• Journal of the Korean Magnetic Resonance Society
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• v.13 no.2
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• pp.135-142
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• 2009

$^{195}Pt$ NMR measurements were performed to deduce the variation of local density of states at the Fermi energy ($E_F$-LDOS) at the surface of carbonsupported Pt catalysts due to the addition of $Nafion^{(R)}$ ionomer in the metalelectrode-assembly for fuel cells. The results showed that the EF-LDOS at the surface of Pt particles was enhanced by the addition of $Nafion^{(R)}$ ionomers whereas it was uninfluenced in the inner (bulk) part of the Pt particles. This suggests that the effects of ionomers on the electronic states of the Pt particle surface are related to the electrochemical activity of the catalysts.

• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.9-22
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• 2000

Optical-optical double resonance experiments have been used to identify and characterize five ion-pair states and several of the bound and repulsive valence states of ClF. This report provides a description of these experiments for $^{35}CIF$ and $^{37}CIF$, and a summary of the current knowledge of the valence and ion-pair states. The important role of perturbations among the rovibronic levels of the bound valence states and their utilization in the double resonance technique is discussed. The ion-pair states of the same symmetry, ${\Omega}$=$0^+$ (E and f) and 1( $\beta$ and G) interact very strongly and the spectroscopy of these states is anomalous and, hence, interesting. Comparison is made to some recent ab initio calculations for ClF. One possible explanation of the irregular vibrational energy levels and rotational constants of the ion-pair states of $O^+$ and 1 symmetry is a crossing of the diabatic potentials of these states. Some currently unresolved questions about ClF spectroscopy are posed for future work. Where appropriate, analogy is made between the electronic states of ClF and the corresponding valence and ion-pair states of $Cl_2.$.

• Bulletin of the Korean Chemical Society
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• v.2 no.1
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• pp.29-34
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• 1981

Chemical shift values of ${\alpha}$-proton of trans- and cis-methyl cinnamates are well correlated with ${\sigma}({\sigma}_1,\; {{\sigma}_R}^{\alpha})$, and (F, R) (r=0.999-0.879). It is observed that (1) the degree of variation of ${\delta}H_{\alpha}$ value by varying the substituents in trans-cinnamates is similar to that of cis-cinnamates $({\rho}_{trans}=0.296,\;{\rho}_{cis}=0.2840, (2) resonance contribution is larger in the trans-cinnamates than that in the cis-cinnamates, but inductive contribution is reversed, (3) for m-substitued derivatives, resonance contribution is very small compared to that for p-substituted derivatives.

• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1084-1096
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• 2023

On-the-fly(OTF) generation of Spectral Superhomogenization(SSPH) factors is analyzed in the multigroup(MG) whole core calculation employing pin-wise continuous energy(CE) slowing-down solutions. The motivation for the work is to avoid the huge computing time required for the generation of a parametrized SSPH factor library(PSSL) which is used to resolve the angular dependency of MG resonance cross sections, and also to exploit the advantage of flexible choice of a MG structure by using CE slowing-down solutions. Two pin-wise CE slowing-down methods, the equivalent Dancoff cell method and the shadowing effect correction method, are evaluated with the OTF SSPH method. The effectiveness of the OTF SSPH method is examined for various simplified and realistic core problems with various MG structures. It is demonstrated that the computing time overhead of this method is negligible whereas the solution accuracy is considerably enhanced.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.66 no.8
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• pp.1207-1214
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• 2017

In the case of frequent braking, when driving downhill or long distance, conventional brakes using friction are problematic in braking safety due to brake rupture and fading phenomenon. Therefore auxiliary brakes is essential for heavy vehicles. And several research has been actively conducted to improve energy efficiency by regenerating mechanical energy into electric energy when the vehicles brake. In this paper, a voltage control method is utilized to recover the electric energy generated in the electromagnetic retarder instead of the eddy current. To regenerate the braking energy into the electrical energy, a resonant L-C circuit is configured in the retarder. The retarder can be modeled as self-excited induction generator due to its operating principle. The driving conditions according to the retarder's parameters are made into 3-D maps. Also, the voltage of the resonant circuit changing depending on the driving pulse applied to the FET was analyzed. For the control of this voltage, we proposed an algorithm using the PI controller. The controlled voltage is converted by a 3-phase AC/DC converter and then charged to a battery inside the heavy vehicles through a DC/DC converter. Electromagnetic retarder and its controller are validated using Matlab Simulink. We also demonstrate the voltage controller through the actual M-G set experiment.

• The Transactions of the Korean Institute of Power Electronics
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• v.10 no.3
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• pp.274-281
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• 2005

A new resonant pulse converter for energy harvesting is proposed. The converter transfers energy from a low-voltage AC current to a battery. The low-voltage AC current source is an equivalent of the piezoelectric generator, which converts the mechanical energy to the electric energy. The converter consists of a full-bridge rectifier having four N-type MOSFETs and a boost converter haying N-type MOSFET and P-type MOSFET instead of diode. Switching of MOSFETs utilizes the capability of the $3^{rd}$ regional operation. The operational principles and switching method for the power control of the converter are investigated with the consideration of effects of the parasitic capacitances of MOSFETs. Simulation and experiment are performed to prove the analysis of the converter operation and to show the possibility of the $\mu$W energy harvesting.

• Advances in Energy Research
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• v.6 no.1
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• pp.35-54
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• 2019

A successful blade design must satisfy some criterions which might be in conflict with maximizing annual energy yield for a specified wind speed distribution. These criterions include maximizing power output, more resistance to fatigue loads, reduction of tip deflection, avoid resonance and minimize weight and cost. These criterions can be satisfied by modifying the geometrical parameters of the blade. This study is dedicated to the aerodynamic assessment of a 20 kW horizontal axis wind turbine operating with two possible airfoils; that is $G{\ddot{o}}ttingen$ 413 and NACA 2415 airfoils (the Gottingen airfoil never been used in wind turbines). For this study parameters such as chord (constant, tapered and elliptic), twist angle (constant and linear) are varied and applied to the two airfoils independently in order to determine the most adequate blade configuration that produce the highest annual energy output. A home built numerical code based on the Blade Element Momentum (BEM) method with both Prandtl tip loss correction and Glauert correction, X-Foil and Weibull distribution is developed in Matlab and validated against available numerical and experimental data. The results of the assessment showed that the NACA 2415 airfoil section with elliptic chord and constant twist angle distributions produced the highest annual energy production.

• Journal of Power Electronics
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• v.19 no.3
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• pp.827-834
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• 2019

Wireless power transfer via coupled magnetic resonances has been a hot research topic in recent years. In addition, the number of related devices has also been increasing. However, reverse signals transfer is often required in addition to wireless power transfer. The structure of the circuit for a wireless power transfer system via coupled magnetic resonances is analyzed. The advantages and disadvantages of both parallel compensation and series compensation are listed. Then the compensation characteristics of the inductor, capacitor and resistor were studied and an appropriate compensation method was selected. The reverse signals can be transferred by controlling the compensation of the resistor. In addition, it can be demodulated by extracting the change of the primary current. A 3.3 MHz resonant frequency with a 100 kHz reverse signals transfer system platform was established in the laboratory. Experimental results demonstrate that wireless power and reverse signals can be transferred synchronously.

• Nuclear Engineering and Technology
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• v.53 no.3
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• pp.732-740
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• 2021

Scattering resonance of medium mass nuclides leads complex spectrum in the fast reactor, which requires thousands of energy groups in the spectrum calculation. When the broad-group cross sections are collapsed, reaction rate cannot be completely conserved. To eliminate the error from energy collapsing, the Super-homogenization method in energy collapsing (ESPH) was employed in the fast reactor code SARAX. An ESPH factor was derived based on the ESPH-corrected SN transport equation. By applying the factor in problems with reflective boundary condition, both the effective multiplication factor and reaction rate were conserved. The fixed-source iteration was used to ensure the stability of ESPH iteration. However, in the energy collapsing process of SARAX, the vacuum boundary condition was adopted, which was necessary for fast reactors with strong heterogeneity. To further reduce the error caused by leakage, an additional conservation factor was proposed to correct the neutron current in energy collapsing. To evaluate the performance of ESPH with conservation factor, numerical benchmarks of fast reactors were calculated. The results of broad-group calculation agreed well with the direct full-core Monte-Carlo calculation, including the effective multiplication factor, radial power distribution, total control rod worth and sodium void worth.

• Nuclear Engineering and Technology
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• v.5 no.1
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• pp.38-43
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• 1973

The spin-rotation constants of the proton and tile fluorine nucleus in C $H_4$, Si $H_4$, Ge $H_4$, C $F_4$, Si $F_4$ and Ge $F_4$ were determined experimentally by the molecular beam magnetic resonance method. From the Hamiltonian and the high field approximation, the quantized energy level is given by the following equation. W $m_{I}$ $m_{J}$=- $g_{I}$ $m_{I}$H- $g_{J}$ $m_{J}$H- $C_{av}$ $m_{I}$ $m_{J}$, where $c_{av}$ is one third of the trace of the C tensor. In the nuclear resonance experiment, the proton and the fluorine nuclear resonance curves consist of many unresolved lines given by v=- $g_{J}$H- $C_{av}$ $m_{I}$, and a Gaussian approximation is made to correlate $c_{av}$ to the experimentally obtained half-width of the resonance curve. In the rotational resonance experiment, the five resonance peaks as predicted by v=- $g_{I}$H- $c_{av}$ $m_{I}$, $m_{I}$=0, $\pm$1 and $\pm$2, were all observed. The magnitude of car was determined by measuring the frequency distance between two adjacent peaks. The sign of $c_{av}$ was determined by the side peak suppression technique. The technique is described, and the sign and magnitude of the spin-rotation constant cav are summarized as following: for C $H_4$ -10.3$\pm$0.4tHz(from the rotational resonance), for SiH +3.71$\pm$0.08kHz(from the nuclear resonance), for Ge $H_4$+3.79$\pm$0.13kHz(from the nuclear resonance), for C $F_4$, -6.81$\pm$0.08kHz(from the rotational resonance), for Si $F_4$, -2.46$\pm$0.06kHz(from the rotational resonance), and finally for Ge $F_4$-1.84$\pm$0.04kHz(from the rotational resonance).onal resonance).esonance).