• Title/Summary/Keyword: residual oil

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유류분해 미생물의 특성 및 제제화 가능성 평가

  • 윤정기;김태승;노회정;김혁;박종겸;고성환
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.297-300
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    • 2004
  • The various microbial tests were performed to determine bioremediation agent capacity for eight strains isolated from the oil contaminated regions. Two tests for isolated strains were conducted such as cell hydrophobicity and emulsifying activity. The biodegradation of SHM (saturated hydrocarbon mixture) and AHM (aromatic hydrocarbon mixture) with the strains also was carried out. The strains having higher cell hydrophobicity and emulsifying activity degraded petroleum oil effectively. The degradation capacity for SHM was represented more than 90% in YS-7 and WLH-1 of isolated strains, and KH3-2 were capable of degrading AHM. Especially, WLH-1 as yeast was shown more than two or three times in the degradation capacity of automobile engine lubricants and the biomonitoring results of contaminated soil for residual oil degrading test showed that the hydrocarbon biodegradation was increased in the second treatment by this strain.

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Preparation of Carbon Fiber from Heavy Oil Residue through Bromination

  • Park, Young-Ok;Yang, Kap-Seung
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.178-183
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    • 2001
  • A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

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The Preparation and Properties of Petroleum Sulfonate Dispersant (열분해 잔유를 원료로 한 분산제의 제조 및 특성)

  • Choi, Sang-Won;Kim, Eun-Young;Chang, Woo-Seok;Kim, Viktor;Moon, Jang-Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.490-494
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    • 2007
  • Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

Monitoring of Residual Pesticides in Pepper Seed Oil Products Sold on the Market (고추씨 기름의 잔류농약 모니터링)

  • Mi-Hui Son;Jae-Kwan Kim;You-Jin Lee;Ji-Eun Kim;Eun-Jin Baek;Byeong-Tae Kim;Myoung-Ki Park;Yong-Bae Park
    • Journal of Food Hygiene and Safety
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    • v.38 no.6
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    • pp.483-488
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    • 2023
  • The status of residual pesticides was investigated in four pepper seed oil samples and 36 pepper-flavored oil samples oil distributed on the market from August to December 2022. A total of 179 pesticides were monitored in 40 samples, and 14 pesticides were detected in 39 of the samples, with a detection range of 0.01-2.16 mg/kg. In chili seed oil, 10 pesticides were detected 27 times with a range of 0.11-2.16 mg/kg, and in pepper-flavored oil, 9 pesticides were detected 94 times with a range of 0.01-0.80 mg/kg. The most frequently detected pesticides were tebuconazole, ethion, and difenoconazole, with ethion being detected in large concentrations in products using Chinese raw materials. Ethion, an unregistered pesticide in the Republic of Korea, has not been detected in the Gyeonggi-do area in the past 10 years. It is thought that the detection of ethion can be utilized as an indicator of products made in China. Peppers are a representative agricultural product for which many pesticides are used, and if the pesticides transferred to pepper seeds are not removed, the probability of detecting various types of pesticides in pepper seed oil is very high. Therefore, continuous research is needed to ensure the safety of pepper seed oil.

A Study on Residual Strength Assessment of Damaged Oil Tanker by Smith Method (Smith법에 의한 손상 유조선의 잔류강도 평가 연구)

  • Ahn, Hyung-Joon;Baek, Deok-Pyo;Lee, Tak-Kee
    • Journal of Navigation and Port Research
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    • v.35 no.10
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    • pp.823-827
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    • 2011
  • The present Common Structural Rules for double hull oil tanker is not included the residual strength, which is one of the functional requirements in design part of Goal-based new ship construction standards (GBS). The GBS will be enforced after July 1, 2016. The requirement related residual strength has the goal to build safe ship even if she has the specified damages due to marine accidents including collision and grounding. In order to assess the residual strength based on risk for structural damages according to GBS, tons of nonlinear FE analysis work taking into account various types of damage will be needed. The Smith's method, a kind of simplified method for the strength analysis is very useful for this purpose. In this paper, the residual strength assessments based on ultimate strength using Smith's method were carried out. The objected ship is VLCC with stranding damage in bottom structures. Also, the results were compared with that of nonlinear FE analysis using three cargo hold model.

Effect of Quenchant Temperature on the Surface Residual Stress in Gas Carburized AISI 8620 Steel (가스침탄 처리한 AISI 8620 강에서 급냉제가 표면잔류응력에 미치는 영향)

  • Jang, C.G.;Hahn, J.H.;Hwang, N.M.;Kim, J.J.;Lim, B.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.2
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    • pp.27-32
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    • 1989
  • The effect of quenchant temperature on the surface residual stress was studied for AISI 8620 steel. Specimens were carburized at $900^{\circ}C$ in all case type furnace using a gas-base atmosphere of methanol cracked and liquefied petroleum gas, and then subjected to single reheat quenchant in oil or salt bath in the temperature range of $60^{\circ}C$ to $300^{\circ}C$. After carburizing and reheat Quenching, residual stress was measured by the hole drilling method. Experimental results showed that the surface residual stress was increased as the quenchant temperature was raised. This is in contrast to the fact that the formation of phase of low transformation strain such as bainite results in lower surface compressive stress. The greater compressive stress observed in specimens Quenched at higher temperature may be attributed to the shifting of the transformation start point farther from the surface, as was reported in other carburizing steels.

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Study for Oil Spill Source Identification by Comprehensive Two Dimensional Gas Chromatography (2차원 가스크로마토그래프를 이용한 해상유출유 감식기법 연구)

  • Lee, Y.S.;Lee, S.J.;Kim, C.S.;Oh, H.J.;Kim, H.G.
    • Proceedings of KOSOMES biannual meeting
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    • 2006.11a
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    • pp.169-174
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    • 2006
  • A distinctive difference of hydrocarbon in crude oil and petroleum products exists. Depending on the origin where it comes from, crude oil shows its own unique pattern which is different from petroleum products containing characteristics according to their operating process and production period. A process of mixing behavior in a tank containing residual amounts of oil draws its own pattern when analysis is conducted. The analytical process described above is named oil fingerprint method. This study investigates an effectiveness of the method for comparing data sets produced by conventional gas chromatography with mass spectrometer (GC/MS) and comprehensive two-dimensional gas chromatography (GC X GC) which is known as powerful new technology for chemical analysis.

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Degumming Effect on Vegetable oil of Degumming agent (각종 탈검제에 의한 식물성 기름의 탈검효과)

  • 김덕숙;안명수
    • Korean journal of food and cookery science
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    • v.4 no.1
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    • pp.27-32
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    • 1988
  • The almost similar degumming effect was obtained by using oxalic acid instead of phosphoric acid, which also improves waste-water treatment. At this point, solution of Phosphoric, Acetic, Citric, Oxalic, and Nitric acid were used for degumming of rapeseed and soybean oil. Compared with Phosphoric(PA) and Oxalic acid(OA) were showed a simillar degumming effect in these vegetable oils. In rapeseed oil of 85% PA treating group and 5,10% OA fretting group, residual soap and phosphorus content in neutralized oil, color in bleached oil, and peroxide value and fatty acid content in deodrized oil were showed to simillar result. Soybean oil as well as rapeseed oil were showed to similar result. As a result, we could comfirmed substitutive possibility, which change PA into OA as a degumming agent. In the other hand, waste waters were obtained from 55% PA treating group and 10% OA treating group. Analytical result for this waste waters has showed a wide difference, especially in the BOD and COD. The amount of treating agents and time required in the precipitation seperation and chemical treatment each 3 and 1.7 times, which is PA treating group than OA treating group. We have investigated both the simillar degumming effect by OA solution and an alternative the pollution program means of a chemical treatment process is not possible.

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Application of the Nonionic Surfactant-enhanced Soil Washing to the Kuwait Soil Seriously Contaminated with the Crude Oil (원유로 심하게 오염된 쿠웨이트 토양 정화를 위한 비이온 계면활성제의 토양세척법 적용)

  • Heo, Hyojin;Lee, Minhee
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.491-500
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    • 2015
  • Batch experiments were performed to determine the feasibility of the surfactant-enhanced soil washing process at various washing conditions for the Kuwait soil seriously contaminated with the crude oil. The soil was sampled at a dried oil pond in Kuwait and its average TPH concentration was 223,754 mg/kg, which was too high to apply the conventional remediation process. Nine commercialized non-ionic surfactants were used for the batch experiment to measure the surfactant solubility for the crude oil because it was reported that they have worked for the soil remediation. Among them, three surfactants having high crude oil solubility were used for the soil washing experiment. From the result of batch experiment, 5% TritonX-100 washing solution showed the highest TPH removal efficiency (67%) for the crude oil contaminated soil. However, because the residual TPH concentration in the washed soil was still higher than the clean-up level in Kuwait (10,000 mg/kg), the repeated soil washing was performed. After five washings with 2% surfactant solution, the cumulative TPH removal efficiency was higher than 96% and the residual TPH concentration in the soil went down below the clean-up level. To measure the desorption capacity of TritonX-100 remained in the soil after the soil washing, the silica beads and the soil were washed five times with 2% TritonX-100 surfactant solution and then they were washed again with distilled water to detach the surfactant adsorbed on beads or soil. After five washings with surfactant solution, 7.8% and 19.6% of the surfactant was adsorbed on beads and soil, respectively. When additionally washed with distilled water, most of the residual surfactant were detached from beads and only 4.3% of surfactant was remained in soil. From the results, it was investigated that the surfactant-enhanced soil washing process with TritonX-100, Tergitol S-15-7, and Tergitol S-15-9 has a great capability for the remediation of the Kuwait soil seriously contaminated by crude oil (more than 220,000 mg/kg).

Optimization of Fermentation Conditions for the Manufacture of Wild Grape Wine (산머루주 제조를 위한 발효조건의 최적화)

  • Kim, Seong-Ho
    • Applied Biological Chemistry
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    • v.51 no.1
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    • pp.24-37
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    • 2008
  • Yeast with excellent ferment ability was isolated and selected from wild grape to manufacture wild grape wine. Wild grape wine by SMR-3 isolated from wild grape was better than other strains in quality, such as high alcohol content and low acidity, residual sugar, organic acid and fusel oil content. Fermentation condition was optimized to manufacture wild grape wine with response surface methodology using isolated SMR-3 as an alcohol fermentation strain. As a result of culture conditions, 10.61% of alcohol content was expected under the conditions of $21.91^{\circ}C$ fermenting temperature, $21.48^{\circ}brix$ of initial sugar content, and 14.65 day of fermentation time. Residual sugar content showed the lowest value at $24.48^{\circ}C$ fermentation temperature, $12.78^{\circ}brix$ of initial sugar content, and 9.02 day fermentation time. The highest level of sensory evaluation was found at $20.23^{\circ}C$ fermentation temperature, $25.30^{\circ}brix$ of initial sugar content, and 5.94 day fermentation time. Ethyl alcohol was the main alcohol component in wild grape wine and fusel oil in wild grape wine was hardly detected; thus, the quality of wild grape wine was considered excellent. The optimal fermentation conditions of wild grape wine was superimposed by deriving a regression equation for alcohol content, fusel oil, ethyl alcohol content, and overall palatability for each variable of wild grape wine. Hence, the optimal fermentation conditions are estimated to be: fermentation temperature $24{\sim}28^{\circ}C$, initial sugar content $20{\sim}24^{\circ}brix$, and fermenting time $12{\sim}14$ days.