• 제목/요약/키워드: rheological characterization

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Mold-Flow Simulation in 3 Die Stack Chip Scale Packaging

  • Rhee Min-Woo
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2005년도 ISMP
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    • pp.67-88
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    • 2005
  • Mold-Flow 3 Die Stack CSP of Mold array packaging with different Gate types. As high density package option such as 3 or 4 die stacking technologies are developed, the major concerning points of mold related qualities such as incomplete mold, exposed wires and wire sweeping issues are increased because of its narrow space between die top and mold surface and higher wiring density. Full 3D rheokinetic simulation of Mold flow for 3 die stacking structure case was done with the rheological parameters acquired from Slit-Die rheometer and DSC of commercial EMC. The center gate showed severe void but corner gate showed relatively better void performance. But in case of wire sweeping related, the center gate type showed less wire sweeping than corner gate types. From the simulation results, corner gate types showed increased velocity, shear stress and mold pressure near the gate and final filling zone. The experimental Case study and the Mold flow simulation showed good agreement on the mold void and wire sweeping related prediction. Full 3D simulation methodologies with proper rheokinetic material characterization by thermal and rheological instruments enable the prediction of micro-scale mold filling behavior in the multi die stacking and other complicated packaging structures for the future application.

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Pseudomonas elodea에 의해서 생산된 Gellan gum과 Agar의 rheology 특성 비교연구 (Study on rheological characterization of Gellan gum Produced by Pseudomonas elodea -Comparative Studies on Rheological Characterization of Gellan gum and Agar-)

  • 권혜숙;구성자
    • 한국식품조리과학회지
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    • 제4권1호
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    • pp.17-26
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    • 1988
  • The polysaccharide produced by pseudomonas elodea, Gellan gum, was rheologically characterized, compared with agar. Rheological properties were determined from the change in the value of intrinsic viscosity with the pH and salt concentration. At the range of pH 2∼ll and salt 0∼0.16M KC1, the intrinsic viscosity of Gellan gum ranged from 8.8 to 21.2dl/g and agar ranged from 1.97 to 11.46d1/g. In the absence of salt, the intrinsic viscosity of Gellan gum increased as the pH of solution increased up to neutral pH then decreased slightly at alkaline pH, whearas the intrinsic viscosity of agar increased as the pH of solution increased up to pH 9 then decreased slightly. Intrinsic viscosity of Gellan gum and agar decreased with an increase in salt concentration. The chain stiffness parameter for the Gellan gum was 0.033. The overlap parameter of Gellan gum and agar were 0.047g/dl and 0.087g/dl, respectively. Gellan gum and agar were shear rate dependent or pseudoplastic. The yield stress and proportionality constant of Gellan gum increased slightly as the concentration increase, on the other hand, the shear index of Gellan gum showed a maximum at 0.75g/dl and gradually decreased as the concentration increase. The apparent viscosity of Gellan gum and agar decreased as the temperature increase. A lower concentration of the divalent cations calcium and magnesium is required to obtain maximum gel strength than for the monovalent cations sodium and potassium.

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Rheological, physico-mechanical and durability properties of multi-recycled concrete

  • Rahmani, Abdessamed Azzaz;Chemrouk, Mohamed;Ammar-Boudjelal, Amina
    • Advances in concrete construction
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    • 제9권1호
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    • pp.9-22
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    • 2020
  • The present work looks at the possibilities of recycling more than once demolished concrete as coarse aggregates, to produce new concrete. Different concrete mixes were made with substitutions of 50%, 75% and 100% of recycled concrete aggregates respectively as coarse aggregates. The physico-mechanical characterization tests carried out on the recycled concrete aggregates revealed that they are suitable for use in obtaining a structural concrete. The resulting concrete materials had rheological parameters, compressive strengths and tensile strengths very slightly lower than those of the original concrete even when 100% of two cycles recycled concrete aggregates were used. The durability of the recycled aggregates concrete was assessed through water permeability, water absorption and chemical attacks. The obtained concretes were thought fit for use as structural materials. A linear regression was developed between the strength of the material and the number of cycles of concrete recycling to anticipate the strength of the recycled aggregates concrete. From the results, it appear clear that recycling demolished concrete represents a valuable resource for aggregates supply to the concrete industry and a the same time plays a key role in meeting the challenge for a sustainable development.

Properties and particles dispersion of biodegradable resin/clay nanocomposites

  • Okada, Kenji;Mitsunaga, Takashi;Nagase, Youichi
    • Korea-Australia Rheology Journal
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    • 제15권1호
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    • pp.43-50
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    • 2003
  • In this study, two types of biodegradable resins-based clay nanocomposites, in which organic montmorillonite clay was filled, were prepared by the direct melt blending method. In order to characterize the nanocomposite structure, wide-angle X-ray diffraction (WAXD) and TEM observation were performed. Characterization of the nanocomposites shows that intercalated and partially exfoliated structures were generated by the melt blending method. Mechanical and rheological properties of the nanocomposites were measured respectively. For the mechanical properties, there were improvements in tensile strength and Young's modulus of the nanocomposites due to the reinforcement of nanoparticles. The rheological behaviors of the nanocomposites were significantly affected by the degree of the dispersion of the organoclay. The storage modulus of the nanocomposites was measured and the degree of the dispersion of the organoclay was evaluated from the value of the terminal slope of the storage modulus. In addition, the quantity of the shear necessary for making the nanocomposite for melt intercalation method was estimated from the relationship between the value of the terminal slope of the storage modulus and the applied shear.

Processing and Characterization of Liquid Crystalline Copoly-(ethylene terephthalate-co-2 (3)-chloro-1,4-phenylene terep hthalate)/Polycarbonate Blends

  • Rhee, Do-Mook;Ha, Wan-Shik;Youk, Ji-Ho;Yoo, Dong-Il
    • Fibers and Polymers
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    • 제2권3호
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    • pp.129-134
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    • 2001
  • Liquid crystalline (LC) poly(ethylene terephthalate-co-2(3)-chloro-1,4-phenylene terephthalate) (50/50, mole/mole) [PECPT] was synthesized and blended with polycarbonate (PC). LC properties of PECPT and thermal, morphological, and rheological behaviors of the PECPT/PC blend were studied. PECPT showed the nematic LC phase and much longer relaxation time than poly(ethylene terephthalate) (PET). The apparent melt viscosity of PECPT was one third of that of FET. An abrupt torque change was observed during the blending process due to the orientation of LC domains. For the blends containing 10~30 wt% of PECPT, the complex viscosities were higher than that of PC. As PECPT content increases above 40 wt%, shear thinning was observed. The lowest complex viscosity was obtained at 40~50 wt%. Transesterification of PECPT and PC was confirmed by the selective chemical degradation of carbonate groups in PC.

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Rheological characterization of nanoparticle filled polymeric systems

  • Kim, Byoung-Chul;Chae, Dong-Wook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.219-219
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    • 2006
  • This study focuses on the effects of dispersion method of a nanoparticle in a polymer matrix such as melt mixing, solution blending, and in-situ polymerization on the physical properties of the nanocomposites. Introduction of a nanoparticle to a polymer resulted in some unusual physical properties. In some cases the nanoparticle played a role of a nucleating agent, leading to decreasing induction time to crystallization. In addition, the dispersion state of the nanoparticle in the polymer matrix also had a significant influence on the physical properties of the nanocomposites. Hence the method of introducing the nanoparticle to the polymer made contribution to the rheological properties of the nanocomposite systems.

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Characterization and processing of Biodegradable polymer blends of poly(lactic acid) with poly(butylene succinate adipate)

  • Lee, Sang-Mook;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제17권2호
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    • pp.71-77
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    • 2005
  • We investigated thermal, rheological, morphological and mechanical properties of a binary blend of poly(lactic acid) (PLA) and poly(butylene succinate adipate) (PBSA). The blends were extruded and their molded properties were examined. DSC thermograms of blends indicated that the thermal properties of PLA did not change noticeably with the amount of PBSA, but thermogravimetric analysis showed that thermal stability of the blends was lower than that of pure PLA and PBSA. Immiscibility was checked with thermal data. The rheological properties of the blends changed remarkably with composition. The tensile strength and modulus of blends decreased with PBSA content. Interestingly, however, the impact strength of PLA/PBSA (80/20) blend was seriously increased higher than the rule of mixture. Morphology of the blends showed a typical sea and island structure of immiscible blend. The effect of the blend composition on the biodegradation was also investigated. In the early stage of the degradation test, the highest rate was observed for the blend containing $80wt\%$ PBSA.