• Korean Chemical Engineering Research
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• 제57권6호
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• pp.749-757
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• 2019

Methyltrimethoxysilane (MTMS)과 trimethylethoxysilane (TMES)을 출발물질로 사용하여 여러 종류의 용매에 용해시킨 후 다양한 종류의 촉매를 사용해 물과의 가수분해 및 중축합반응을 진행시켜 비불소계 발수 코팅 용액을 제조하였다. 또한 이 코팅 용액을 냉연 강판 위에 스핀 코팅하고 열 경화시켜 발수 코팅 도막을 제조 하였다. 이 과정 중 촉매와 용매의 종류 변화가 생성된 코팅 도막의 발수성에 미치는 영향을 연구하였다. 강산인 염산과 질산을 촉매로 사용한 경우에는 용액 내에 siloxane polymer들의 응집이 발생한 흰색의 불투명 상태를 나타냈다. 반면에 약산인 아세트산, 인산과 옥살산을 사용한 경우에는 투명하고 침전이 없는 안정한 용액 상태를 보였다. 이로 인해 강산인 염산과 질산을 사용한 경우의 코팅 도막의 접촉각은 각각 $58^{\circ}$와 $92^{\circ}$로 낮은 발수성을 보인 반면에 약산인 아세트산, 인산과 옥살산으로 제조된 경우에는 각각 $101^{\circ}$, $103^{\circ}$, $116^{\circ}$의 접촉각을 보여 높은 발수성을 나타내었다. 또한 이소프로판올과 에탄올을 용매로 사용한 경우에는 용액 내에서 siloxane polymer들의 응집이 일어나 불투명한 침전이 발생한 상분리 현상을 보인 반면 메탄올, 에틸아세테이트와 메틸에틸케톤을 용매로 사용한 경우에는 투명하고 침전이 없는 안정된 상태를 나타내었다.

• 한국토양비료학회지
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• 제45권2호
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• pp.204-208
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• 2012

소수성 토양이란 물방울이 떨어져도 자연스럽게 젖지 못하고 표면 위에 그대로 존재하는 토양을 말한다. 소수성 토양은 토양입자들 사이 혹은 토양입자와 그 중간물질의 사이에 소수성 유기물질이 침투하여 입자를 코팅하여 소수성을 띠게 되는 것이다. 토양이 소수성화가 되면 심한 침식과 침출, 농약의 급속한 침출, 식물이 이용할 수 있는 많은 양의 물과 영양분의 손실 그리고 농작물과 목초의 생산성 감소 등을 야기한다. 본 실험에서는 미량원소가 어떤 흡착과 이동 메커니즘을 갖는지를 배치 실험과 컬럼 실험을 통해 비교 평가하였다. 배치 실험에서는 $Cu^{2+}$, $Mn^{2+}$, $Fe^{2+}$, $Zn^{2+}$ 및 $Mo^{5+}$를 이용하여 일반 토양과 소수성 토양의 수착의 차이, 소수성 정도에 따른 차이, 각각의 미량원소 별 차이를 비교 하였고, 컬럼 실험에서는 피흡착물질인 미량원소 $Fe^{2+}$ 및 $Mo^{5+}$에 대한 탈착성능 비교와, 특정시간에 따른 공간적 농도 분포를 측정하였다. $Fe^{2+}$와 $Mo^{5+}$의 경우 비소수성 토양보다 소수성 토양에서 더 높은 흡착을 나타났다. $Fe^{2+}$의 흡착성능은 소수성 토양별 40% > 15% > 0% 순으로 나타났다. 특히 $Mo^{5+}$의 경우 0%, 15% 및 40%의 소수성 토양에서 초기에는 비슷한 경향을 보였으나 시간이 지나면서 소수성 토양에서 비소수성 토양보다 빠른 탈착속도를 보였다. $Fe^{2+}$와 $Mo^{5+}$의 파과곡선 분석결과 소수성 토양에서 더 빠른 이동속도를 나타내었다.

• 한국염색가공학회지
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• 제5권1호
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• pp.1-9
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• 1993

The polymethylhydrosiloxane(PMHS) was synthesized by the co-hydrolysis of methyldichlorophydrosilane and ethyl ether, also polydimethylsiloxane(PDMS) was synthesized by the hydrolysis of dimethyl dichlorosilane and ethyl ether. The silk fabrics were treated with PMHS and PDMS in order to improve the water repellency and the wrinkle recovery. Also the effect of PMHS concentration, PDMS concentration and cure temperature on the physical properties of silk fabrics were studied. The maximum water repellency and maximum wrinkle recovery were obtained from the fabrics treated under the conditions 5%-PMHS and PDMS at 16$0^{\circ}C$, and 3%-PMHD and PDMS at 16$0^{\circ}C$, respectively. The tensile strength, the breaking elongation, the reflection and the bending properties of silk fabrics were not degraded severely by the treatment of PMHS or PDMS.

• 한국염색가공학회지
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• 제5권2호
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• pp.125-133
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• 1993

This study was to investigate the application of foam finishing technology (FFT) for the silicone finishing of cotton fabrics and the tluorochemical finishing of polyester fabrics. The repellency properties, soil resistance properties and selected physical properties were demonstrated and compared the foam finishing with the conventional padding application. Amino-funetional silicone prorided better durability than epoxy-functional silicone and conventional reactive silicone after three launderings. Foam finishing fabrics improved stiffness but showed lower or equivalent water and oil repellency properties, soil resistance properties, tearing strength and abrasion resistance than those of the fabrics treated by conventional padding process. But, it was evident that the foam application of silicone and fluorochemical finishes to the fabrics were feasible.

• 품질경영학회지
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• 제16권1호
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• pp.43-48
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• 1988

Most of silicone used for water repellent finish is MHP (methyl hydrodiene polysiloxane), which is formed by hydrolysis and condensation polymerization of MHD (methyl hydrodiene dichlorosilane: Me H Si $Cl_2$). The cross-linking theory explains the water repellent mechanism of MHP. The silicone finish on fiber could improve in handle, softness, abrasion resistance, soil repellency, tear strength and crease resistance, as well as water repellency. According to using method silicone-water repellent finishing agents, could be devided into air dry type and curing type. MHP is the typical curing type of water repellent finishing agent, and this type requires the curing temperature above $150^{\circ}C$ at least. High curing temperature is the very drawback of this curing type. For this reason, there has been global interest in the lowering of its temperature. The objective of this study is to investigate merits of alkali treatment for silicone finishing by ANOVA and LSD (least significant difference).

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 추계학술발표논문집
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• pp.207-212
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• 2006

The development of practical utilization way of water repelling technology for manufacturing of fruiting bag was main purpose of this study. The water repelling technology was developed by wax emulsion coating The wax emulsion was manufactured at Chungsan chemical(Co) on pilot scale. The coating paper was tried in plant coater of Agro(Co). The water repellency of wax emulsion coated paper was good as fruit bagging paper.

• 한국염색가공학회지
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• 제23권2호
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• pp.100-106
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• 2011

UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.

• 한국표면공학회지
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• 제29권5호
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• pp.577-584
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• 1996

Silicon oxide films with high hardness and water repellency were prepared by microwave plasma-enhanced CVD using four kind of organosilicon compound-fluoro-alkyl silane mixtures as source gases. An argon gas was used as a carrier gas for fluoro-alkyl silane. The substrate temperatures during deposition were controlled by resistant heating at a constant value between 50 and $300^{\circ}C$. The hardness of the films increased, but the deposition rate and the contact angle for a water drop decreased with increasing substrate temperature. The number of methoxy groups also affected the water repellency and hardness. The deposited films became more inorganic with increasing substrate temperature because of the thermal dissociation of reactants.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.76-77
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• 2021

compared and reviewed the water repellency and strength characteristics by controlling the surface stamping size and fine aggregate ratio of cement mortar mixed with water repellent as a method to control the ecological imitation surface structure. As a result of measuring the contact angle, the higher the ratio of fine aggregate, the larger the contact angle. The contact angle increased when the surface structure was changed by stamping, and increased as the stamping size became smaller. In the surface stamping of mesh#150, the contact angle was particularly increased.

• 한국연초학회:학술대회논문집
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• 한국연초학회 2003년도 27회 정기총회 및 49회 학술발표회
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• pp.32-32
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• 2003