• Journal of the Korean GEO-environmental Society
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• v.16 no.5
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• pp.5-11
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• 2015

The double sheeted permeable reactive barrier containing two different reactive materials can be applied to remediate the groundwater contaminated by nutrients and heavy metals. In this study, in order to evaluate the removal efficiency of contaminants including ammonium, cadmium and phosphate by double layered permeable reactive barrier containing zeolite and steelmaking slag, column tests were performed. In addition, nonequilibrium reaction in column tests was analyzed by two-site nonequilibrium advection-dispersion model. Column test results showed that zeolite is effective for removal of ammonium, while steelmaking slag is effective for removal of phosphate and cadmium. The sequential reaction of zeolite and steelmaking slag gave the better removal efficiency for ammonium.

• Journal of Korean Society on Water Environment
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• v.20 no.2
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• pp.104-109
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• 2004

Removal of nutrients from domestic sewage or industrial wastewater is needed to protect surface waters from eutrophication. This research was carried out to remove the nitrogen (N) and phosphorus (P) from the wastewater using the iron oxide obtained from the steel industry and the natural zeolite, respectively. This research was conducted in both batch and continuous systems. The removal efficiency of the nutrients was evaluated in the batch system using the varying concentrations of zeolite and iron oxide added. The removal efficiency of N was 60% at the 8g of zeolite added. In the same condition, the removal efficiencies of N were 76% and 82% at 12g and 16g of zeolite added, respectively. Removal efficiency of P was 80% as 8g of iron oxide was added. The removal efficiency of P was correspondingly increased as the concentration of iron oxide was increased. Continuous column system was also used to evaluate the removal efficiency of N and P by the addition of zeolite and ferric oxide, respectively. Removal efficiencies of N were compared in the mixed packing, two stage, and four stage columns, respectively. The removal efficiencies (80%) of N in the separate packed columns (two and four stages) were higher than the mixed packing column (400%) after 90 hr. Whereas, the removal efficiencies of P were similar to each other in the three columns.

• Korean Journal of Environmental Agriculture
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• v.16 no.4
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• pp.327-332
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• 1997

This study was conducted to find out the effect for removal of $NH_3$ gas, one of the offensive odor. The removal efficiencies of $NH_3$ gas through zeolie column increased with the decreased percolation velocity. The effect of zeolite colum in removing $NH_3$ gas was influenced by the water content of zeolite and the added amount of zeolite, but was not influenced by the setting method of zeolite. The $NH_3$ gas removing sequence of saturated cation species on zeolite was in order of Ca->Na->$NH_4$ ->Natural->K-zeolite. Consequently the effect of zeolite on $NH_3$ gas removal efficiency is consided by the water content, added amount and saturated cation of the zeolite.

• Economic and Environmental Geology
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• v.35 no.5
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• pp.421-428
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• 2002

Lab-scale experiments were conducted to evaluate the effect of surface tension reduction on the extension of the influence zone and the VOC removal efficiency of ground water sparging. A glass column packed with coarse sand was used for VOC removal test at two different surface tensions. A glass column without porous media was also used fer control purpose prior to sand-packed column test. A quasi-two-dimensional glass box model, packed with a sand, was used fer sparging zone tests at different water surface tensions. Surface tension of the aquoues solution used in this study was controlled using sodium dodecyl sulfate (SDS). For the glass, sand column experiments, total amount of air filled in the media increased as surface tension decreased. Toluene (used as VOC in this study) removal rate increased slightly with decreased surface tension f3r both free water column and sand-packed column. Air sparging zone extended up to 500% as the surface tension decreased. Combining the results from two different experiments, VOC removal efficiency is expected to increase significantly with surface tension reduction.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.3
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• pp.182-190
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• 2015

This study was conducted to evaluate the removal efficiencies of organic matter and pharmaceuticals and to identify the removal mechanism of pharmaceuticals using sand obtained from Hwangryong River in Jangsung. Batch and column studies were used to simulate managed aquifer recharge (MAR) systems. All experiments were performed using field effluent containing pharmaceuticals from Damyang Wastewater Treatment Plant as an influent. Based on the removal results of organic matter and pharmaceuticals from the batch and column experiments, soil organic matter (SOM) and microbial activity were found to effectively remove target contaminants. The removal of organic matter was found to increase under biotic conditions. Neutral and cation pharmaceuticals (iopromide, estrone, and trimethoprim) exhibited removal efficiencies higher than 70% from natural sand and baked sand media in batch and column studies. Carbamazepine persisted in the sand batch and column studies. Anion pharmaceuticals (ketoprofen, ibuprofen, and diclofenac) can be removed under conditions featuring high SOM and adenosine triphosphate (ATP) concentrations in the sand surface. Based on the experimental Batch and column results, biodegradation and sorption were found to be important mechanisms for the removal of pharmaceuticals within the simulated MAR systems.

• Journal of Microbiology and Biotechnology
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• v.15 no.3
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• pp.497-501
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• 2005

This study deals with the removal of mercury species using a packed-bed column with spherical aminated chitosan material. These adsorbents revealed a high adsorption capacity for mercury species. Experiments with feed solutions of 10 ppm Hg dissolved in distilled water showed an excellent removal with a sharp increase of the filter effluent concentration after a total throughput of 900 bed volumes of feed water. Up to $95\%$ desorption was reached by using 3 bed volumes of 0.01 N EDTA solution. EDTA could be recovered by means of sulfuric acid with about $75\%$ efficiency. Almost the same results were obtained in repeated sorption and desorption experiments at identical conditions. The experiments demonstrated that the sorbents possessed practically no sorption capacity for alkaline earth ions ($Ca^{2+}\;and\;Mg^{2+}$). Their influence on the sorption of mercury was negligible. In experiments with spiked tap water of the Karlsruhe Research Centre and a feed mercury concentration of 0.01 mg/l, the breakthrough of Hg was observed only after a total throughput of about 6,000 bed volumes of feed water.

• Architectural research
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• v.10 no.1
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• pp.1-11
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• 2008

A Steel column with damaged spray-applied fire resistive material (SFRM) may exhibit reduced structural performance due to the effects of elevated temperature during fire events. Thus, the fire load behavior of steel columns with removed or reduced SFRM needs to be examined to predict the structural damage by fire. FEM analyses were performed for the flange thinning removal models in which the SFRM was reduced as a constant strip in thickness at the top flange of the column. The temperature results for all models obtained from the heat transfer analyses were included as an initial condition in the FEM structural analyses. In this study, the results of analysis show that even small remnants of SFRM led to an effective reduction of temperature at any given fire duration, and improved significantly the axial load capacity of a column as compared to the complete removal cases of SFRM.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.3
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• pp.307-317
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• 2010

This study was conducted in order to investigate bulk organic matter characteristics and behavior of geosmin and 2-methylisoborneol (2-MIB) during riverbank filtration, which are general surrogates of taste and odor in drinking water. Column studies were used to simulate bank filtration systems. Most of the aliphatic organic matter was removed effectively after soil passage, and it is believed to be polysaccharides according to LC-OCD and F-EEM analysises. Removal efficiencies of geosmin and 2-MIB within the filtration column reached above 95%. It was found that the removal of total dissolved organic matter has a correlation with that of geosmin and 2-MIB in the near of filtration surface (about 50cm).

• Journal of environmental and Sanitary engineering
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• v.17 no.2
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• pp.79-84
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• 2002

This study investigated possibility of the nitrification and denitrification in one counter-current column with the growth of biofilm attached to its media. This experiment was performed through use of the lab scale reactor composed of the column and settler. The column used was packed with the small size of plastic rings called PALL($1.5{\times}1.5{\;}cm$) with a cylindrical shape. Synthetic wastewater was used in the experiment. The loading rates of carbon (C) and total nitrogen (TN) furnished to the reactor were 0.23 to 1.0 kg COD/m3.d and 0.023 to 1.0 kg N/m3.d, respectively. Major factors controlling the removal efficiencies of COD and TN were the different air flux and volumetric loading rates of COD and TN. The experimental results obtained from this study demonstrated that the removal efficiencies of COD ranged from 90 to 95% and those of TN were from 80 to 83% under the N loading rate of 0.035 and $0.058{\;}kg{\;}N/m^3{\cdot}d$, respectively. The patterns of TN removed were distinctively different on the limit of 50cm of column in depth. This indicated that the nitrification and denitrification occurred near the surface zone of and inside the biofilm respectively, upto the 50cm of the column in depth.

• Nuclear Engineering and Technology
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• v.28 no.5
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• pp.482-487
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• 1996

The dissolved oxygen removal by H$_2$-O$_2$ reaction in column packed with various catalysts wes examined. The catalysts employed were the prepared polymeric catalyst platinum on activated carbon, and Lewatit OC-1045 which is available commercially. The column experiments with the prepared polymeric catalyst showed the dissolved oxygen reduced to 35 ppb which is below the limit in feed water of power plants. This implies the likely application of the prepared catalyst for practical use. The activated carbon required the pre-treatment for the removal of dissolved oxygen, since the surface of activated carbon contains much oxygen adsorbed initially. The Lewatit catalyst exposed the best performance, however, the aged one showed the gradual loss of catalytic activity due to degradation of resin catalyst.