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Core-shell TiO2/Ag Nanoparticle Synthesis and Characterization for Conductive Paste (전도성 페이스트용 코어-쉘 TiO2/Ag 나노입자의 합성 및 특성 연구)

  • Sang-Bo, Sim;Jong-Dae, Han
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.36-44
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    • 2023
  • Core-shell TiO2/Ag nanoparticles were synthesized by a modified sol-gel process and the reverse micelle method using acetoxime as a reducing agent in water/dodecylbenzenesulfonic acid (DDBA)/cyclohexane. The structure, shape, and size of the TiO2/Ag nanoparticles were investigated using X-ray diffraction (XRD), UV-visible spectroscopy, scanning electron microscope (SEM), transmission electron microscope (TEM), and thermogravimetric analysis (TGA). The size of TiO2/Ag nanoparticles could be controlled by changing the [water]/[DDBA] molar ratio values. The size and the polydispersity of TiO2/Ag nanoparticles increased when the [water]/[DDBA] molar ratio rose. The resultant Ag nanoparticles over the anatase crystal TiO2 nanoparticles exhibited a strong surface plasmon resonance (SPR) peak at about 430 nm. The SPR peak shifted to the red side with the increase in nanoparticle size. Conductive pastes with 70 wt% TiO2/Ag nanoparticles were prepared, and the pastes were coated on the PET films using a screen-printing method. The printed paste films of the TiO2/Ag nanoparticles demonstrated greater surface resistance than conventional Ag paste in the range of 405~630 μΩ/sq.

Evaluation of Shear Bond Strength of Various Orthodontic Bracket Bonding Agents (수종의 교정용 브라켓 접착 레진의 전단 강도 평가)

  • Youngjun, Ham;Miran, Han
    • Journal of the korean academy of Pediatric Dentistry
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    • v.49 no.3
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    • pp.264-273
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    • 2022
  • Due to the development of properties of adhesive materials currently used in dentistry, the bonding ability between the brackets and the tooth enamel has been greatly improved. In general, in situations where cooperation can be obtained, adhesion of the orthodontic bracket through the conventional three-step process can show excellent bonding strength. However, if it is difficult to expect patient cooperation, as in the pediatric dentistry area, or if moisture isolation is not properly performed, the binding strength that does not reach the expected effect. As a result, various products that simplify the process for adhesion are being developed. The aim of this study was to evaluate and compare the shear bonding strength between the conventional 3-step adhesion system, self-etching primer system and one-step adhesion system that reduces the priming process. A total of 60 human maxillary, mandibular premolars were prepared. Group I (control group) were followed conventional 3-step bonding process. Group II were conditioned with self-etching primer. Group III were etched with 37% phosphoric acid and brackets were bonded with self-priming adhesive. The resultant shear bond strength of each group was measured and an adhesive remnant index (ARI) was recorded. The mean shear bond strength of group I, II, III were 14.69 MPa, 11.21 MPa and 12.21 MPa respectively. Significant differences could only be found between group I, II and group I, III (p < 0.05). The ARI indicated no significant difference among all groups.

Effect of COVID-19 Pandemic on Negative Emotions in Korean College Students (코로나바이러스(COVID-19) 유행이 대학생의 부정정서에 미치는 영향)

  • Jang, Jun-Hyuk;Park, Seung-Hee;Kim, Jin-Hwi;Kim, Jongwan
    • Science of Emotion and Sensibility
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    • v.24 no.4
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    • pp.39-52
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    • 2021
  • This study aims to investigate the effect of the coronavirus disease 2019 (COVID-19) epidemic on negative emotions, such as anxiety, depression, fear, and stress, in Korean college students. The study recruited students from J University and conducted interviews across three time points, namely, March 2019, March 2020, and November 2020. For three time points, the participants responded to structured questions about situations they may have encountered and they were asked to summarize their responses. Repeated-measures ANOVAs were performed to examine whether differences exist in negative emotions between time points. Furthermore, polynomial trend analyses were conducted to examine resultant patterns over time. The results revealed that negative emotions displayed significant differences between time points. Moreover, trend analyses revealed a curvilinear pattern, which indicates that negative emotions increased and were then sustained. These findings suggest that negative emotions may continue to become prevalent among college students with the increased impacts of the ongoing COVID-19 pandemic. The study discussed the need for psychological support systems, such as stress management and psychological counseling, for college students.

Effect of DNA Conformation on Genomic Integration of Transgenes and Its Implications on Integration Mechanism (외래유전자의 게놈내 삽입에 있어서 DNA형태가 미치는 영향)

  • Kang, Y.K.;Park, J.S.;Lee, C.S.;Han, Y.M.;Lee, K.K.
    • Korean Journal of Animal Reproduction
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    • v.25 no.3
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    • pp.237-242
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    • 2001
  • We recently demonstrated that both linear- and supercoil-form B1/B2 SINE (short interspersed elements) sequences could increase an integration frequency of a reporter gene in preimplatation mouse embryos. In those reports, when either a control or SINE-flanked DNA was separately applied to microinjection, the proportions of $\beta$-gal positives were 16% and 63%, respectively, in linear-form DNA, and 6% and 25%, respectively, in circular-form DNA. Here, we examined the contribution of a circular-form DNA moiety to integration frequency by using a mixed-farm (linear and circular-form) DNA in microinjection. When examined in the blastocyst stage, the proportion of $\beta$-gal-positive embryos was 17.3% and 46.6% in control and SINE-flanked DNA, respectively. These results suggest that there is little contribution of circular-form DNA moiety to the resultant integration frequency, and that the majority of the integration events are mediated through a linear conformation of vector DNA. In addition, some clues on integration process could be obtained from the analysis of microinjection results.

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Assessment of Formwork-Seepage Minimization in High Fluidity, Normal Strength Concrete Utilizing Thixotropic Properties (고유동 일반강도 콘크리트의 요변성 부여에 따른 거푸집 누출 저감 성능 분석)

  • Kim, Young-Ki;Lee, Yu-Jeong;Kim, In-Tae;Han, Dong-Yeop
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.337-348
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    • 2023
  • The central objective of this study is to curtail the leakage of mortar or cement paste, often resultant of ill-constructed formwork, by implementing thixotropy in the formulation of high-fluidity, standard-strength concrete. When such concrete is utilized in smaller scale construction projects, instances of formwork gaps due to suboptimal construction precision may lead to significant leakage of mortar and paste, a problem not typically encountered with traditional slump-flow concrete. In this investigation, Polyvinyl Alcohol(PVA) and borax are incorporated into the concrete mixture to induce thixotropy. The experimental design includes varying methodologies for integrating PVA and borax, while assessing alterations in diverse concrete performances, including thixotropy and leakage reduction potential that simulates formwork gap conditions. Under the experimental conditions defined within this study, it was found that replacing, rather than merely adding PVA and borax, aids in averting water addition via suspensions. This approach yielded promising results in terms of concrete properties and proved efficacious in stemming leakage in concrete possessing sufficient thixotropy. Notably, when a 6% PVA suspension was substituted, a significant reduction in leakage was observed. Consequently, it is projected that construction quality can be ensured, even with lower precision formwork, by applying thixotropy to concrete through the use of PVA and borax.

Quantitative Analysis on Intensity of 1936 Jirisan Earthquake by Estimating Seismic Response Characteristics at the Site of Five-story Stone Pagoda in Ssang-gye-sa (쌍계사 오층 석탑 부지의 지진 응답 특성 평가를 통한 1936년 지리산 지진 세기의 정량적 분석)

  • Sun, Chang-Guk;Chung, Choong-Ki;Kim, Jae-Kwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.3C
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    • pp.187-196
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    • 2008
  • An earthquake of magnitude 5.0 occurred at Ssang-gye-sa, a Buddhist temple in Jirisan, located near the southern border of the Korean peninsula on 4 July 1936. It resulted in severe damage of several buildings and structures in Ssang-gye-sa. Particularly, the top component of a five-story stone pagoda in the temple was tipped over and fell down during the earthquake. This earthquake damage case would be usefully applied to estimating the intensity of ground motion in the Korean peninsula, a moderate seismicity region, where strong motion has never been recorded with the exception of historic seismic events. In order to estimate the local site effects and the corresponding ground motion at Ssang-gye-sa site, intensive site investigations including borehole drilling and in-situ seismic tests such as crosshole and SASW tests were performed in the temple area. Based on the site characteristics, site-specific seismic response analyses using various input motions were conducted for a representative Ssang-gye-sa site by means of both one-dimensional equivalent-linear and nonlinear methods with six input rock outcrop acceleration levels ranging from 0.044g to 0.220g. The resultant site-specific seismic responses indicated the amplified ground motions in the short-period range near the site period of Ssang-gye-sa. Furthermore, the intensity on rock outcrop of the 1936 Jirisan earthquake was estimated by making a comparison between the site responses analysis results in this study and the full-scaled seismic test of pagoda model in the prior study.

Grinding Characteristics of Domestic Sericite using a Planetary Ball Mill (유성밀에 의한 국내 견운모 광석의 분쇄 특성)

  • Hee-Young Shin;Sang-hun Lee
    • Resources Recycling
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    • v.32 no.3
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    • pp.18-25
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    • 2023
  • Sericite was ground with or without additives (LiNO3 or TiO2) using a planetary mill. The resultant ground products included the average particle size of 2-3 ㎛ (sericite only or sericite+LiNO3) and 0.5-0.6 ㎛ (sericite+TiO2) were obtained within 10 minutes of grinding time. respectively. In the grinding of the sericite without any addictive, the particle size initially decreased, but, as grinding time elapsed thereafter, agglomerates were formed and D50 increased over 10 ㎛. In contrast, when the additive was added, the particle size decreased as the grinding time elapsed and any aggregation was relatively not noticeable, compared with the grinding of the sericite only. As a result of measuring the zeta potential for the raw or the ground samples, variation of the zeta potential values according to pH at the early stage of the grinding with the addictives was gentler than that at the final stage of grinding, which showed the relatively similar trend to the pH-zeta potential correlation in grinding of raw sericite. In addition, as a result of the disintegration experiment through ultrasonic excitation, D50 decreased rapidly only until the disintegration time of about 50 minutes.

Numerical Analysis of Runup and Wave Force Acting on Coastal Revetment and Onshore Structure due to Tsunami (해안안벽과 육상구조물에서 지진해일파의 처오름 및 작용파력에 관한 수치해석)

  • Lee, Kwang Ho;Kim, Chang Hoon;Kim, Do Sam;Yeh, Harry;Hwang, Young Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.3B
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    • pp.289-301
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    • 2009
  • In this work, wave run-up heights and resultant wave forces on a vertical revetment due to tsunami (solitary wave) are investigated numerically using a numerical wave tank model called CADMAS-SURF (CDIT, 2001. Research and Development of Numerical Wave Channel (CADMAS-SURF). CDIT library, No. 12, Japan.), which is based on a 2-D Navier-Stokes solver, coupled to a volume of fluid (VOF) method. The third order approximate solution (Fenton, 1972. A ninth-order solution for the solitary wave. J. of Fluid Mech., Vol. 53, No.2, pp.257-271) is used to generate solitary waves and implemented in original CADMAS-SURF code. Numerical results of the wave profiles and forces are in good agreements with available experimental data. Using the numerical results, the regression curves determined from the least-square analysis are proposed, which can be used to determine the maximum wave run-up height and force on a vertical revetment due to tsunami. In addition, the capability of CADMAS-SURF is demonstrated for tsunami wave forces acting on an onshore structure using various configuration computations including the variations of the crown heights of the vertical wall and the position of the onshore structure. Based on the numerical results such as water level, velocity field and wave force, the direct effects of tsunami on an onshore structure are discussed.

Numerical Analysis of Wave Transformation of Bore in 2-Dimensional Water Channel and Resultant Wave Loads Acting on 2-Dimensional Vertical Structure (2차원수조내에서 단파의 변형과 구조물에 작용하는 단파파력에 관한 수치해석)

  • Lee, Kwang Ho;Kim, Chang Hoon;Kim, Do Sam;Hwang, Young Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5B
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    • pp.473-482
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    • 2009
  • This study numerically discusses wave forces acting on a vertical wall such as breakwaters or revetments, subjected to incident undular or turbulent bores. Due to the complex hydrodynamics of bore, its wave forces have been predicted, mainly through laboratory experiments. Numerical simulations in this paper were carried out by CADMAS-SURF(CDIT, 2001), which is based on Navier-Stokes momentum equations and VOF method (Hirt and Nichols, 1981) for tracking free water surface. Its original source code was also partly revised to generate bore in the numerical water channel. Numerical raw data computed by CADMAS-SURF included great strong spike phenomena that show the abrupt jumps of wave loads. To resolve this undesired noise of raw data, the band-pass filter with the frequency of 5Hz was utilized. The filtered results showed reasonable agreements with the experimental results performed by Matsutomi (1991) and Ramsden (1996). It was confirmed that CADMASSURF can be applied to the design of coastal structures against tsunami bores. In addition, the transformation process and propagation speed of bores in the same 2-d water channel were discussed by the variations of water level for time and space. The numerical results indicated that the propagation speed of bore was changed due to the nonlinear interactions between negative and reflected waves.

The Effects of Perceived Social Stigma on the Life Satisfaction of Sexual Minorities (사회적 낙인 인식이 성소수자의 삶의 만족도에 미치는 영향)

  • Kang, Byung Chul
    • Korean Journal of Social Welfare Studies
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    • v.42 no.2
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    • pp.381-417
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    • 2011
  • The primary goal of this study is to examine the factors that affect how satisfied sexual minorities are with their lives. This study focuses on how sexual minorities perceive social stigma, the social influences involved in its perception, and the effects this perception has. Using stress-coping theory, this study looks at how social stigma, as a perceived stress, affects social support and self-esteem, how the stigma influences the degree to which individuals "come out" in an effort to cope, and the resultant effects of this coping mechanism on life satisfaction. The data used if from a sample of 478 individuals who self identify as gay, lesbian or bisexual. It was collected through an online survey. Using SEM, the quality was evaluated by analyzing the measurement model, and the relationship of the variables included in the theoretical model was verified by analyzing the structural model. The results of this study show that social stigma directly affects the life satisfaction of Korean sexual minorities. It significantly influences the social support they receive(from family and sexual minority peers), and their self-esteem. The degree to which the individual "comes out" is shown to affect life satisfaction as well. In contrast, the mediating effect of heterosexual support is shown to be insignificant. Based on the analyses, practical strategies regarding social stigma, social support, self-esteem, and "coming out" are suggested for sexual minorities. The social stigma should be reduced and society-scaled campaigns promoted in order to improve their level of life satisfaction. In addition, institutional protection should be developed and specialized educational courses on human rights provided which will empower these minorities with self-help mechanisms. Furthermore, issues such as establishing support system and providing a social welfare system for the sexual minority community are discussed.