로 전환하여 표현하고 분산계에서 입자의 부피비에 따른 점도변화를 예측하는 실험식인 Krieger-Dougherty 식과 Frankel-Acrivos 식에 적용하였다. 점도 실험값을 가지 고 식의 변수들을 결정해 본결과 CWM이 나타내는 점도의 석탄함량에 따른 변화를 위 식 들이 비교적 정확시 나타내 주는 것을 확인하였다.

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Rheological Implications of mesomorphic Order in the Lyotropic Liquid Crystalline Polymer Systems (유방성 액정고분자계에 있어서 중간상의 분자배열 규칙성의 유변학적 해석)

  • 김병철
    • The Korean Journal of Rheology
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    • v.9 no.4
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    • pp.200-205
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    • 1997
  • 등방상에서는 폴리파라페닐렌테레프탈아미드(PPD-T)와 히드록시 프로필 셀룰로오 스(HPC)가 비슷한 유변학적 거동을 보였다. 그러나 이방성에서는 네마틱상을 형성하는 PPD-T와 콜레스테릭상(또는 꼬인 네마틱상)을 형성하는 HPC는 상이한 유변학적 특성을 나타냈다. 이방상을 나타내는 임계농도(C*)이상의 농도에서 Herchel-Bulkey 모델에 의해 얻 어진 항복응력을 보면 HPC의 경우 농도에 관계없이 거의 일정한 값을 나타낸 반면PPD-T 의경우에는 농도증가와 더불어 항북응력값이 크게 증가하였다. 또한 PPD-T가 일\ulcorner거으로 HPC보다 큰값의 항복응력을 나타냈다. 진동수 1 rad/s 에서는 PPD-T와 HPCahen 탄성계 수 G'/2G"가 농도의 증가와 더불어 증가하엿다. 그러나 100rad/s 에서는 HPCdmlruddn 임계농도이상의 농도에서 농도증가와 더불어 탄성계수값이 단순감소한 반면 PPD-T의 경우 에는 포화농도(B-point)이상의 농도에서 농도증가와 더불어 탄성계수값이 계속적으로 증가 하였다. HPC의 경우 저장탄성률이 변형정도의 영향을 받지 않았으나 PPD-T의 경우에는 저장탄성률이 변형정도에 매우 민감하였다.

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Manufacture of Aluminum Alloy Rheology Materials Using Spiral Stirring Equipment (나선형 기계 교반 장치를 이용한 Al 합금 레오로지 소재의 제조)

  • Bae, J.W.;Han, S.H.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.17 no.1
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    • pp.9-12
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    • 2008
  • Recently, industries and academic institutes have been interested in the rheology forming technology for light weight materials. However, this rheocasting process has advantages such as the high initial investment cost and the lower mechanical properties than thixocasting. In this study, the continuous fabrication of rheological material with a spiral stirring equipment(mechanical stirring system) was newly devised to overcome the disadvantages of rheocasting process. The experimental parameters were stirring time($0{\sim}1200sec$), stirring velocity ($0{\sim}100rpm$) and stirring temperature($650{\sim}680^{\circ}C$). The optimal conditions for fabricated rheological material of A6061 alloy were stirring time at 300sec, stirring velocity at 60rpm and stirring temperature at $650^{\circ}C$. At these results, the equivalent diameter was $45{\sim}65{\mu}m$, mean roundness was $1.4{\sim}1.6$ and Vickers hardness was 60Hv.

Experimental Evaluation on Shear Modulus of MRE due to MRP Coating and Induced Current (Magnetic Reactive Particle 코팅 및 인가전류에 따른 Magnetorheological Elastomer 의 전단계수 측정)

  • Oh, Jae-Eung;Jeong, Un-Chang;Kim, Jin-Su;Yoon, Jung-Min;Roh, Jeong-Joon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.927-929
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    • 2014
  • MRE(Magneto-rheological Elastomer) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation). Magnetic reactive powder(MRP), having rapid magnetic reaction, was selected as a magnetic particle to give magnetic field reactive modulus. The mechanical properties of manufactured MREs were measured with the application of magnetic field. The analysis of MR effect was carried out by FFT analyzer with various induced current. As induced magnetic field intensity increased and coated with MRP, increment of MR effect was observed.

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Dynamic Properties of Squeeze Type Mount Using MR Fluid (MR유체를 이용한 스퀴즈모드형 마운트의 동특성)

  • 하종용;안영공;양보석;정석권;김동조
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.374-378
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    • 2003
  • This paper presents investigation of damping characteristics of squeeze mode type MR (Magneto-Rheological) mount experimentally. Since damping property of the MR fluid is changed by variation of the applied magnetic field strength, squeeze mode type MR mount proposed in the study has variable damping characteristics according to the applied magnetic field s strength. In the present work, the performance of the mount was experimentally investigated according to the magnetic field strength and exciting frequencies. The experimental results present that the MR mount can effectively reduce the vibration in a wide range of frequency by controlling the applied electromagnetic filed strength. Viscous damping and stiffness coefficients of the MR mount tend to be changed according to the variation of the applied currents in this study and MR effect is reduced by increasing exciting frequency.

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Phase Formation and Rheological Characteristics of LAS Derived from the Monophasic Sol-Gel Route (Sol-Gel 반응으로 유도된 LAS의 상 생성과 점성 특성)

  • 장현명;김광수;정창주
    • Journal of the Korean Ceramic Society
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    • v.28 no.5
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    • pp.365-372
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    • 1991
  • LAS (lithium aluminosilicate) sol was synthesized using the hydrolysis-condensation reaction of TEOS, chelated Al(OBus)3 and Li-salt with H2O in alcohol (EtOH+2-Propanol) medium. Effects of important reaction parameters on the properties of sol and gel-derived LAS were examined. The crystallization of the sol-gel derived LAS with ${\beta}$-spodumene composition began at ∼600$^{\circ}C$, and a series of polymorphic transformations occurred as temperature was increased to 1100$^{\circ}C$: amorphous LAS\longrightarrowhexagonal LiAl(SiO3)2\longrightarrow${\beta}$-spodumene. Lowering Li content in the gel enhanced densification and retarded the crystallization significantly. Optimum reaction conditions of LAS sol formation for thin coating applications were derived from rheological measurements, and these can be summarized as: H2O/total alkoxides molar ratio=4, pH=∼2.5, and aging time of ∼250h.

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Surface Tension of Magneto-Rheological Fluids

  • Rahimi, Shai;Weihs, Daniel
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.261-265
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    • 2016
  • Surface tension is a major factor in the thermodynamics as well as fluid properties of Magneto-Rheological Fluids (MRF). We measured the surface tension of an MRF using two different methods. A wettability characterization based on contact angles measurements for the fluid interacting with two different surfaces was conducted. A hydrocarbon based commercial MRF with more than 80% solid weight, placed on quartz and poly-tetra-fluoroethylene (PTFE) surfaces was used. We measured the fluids' surface tension value by means of contact angles measurements and by the falling drop method.

Effects of Monosaccharides and Disaccharides on the Rheological Behavior of Dense Alumina Slurries I. Creep Testing Method

  • Kim, Jong-Cheol;Auh, Keun-Ho;Chr
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.104-109
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    • 1999
  • Rheological properties of dense slurries over 45 volume % with different monosaccharides and disaccharides were checked in order to increase the solid content of dense slurries without sacrificing plasticity using creep testing method. Strain in creep test showed good correlations with Burger model which is expressed as an exponential function of time. Among several monosaccharides and disaccharides studied here, fructose and sucrose were most effective in making dense alumina slurry plastic than other monosaccharides and disaccharides like glucose, galactose, xyloss and maltose. In the case of dense alumina slurry with sucrose, sucrose content or additional water content enhanced to the plasticity of the slurries.

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Dynamic Properties of Squeeze Type Mount Using MR Fluid (MR 유체를 이용한 스퀴즈모드형 마운트의 동특성)

  • 안영공
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.13 no.6
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    • pp.490-495
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    • 2003
  • This paper presents investigation of damping characteristics of squeeze mode type MR (magneto-rheological) mount experimentally. Since damping property of the MR fluid is changed by variation of the applied magnetic field strength, squeeze mode type MR mount proposed in the study has variable damping characteristics according to the applied magnetic field strength. In the present work, the performance of the mount was experimentally Investigated according to the magnetic field strength and exciting frequencies. The experimental results present that the MR mount can effectively reduce the vibration in a wide range of frequency by controlling the applied electromagnetic field strength. Viscous damping and stiffness coefficients of the MR mount tend to be changed according to the variation of the applied currents in this study and MR effect is reduced by increasing exciting frequency.

Dynamic Rheological Comparison of Selected Gum Solutions

  • Choi, Su-Jin;Chu, So-Young;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.15 no.3
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    • pp.474-477
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    • 2006
  • Dynamic rheological properties of commercial 0.8, 1.0, and 1.2% gums [carboxylmethylcellulose (CMC), guar gum, hydroxypropylmethylcellulose (HPMC), tara gum, and xanthan gum], which can be dissolved in cold water, were investigated by small-deformation oscillatory measurements. Magnitudes of storage (G') and loss (G") moduli increased with increasing concentration of gum solutions except for xanthan gum. Guar gum exhibited greatest G' and G" values among all gums except for G' value at 0.8% concentration. Slopes of G' and G" decreased with increasing concentration of gum solutions except for xanthan gum. Tan ${\delta}$ (G"/G') values decreased with increasing concentration of gum solutions except for xanthan gum. Tan ${\delta}$ values of xanthan gum solutions were much lower than those of other gum solutions, indicating that xanthan gum solutions were predominantly more elastic than viscous.