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Complex Formation between 3CaO.$Al_2O_3$ and Sodium Gluconate (3CaO.$Al_2O_3$와 글루콘산 나트륨간의 착체형성)

  • 김창은;이승헌;이승규
    • Journal of the Korean Ceramic Society
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    • v.27 no.7
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    • pp.883-890
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    • 1990
  • Although various theories have been presented on the mechanism of setting retardation of 3CaO·Al2O3, this phenomenon has not yet been defined. The present investigation was initiated in order to solve the mechanism from the view point of coordination chemistry. The solubility of Ca(OH)2 in aquous solution of soldium gluconate was abnormally high, and was proportional to the concentration of sodium gluconate. These phenomena were attributed to the soluble complex formation, that is, (1 : 1)Ca complex formation between calcium ion and gluconate ion. The author's proposal was further confirmed by the results of electrical conductivity measurement. The formation of calcium complex was also supported by IR spectra and DTA. When sodium gluconate was dissolved in 3CaO·Al2O3 suspension, calcium complex and aluminum complex were formed. As an experimental evidence, the asymmetric stretching vibration of carboxyl group in sodium gluconate was observed to be shifted to lower frequency from 1625cm-1 to 1585cm-1 characteristically. The characteristic exothermic peaks of the complexs at 430℃ and 700℃ observed in DTA curve also suggest the formation of the complexs between sodium gluconate and 3CaO·Al2O3.

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Corrosion Behavior of TiN Ion Plated Steel Plate(I)-Effects of Ti interlayer and TiN coating thickness (TiN 이온 플레이팅한 강판의 내식성에 관한 연구(I)-Ti 하지 코팅 및 TiN 코팅 두께의 영향)

  • Yeon, Yun Mo;Han, Jeon Geon;Kim, Dae Jin;Bae, Eun Hyeon
    • Journal of the Korean institute of surface engineering
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    • v.24 no.1
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    • pp.34-34
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    • 1991
  • Corrosion behavior of TiN coated steel was studied in terms of thickness of interlayer Ti and TiN coating TiN was are ion plated to a thickness of 1$\mu\textrm{m}$ and 2$\mu\textrm{m}$ respectively with interlayer coating of Ti of 1$\mu\textrm{m}$, 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$. Corrosion resistance of TiN coated steel was evaluated by anodic palarization test in 1N H2SO4 as well as salt spray test. Porosity of each coating was also tested by using SO2 test method. Corrosion current density decreased with increasing TiN coating thickness and Ti interlayer coating markedly enhanced the corrosion resistance. Ti interlayer coating of 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$ prior to 2$\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 2. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ti interlayer. Ti interlayer coating was also very effective in improvement of corrosion resistance under salt atmosphere.

The Effects of Therapeutic Horseback Riding on Equilibrium for Children with Disabilities

  • Kang, Ok-Deuk;Kang, Anna;Ryu, Youn-Chul;Lee, Wang-Shik
    • Journal of Animal Science and Technology
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    • v.55 no.2
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    • pp.141-146
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    • 2013
  • This study was performed on 26 disabled adolescent participants (16 male, 10 female) with the objective of testing changes in equilibrium after engagement in horseback riding. Participants of total 26 persons were divided into three groups as follows: 6 children with Cerebral Palsy (CP), 14 children with Intellectual Disability (ID) and 6 children with Autism (AT). Participants engaged in therapeutic horseback riding (TR) two times per week for 30 minutes per session. The 26 participants demonstrated a considerable increase in equilibrium ability, with an average increase in equilibrium time of $44.22{\pm}50.70$ sec after TR. Equilibrium also increased according to disability group: CP (P < 0.05), ID (P < 0.001), and AT (P < 0.05). TR should be considered as a possible method for improving functionality in the physically disabled. This data may also be usefully applied to the development of a horseback riding program for the improvement of equilibrium in the disabled.

Congenital Anonychia with Ectrodactyly of 5th Finger (원위지골 결손을 동반한 제 5수지의 선천성 무조갑증의 치험례)

  • Kim, Kook Hyun;Kim, Cheol Hann;Kang, Sang Gue;Tark, Min Sung
    • Archives of Plastic Surgery
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    • v.34 no.3
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    • pp.406-408
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    • 2007
  • Purpose: Despite a high frequency of acquired nail disease, congenital absence of the nail, also called as anonychia, is a rare anomaly. It may be seen as an isolated of phalangeal bone(ectrodactyly), nail-patella syndrome, birth trauma, impaired peripheral circulation, alopecia areata, and pemphigus, idiopathic atrophy of the nail, bullous drug eruptions, periodic shedding, lichen planus, Stenvens-Johnson syndrome and so forth. Methods: We have experienced a rare case of 40-day-old neonate, suffering from intrauterine growth retardation, but without familial history, chromosomal anomalies or any other diseases. Results: There was no nail on left 5th finger and distal phalangeal bone of same finger. So, We diagnosed as Congenital Anonychia with ectrodactyly of 5th Finger. Conclusion: We report this case as congenital anonychia of 5th finger which have developed from underlying distal phalangeal ectrodactyly. We also review other reported cased in the literatures.

Arsenic Toxicity in Male Reproduction and Development

  • Kim, Yoon-Jae;Kim, Jong-Min
    • Development and Reproduction
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    • v.19 no.4
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    • pp.167-180
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    • 2015
  • Arsenic is a toxic metalloid that exists ubiquitously in the environment, and affects global health problems due to its carcinogenicity. In most populations, the main source of arsenic exposure is the drinking water. In drinking water, chronic exposure to arsenic is associated with increased risks of various cancers including those of skin, lung, bladder, and liver, as well as numerous other non-cancer diseases including gastrointestinal and cardiovascular diseases, diabetes, and neurologic and cognitive problems. Recent emerging evidences suggest that arsenic exposure affects the reproductive and developmental toxicity. Prenatal exposure to inorganic arsenic causes adverse pregnancy outcomes and children's health problems. Some epidemiological studies have reported that arsenic exposure induces premature delivery, spontaneous abortion, and stillbirth. In animal studies, inorganic arsenic also causes fetal malformation, growth retardation, and fetal death. These toxic effects depend on dose, route and gestation periods of arsenic exposure. In males, inorganic arsenic causes reproductive dysfunctions including reductions of the testis weights, accessory sex organs weights, and epididymal sperm counts. In addition, inorganic arsenic exposure also induces alterations of spermatogenesis, reductions of testosterone and gonadotrophins, and disruptions of steroidogenesis. However, the reproductive and developmental problems following arsenic exposure are poorly understood, and the molecular mechanism of arsenic-induced reproductive toxicity remains unclear. Thus, we further investigated several possible mechanisms underlying arsenic-induced reproductive toxicity.

Corrosion Behavior of TiN Ion Plated Steel Plate(I) -Effects of Ti interlayer and TiN coating thickness- (TiN 이온 플레이팅한 강판의 내식성에 관한 연구(I) - Ti 하지 코팅 및 TiN 코팅 두께의 영향 -)

  • 연윤모;한전건;김대진;배은현
    • Journal of the Korean institute of surface engineering
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    • v.25 no.1
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    • pp.34-39
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    • 1992
  • Corrosion behavior of TiN coated steel was studied in terms of thickness of interlayer Ti and TiN coating. TiN was arc ion plated to a thickness of 1$\mu\textrm{m}$ and 2$\mu\textrm{m}$ respectively with interlayer coating of Ti of 1$\mu\textrm{m}$, $2\mu\textrm{m}$ and $3\mu\textrm{m}$. Corrosion resistance of TiN coated steel was evaluated by anodic palarization test in 1N $H_2$SO$_4$ as well as salt spray test. Porosity of each coating was also tested by using $SO_2$ test method. Corrosion current density decreased with increasing TiN coating thickness and Ti interlayer coating markedly enhanced the corrosion resistance. Ti interlayer coating of $2\mu\textrm{m}$ and $3\mu\textrm{m}$ prior to $2\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 2. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ti interlayer. Ti interlayer coating was also very effective in improvement of corrosion resistance under salt atmosphere.

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Endogenous retinoic acid mediates the early events in salamander limb regeneration

  • Lee, Eugene;Ju, Bong-Gun;Kim, Won-Sun
    • Animal cells and systems
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    • v.16 no.6
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    • pp.462-468
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    • 2012
  • Urodeles including newt and salamander have remarkable regenerative capacity during the postembryonic life span. Some of the unique features are the formation of the well-developed wound epidermis and the active dedifferentiation process in the early phase of regeneration. These are regarded as key events for the successful regeneration since no further regenerative activity is possible without them. In this study, we investigated the role of retinoic acid (RA) in salamander limb regeneration by blocking RA synthesis using disulfiram, an inhibitor of aldehyde dehydrogenase that oxidizes retinal to RA. Disulfiram treatment resulted in delaying the limb regeneration processes via inhibition of wound epidermis formation and dedifferentiation process. When RA was administered after disulfiram treatment, the inhibitory effect of disulfiram was rescued. In addition, disulfiram treatment after the dedifferentiation stage resulted in the mild retardation of limb regeneration, suggesting that RA might also be involved in the blastema outgrowth. Furthermore, salamander MMP-9 gene expression was also inhibited by disulfiram treatment. Collectively, our findings indicate that endogenous RA may play an important role(s) in the early phase of limb regeneration by regulating the expression of molecules responsible for the modification of intracellular and extracellular environment during salamander limb regeneration.

Corrosion Behavior of TiN Ion Plated Steel Plate(II)-Effects of Ni and Ni/Ti interlayers- (TiN 이온 플레이팅한 강판의 내식성에 관한 연구 (II)-Ni 및 Ni-Ti 하지코팅의 영향-)

  • 한전건;연윤모;홍준희
    • Journal of the Korean institute of surface engineering
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    • v.25 no.2
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    • pp.82-89
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    • 1992
  • The effect of interlayer coating of Ni and Ti on corrosion behavior was studied in TiN ion plated steel plate. Interlayer coating was carried out in a single and bi-layer to a various thickness combination prior to final TiN coating of $2\mu\textrm{m}$. Corrosion behavior was evaluated by anodic polarization test in 1N H2SO4 as well as salt spray test. Porosity of each coating was also tested by using SO2 test. Corrosion resistance was improved with increasing the thickness of Ni interlayer coating and Ni-Ti interlayer coating markedly enhanced the corrosion resistance. Ni/Ti interlayer coating of $2\mu\textrm{m}$/2$\mu\textrm{m}$ prior to $2\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 1. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ni and Ti interlayers, Ni/Ti interlayers coating were also very effective in improvement of corrosion resistance under salt atmosphere.

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Effect of Anisotropy on Fatigue Crack Propagation Rate and Arrest Behavior with 2024-T3 Alumunum Alloy (2024-T3 A1 합금의 이방성이 피로균열진전속도와 정류거동에 미치는 영향)

  • 오세욱;김태형;오정종
    • Journal of Ocean Engineering and Technology
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    • v.7 no.1
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    • pp.124-132
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    • 1993
  • In order to examine the effect of anisotropy and stress ratio on fatigue crack propagation rate and opening-closing behavior and also arrest behavior by single tension peak overload, the fatigue tests of constant amplitude atress and single tension peak overload adding to cycle of constant amplitude were carried out in stress ratio of -0.4, -0.2, and 0.4 with materials of T-L and L-T directions in 2024-T3 aluminum alloy plate. Crack opening-closing begavior were measured by the compliance method using COD gage and strain gage. In case of the crack opening-closing behavior was measured by strain gage, the effect of stress ratio is unchangeable. But in the case of COD gage, that is remarkably decreased. Fictitious effective stress intensity factor(U sub(f)) and effective stress intensity factor ratio(U) in L-T direction was higher than those in T-L direction and also threshold arrest overload ratio incrased as stress ratio decreased and that of T-L direction was higher than that in L-T direction.

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The clinical study of Digital lnfrared Thermographic Imaging on Depressed patients (우울증환자(憂鬱症患者)의 전신체열촬영(全身體熱撮影)에 의한 임상적(臨床的) 연구(硏究))

  • Kim, Tae-Heon;Lee, Yong-Keun
    • Journal of Oriental Neuropsychiatry
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    • v.11 no.1
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    • pp.59-73
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    • 2000
  • Depression is a psychiatric syndrom consisting of dejected mood, psychomotor retardation, insomnia and weight loss, sometimes associated with irrational guilt feeling. And it is also similiar to Hwa-byung(火病) symptom in oriental medicine. But it is difficult to diagnose with objective method. Digital Infrared Thermographic Imaging(D.I.T.I.) is one of diagnotic method that measure the changes of skin temperature in body. Specially we checked the skin temperature on depressed patients by using D.I.T.I. and compared with Bell's palsy patients and normal persons group. The results are as follows; Average body temperature of the depressed patient group is $36.68{\pm}0.43^{\circ}C.$ and that of the control group is $36.73{\pm}0.40^{\circ}C.$. So there is no meaningful difference. The depressed patient group has higher temperature than the control group by ${\triangle}T>1.0^{\circ}C$ at the following acupuncture points in these body parts - upper and lower, left and right, anterior and posterior. When acupuncture points temperature was compared superior and inferior part of the body, depressed patient group have meaningful difference at the GV-4(Myung-moon) and also in the control group. When acupuncture points temperature was compared left and right part of the body, depressed patient group have no meaningful difference and also in the control group. When acupuncture points temperature was compared in the anterior and posterior part of the body, depressed patient group have meaningful difference at the GV-4(Myung- moon) and also in the control group. From this study, we think that D.I.T.I. could be used to diagnose objectively on the depressed patients and useful to another psychoneurogenic diagnosis in oriental medicine.

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