• Title/Summary/Keyword: resistance change

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Spalling of Intermetallic Compound during the Reaction between Electroless Ni(P) and Lead-free Solders (무전해 Ni(P)과 무연솔더와의 반응 중 금속간화합물의 spalling 현상에 관한 연구)

  • Sohn Yoon-Chul;Yu Jin;Kang S. K.;Shih D. Y,;Lee Taek-Yeong
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.3 s.32
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    • pp.37-45
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    • 2004
  • Electroless Ni(P) has been widely used for under bump metallization (UBM) of flip chip and surface finish layer in microelectronic packaging because of its excellent solderability, corrosion resistance, uniformity, selective deposition without photo-lithography, and also good diffusion barrier. However, the brittle fracture at solder joints and the spatting of intermetallic compound (IMC) associated with electroless Ni(P) are critical issues for its successful applications. In the present study, the mechanism of IMC spatting and microstructure change of the Ni(P) film were investigated with varying P content in the Ni(P) film (4.6,9, and $13 wt.\%$P). A reaction between Sn penetrated through the channels among $Ni_3Sn_4$ IMCs and the P-rich layer ($Ni_3P$) of the Ni(P) film formed a $Ni_3SnP$ layer. Thickening of the $Ni_3SnP$ layer led to $Ni_3Sn_4$ spatting. After $Ni_3Sn_4$ spatting, the Ni(P) film directly contacted the molten solder and the $Ni_3P$ phase further transformed into a $Ni_2P$ phase. During the crystallization process, some cracks formed in the Ni(P) film to release tensile stress accumulated from volume shrinkage of the film.

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The Effect of Residual Stress on Magnetoresistance in GMR Head Multilayers (자기기록 MR 헤드 용 다층박막의 자기저항에 미치는 잔류응력 효과)

  • Hwang, Do-Guwn
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.4
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    • pp.322-327
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    • 2003
  • Giant magnetoresistance(GMR) NiO multilayer, which has been used to reading head of highly dense magnetic recording, was fabricated, and oxidized in an air during 80 days to study the dependence of magnetoresistance properties on residual stress in the interfaces. The magnetoresistance ratio and the exchange biasing $field(H_{ex})$ of $NiO(60nm)/Ni_{81}Fe_{19}(5nm)/Co(0.7nm)/Cu(2nm)/Co(0.7nm)/Ni_{81}Fe_{19}(7nm)$ spin valves were increased from 4.9% to 7.3%, and 110 Oe to 170 Oe after natural oxidation in the atmosphere for 80 days, respectively. The sheet resistivity ${\rho}$ decreased from $28{\mu}{\Omega}m$ to $17{\mu}{\Omega}m$, but ${\Delta}p$ did not almost change after the oxidation. Therefore, the increase of MR ratio is due to the decrease in the sheet resistivity. the reduced resistance may result from the increase in the reflection of conduction electrons at the oxidized top surface. Also, the increase in the exchange biasing field is originated from the reduction of residual stress at the interface of $NiO/Ni_{81}Fe_{19}$ according as the aging time increases.

DIMENSIONAL ACCURACY OF EPOXY RESINS AND THEIR COMPATIBILITY WITH IMPRESSION MATERIALS (EPOXY RESIN의 정확도와 인상재와의 친화성에 관한 연구)

  • Chang, Su-Kyoung;Chang, Ik-Tae;Yim, Soon-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.3
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    • pp.383-394
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    • 1999
  • The indirect technique for making cast restoration requires that dies be as accurate and durable as possible. Currently, stone is the most commonly used material for die. However, it has some problems such as the weakness in its strength and low abrasion resistance. Recently, epoxy resin die systems have become available. The purpose of this study was to examine two commercially available resin die systems and evaluate some characteristics for their clinical performance. This study evaluated the dimensional accuracy of epoxy resins and their wettability with impression materials. In this study, the first experiment was about dimensional accuracy of different die materials. The master model was made of stainless steel. 10 models were made of two epoxy resins (Die-epoxy, Tri-epoxy) and a die stone (Fujirock) each. Occlusal diameter (Dimension I), occluso-gingival height (Dimension II), and interabutment distance (Dimension III) were measured in each model. Next, the contact angles of die materials with impression materials were observed. The blocks were made of polyether, hydrophilic additional silicone, polysulfide impression materials. By drop-ping the same amount (0.05ml) of Tri-epoxy, Die-epoxy, and die stone on the blocks, 10 samples of each die material were made. After setting of materials, the contact angles were measured. The results of this study were as follows. 1. The expansion of stone die and the shrinkage of resin dies in occlusal diameter were observed, and stone and Tri-epoxy were expanded and Die-epoxy was shrinked in occluso-gingival height. There was little change among materials in interabutment distance (p<0.05). 2. In comparison with the master model Tri-epoxy had the least variation in measurement of the three die systems examined. Die-epoxy was next, and die stone showed the greatest variation. 3. The compatibility of die stone for polyether, hydrophilic additional silicone, polysulfide decreased in order, wherease epoxy materials had the decreased compatibility for polyether and polysulnde, hydrophilic additional silicone in order. It was not statistically different between polyether and polysulfide (p<0.05). 4. The contact angles of Tri-epoxy, Die-epoxy, die stone were getting bigger in order.

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An Empirical Study on the Between Cross-Culture Exchange and Communication(Negotiation) of Korean Youth (한국청년의 이문화 변화와 커뮤니케이션 관계와의 실증적 연구)

  • Lee, J. Hong
    • International Commerce and Information Review
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    • v.19 no.3
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    • pp.153-174
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    • 2017
  • The cultural values of the traditional way and the current cultural values of young people are very different, and the rejection of cross-cultural contact is greatly reduced because Korean young people easily accommodate other cultures of the US, Europe or Asia. At present, the cultural values of the traditional way and the current cultural values of young people are very different, and the youthfulness of Korean young people easily accepts other cultures of the US, Europe or Asia, so the resistance to cross - cultural contact is greatly reduced. The purpose of this study is to find out how the younger Korean youths are forming the change of the foreign culture and how the negotiation will proceed according to the formation of these cultures. The results of the analysis show that Korean young people have collectivism cultural rights and that they are consistent with the previous research that there is tendency to avoid uncertainty. On the other hand, there is a tendency of opposition as a result of the empirical analysis that the Koreans have a strong orientation, a high power interval, and strong masculinity. Also, as a result of analyzing the changes in Korean culture that belongs to the high background culture, Korean young people tend to be centered in the past and decision makers tend to decide by the chief executive. On the other hand, Korean young people were denied all the verifiable cultural attributes that cultural properties and communication that maintain openness to share space exposures and office space are non - verbal, tacit communication and time observation are very long and uncertain.

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A STUDY ON THE PHYSICAL PROPERTIES AND VOLUMETRIC STABILITY OF SR-IVOCAP RESIN SYSTEM (SR-Ivocap resin system의 물리적 특성과 체적 안정성에 관한 연구)

  • Eun, Sung-Sik;Kweon, Hyeog-Sin;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.3
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    • pp.453-467
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    • 1998
  • This study helps to clarify conflicting reports by comparing the physical properties and accuracy of complete denture processed by the pack and press technique, continuous- pressure injection technique(SR-Ivocap system) and Mark press technique. The 6 different specimens have been evaluated using the SEM, Impact test, DSC (Differential Scanning Calorimetry) and DMTA (Dynamic Mechanical Thermal Analysis). Each sample was made of SR-Ivocap resin and QC-20 resin by different processing methods. The results were as follows ; 1. As the result of the observation on the fracture surface of resin by use of SEM, sample SR-Ivocap resin cured by continuous pressure injection method showed the most homogeneous structure. This is why molecules in SR-Ivocap resin have no orientation. 2. As the result of the Impact test in order to measure the deformity, fracture energy and impact resistance of resin, the samples with QC-20 acrylic resin and SR-Ivocap resin cured by continuous pressure injection method were exellent. 3. In consequence of measuring ${\alpha}$-glass transition temperature by use of DSC on the basis of temperature change, the glass transition temperatures of sample QC-20 resin cured by pack and press method and sample SR-Ivocap resin cured by continuous pressure injection method were very similar. Thus volumetric stability could not be evaluated only by glass transition temperature. 4. In comparing volumetric stability data by DMTA, the glass transition temperature(Tg) showed $137.88^{\circ}C$ at sample QC-20 resin cured by pack and press method and $139.78^{\circ}C$ at sample SR-Ivocap resin cured by continuous pressure injection method. Therefore sample SR-Ivocap resin cured by continuous pressure injection method seems to be superior to sample QC-20 resin cured by pack and press method in the dimensional stability at high temperature. 5. In comparing storage modulus data by DMTA, the storage modulus of sample SR-Ivocap resin cured by continuous pressure injection method was higher than that of sample QC-20 resin cured by pack and press method. So. sample SR-Ivocap resin cured by continuous pressure injection method seems to be superior to sample QC-20 resin cured by pack and press method in impact strength.

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The Liquid Flame Proofing Agent's Permeating Effect of Wood Using Microwave (마이크로파를 이용한 목재의 액상방염약제 침투효과 연구)

  • Park, Cheul-Woo;Her, Jae-Won;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.3
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    • pp.256-264
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    • 2011
  • By implementing an analysis on the liquid flame proof agent infiltration of microwave-heated wood under soaking conditions (room temperature soaking, heat soaking), its correlation with wood temperature, and the structure of wood and permeating components after soaking in flame proof agent, which was carried out as basic research in order to improve the fire resistance performance of the wood itself, it is found that the infiltration increases as the microwave heating time increases, while for heat soaking, it is found that high infiltration as well as the stable permeability of flame proof agent is achievable. Also, when the wood temperature is more than $80^{\circ}C$, the infiltration by the flame proof agent increased, and a very even infiltration of flame proof agent was observed, which implies that the liquid flame proof agent has a dependency on temperature change of the wood as a condition to penetrate into the wood. As a result of fine structure analysis, the flame proof agent transfer between cells through pits was considered as a cause to increase the infiltration of flame proof agent, and it is also shown that for heat soaking among the permeating component analysis, as the crystallized flame proof agent around the heartwood and sapwood inner pits increases, the flame proof agent can penetrate into the the heartwood part.

An Experimental Study on a Performance Evaluation of Internal Insulation of Buildings Over 20 Years Old (20년 이상 경과된 노후건축물의 단열재 성능평가에 관한 실험적 연구)

  • Kim, Hyun-Jin;Choi, Se-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.6
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    • pp.539-547
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    • 2019
  • Recently, the international community signed a climate change agreement to prevent global warming. Yet currently, the fossil fuels have been widely used in to supply building energy for cooling and heating. The Green Building certification (G-SEED), an energy efficiency rating for new or existing buildings requires that buildings meet certain conditions. Insulation is used as a building material to reduce the energy supply to buildings and to improve the thermal insulation, and it accounts for more than 90% of the total heat resistance provided by the building surface components that meet the energy-saving design standards of new buildings. In this investigation, a performance evaluation study was conducted through an experimental study by directly extracting the foam polystyrene insulation on-site during the remodeling of a building that was in the range of 22~38 years old. Through tests, it was found that the thermal conductivity of the extrusion method insulation (XPS) was reduced by 48% and the compressive strength of XPS decreased by 36% compared to KS M 3808, which is the initial quality standard. For bead method insulation (EPS) with a thickness of 50mm, the thermal conductivity, the compressive strength, and flexural failure load were similar to the initial quality standard. Therefore, in the calculation of the primary energy requirement per unit area per year, the performance of bead method insulation can be estimated simply by considering the thickness of the insulation, while a correction factor that considers its performance deterioration should be applied when extrusion method insulation is used.

A study on the change of EEOI before and after modifying bulbous at the large container ship adopting low speed operation (대형 컨테이너선의 저속 운항 시 선수부 개조 전후 EEOI 변화에 대한 연구)

  • Park, Goryong;Cho, Kwonhae
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.1
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    • pp.15-20
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    • 2017
  • The International Maritime Organization(IMO) has adopted and implemented compulsory regulation for reducing greenhouse gas emission that cause global warming. However, with global warming underway, the IMO plans to enforce voluntary carbon dioxide emissions reduction based on the Ship Energy Efficient Management Plan and the Energy Efficiency Operational Indicator(EEOI) in the near future. Large container ships sail at low speeds in order to save fuel and reduce carbon dioxide emissions. However, bulbous bows designed for high-speed ships decrease fuel efficiency by acting as resistance when reduced speeds are adopted by large container ships. In order to adopt low-speed operations and increase fuel savings, the bulbous bow of a large container ship was modified into the proper shape and size. Fuel consumption was compared for checking the result of EEOI before and after modifying the bulbous bow adopted on low speed operation of large high-speed ships. The results confirmed much larger carbon dioxide emissions reduction than expected. If EEOI would be implemented as compulsory regulation for reducing carbon dioxide emissions, bulbous bow modification can be considered as one of the fuel saving methods for the high-speed ships.

Changes of Polyamine Content and Phytoavailability in Lactuca sativa cultivated in Cadmium and Arsenic Treated Soil (카드뮴과 비소처리가 상추의 polyamine함량 및 유효도에 미치는 영향)

  • Moon, Kwang-Hyun;Koh, Mun-Hwan;Kim, Won-Il;Jung, Goo-Bok;Kim, Kyung-Min
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.223-227
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    • 2000
  • Absorption of Cadmium(Cd) and Arsenic(As) by lettuce following to the change of polyamine content in lettuce were examined to find the effect of these elements on lettuce growth and on the basic resistance mechanism. As the contents of Cd and As were increased in soil, the contents of these elements were significantly increased in lettuce but lettuce growth was decreased. Sequential fractionation experiment of the Cd and As treated soil was shown that exchangeable, dilute acid extractable, and organically bound form, which were more mobile and phyto-available, of Cd were increased by 5.6, 42.9, and 56.7% during a growing season whereas 17.6, 25.0, and 24.1% were increased in case of As, respectively. Specially, the Cd content of leaves and roots in lettuce was positively correlated with exchangeable, dilute acid extractable, and residual form of Cd in the treated soil. However, the As content of roots in lettuce was positively correlated with all chemical forms of As in the treated soil. The contents of putrescine and cadaverine, a kind of polyamine, were also increased in lettuce as both elements were increased in soil.

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Characteristics and Fabrication of Micro Gas Sensor with Single Electrode (단일전극을 가진 마이크로 가스센서의 제작 및 특성)

  • Song, Kap-Duk;Bang, Yeung-Il;Lee, Sang-Mun;Lee, Yun-Su;Choi, Nak-Jin;Joo, Byung-Su;Seo, Moo-Gyo;Huh, Jeung-Soo;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.11 no.6
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    • pp.350-357
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    • 2002
  • Micro gas sensor with single electrode was proposed for improving stability and sensitivity. Generally, metal oxide gas sensors have two electrodes for heating and sensing. This fabricated new type sensor have only a single electrode by forming a sensing material onto heating electrode. Pt as a heating and sensing electrode was sputtered on glass substrate and a $SnO_2$ sensing material was thermally evaporated on Pt electrode. $SnO_2$ was patterned by lift-off process and then thermally oxidized in $O_2$ condition for 1 hr., $600^{\circ}C$. The size of fabricated sensor was $1.9{\times}2.1\;mm^2$. As a result of CO gas sensing characteristics, this sensor showed 100 mV change for 1,000 ppm and linearity for wide range($0{\sim}10,000\;ppm$) of gas concentrations. And the sensor shows a good recovery characteristics of 1% deviation compared to initial resistance.