• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2269-2279
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• 2009

Six metal-free organic dyes having thiophene (1), benzene-thiophene (2), thiophene-benzene (3), thiophene-pyridine (4), thiophene-thiophene (5), and pyridine (6) linkers between 9,9-dimethylfluorenyl terminal group and $\alpha$-cyanoacrylic acid anchor were synthesized. Among them, organic dye 5 showed the longest ${\lambda}_{max}$ value (424 nm) in UV-Vis absorption spectrum, better incident monochromatic photon-to-current conversion efficiency (IPCE), highest short circuit photocurrent density ($J_{SC},\;9.33\;mA^2/cm^2$), and highest overall conversion efficiency ($\eta$, 3.91%).