• Title/Summary/Keyword: release behavior

검색결과 631건 처리시간 0.024초

다양한 Block Copolymer를 유화제 및 안정화제로 사용한 W1/O/W2-Type 다중에멀젼의 방출거동 및 안정성 (Stabilization and Release Behavior of W1/O/W2-Type Multiple Emulsions Using Various Block Copolymer Emulsifier and Stabilizer)

  • 허정림;김철훈
    • 공업화학
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    • 제8권4호
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    • pp.560-567
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    • 1997
  • 안정한 $W_1/O/W_2$ 다중에멀젼을 얻기 위한 새로운 시도가 연구 되었다; 오일상에 분산된 친유성 유화제와 PCL-PEO-PCL triblock copolymer 사이의 계면상호 작용이 연구되었다. $W_1/O/W_2$ 다중에멀젼은 2단계 방법으로 제조하였다. 친유성 유화제로서 Arlacel P-135와 친수성 유화제로서 Synperonic PE/F 127을 사용하였으며, Eutanol-G를 오일상으로 사용하였다. 다중에멀젼의 내부수상에 시약 방출물질로서 NaCl을 첨가하였으며, 이의 방출속도가 연구되었다. 다중에멀젼의 안정성은 분리도 측정과 광학현미경을 이용하여 평가하였다. 오일상에 PCL-PEO-PCL triblock copolymer를 용해하여 실험한 결과 2k-4k-2k와 6k-4k-6k의 조성 갖는 copolymer로 제조한 다중에멀젼에서 NaCl의 방출이 크게 감소하였다. 이것은 copolymer와 유화제가 안정성 증대와 방출 속도를 조절하는 효과적인 계면 복합체를 형성하기 때문이라고 사료된다. 2k-4k-2k의 조성 갖는 PCL-PEO-PCL triblock copolymer 1.2wt%의 함량으로 제조한 다중에멀젼에서 NaCl의 확산계수는 $2.64{\times}10^{-15}gcm^2/s$이고, 6k-4k-6k에서는 $3.23{\times}10^{-16}gcm^2/s$값을 얻었다. NaCl의 초기 농도의 증가에 따라 NaCl 방출이 감소하였고, Higuchi의 방출 모델식을 개정하여 적용한 결과, 고분자 matrix에 분산된 시약의 방출모델과 유사한 kinetic모델이 다중에멀젼에서 NaCl의 방출에 적당함이 발견되었다.

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Combustion Instability Mechanism of a Lean Premixed Gas Turbine Combustor

  • Seo, Seonghyeon
    • Journal of Mechanical Science and Technology
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    • 제17권6호
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    • pp.906-913
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    • 2003
  • Lean premixed combustion has been considered as one of the promising solutions for the reduction of NOx emissions from gas turbines. However, unstable combustion of lean premixed flow becomes a real challenge on the way to design a reliable, highly efficient dry low NOx gas turbine combustor. Contrary to a conventional diffusion type combustion system, characteristics of premixed combustion significantly depend on a premixing degree of combusting flow. Combustion behavior in terms of stability has been studied in a model gas turbine combustor burning natural gas and air. Incompleteness of premixing is identified as significant perturbation source for inducing unstable combustion. Application of a simple convection time lag theory can only predict instability modes but cannot determine whether instability occurs or not. Low frequency perturbations are observed at the onset of instability and believed to initiate the coupling between heat release rate and pressure fluctuations.

NUMERICAL STUDY OF AN EXTERNAL STORE RELEASED FROM A FIGHTER AIRCRAFT

  • Yoon, Young-Hyun;Cho, Hwan-Kee;Chung, H.S.;Lee, S.H.;Han, C.H.
    • 한국전산유체공학회지
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    • 제13권4호
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    • pp.80-85
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    • 2008
  • The prediction of the separation trajectories of external stores released from a military aircraft is an important task in the aircraft design area having the objective to define the operational and release envelopes. This paper presents the results obtained for store separation by employing commercial softwares, FLUENT and CFD-FASTRAN. FLUENT treats the rigid body motion by employing a remeshing scheme. CFD-FASTRAN uses Chimera(overset) grid and interpolations. It was found that, for the prediction of the trajectories and behavior of the stores separated from the wing, both codes show the good agreement with the experimental results.

연료와 공기의 혼합정도가 모델 가스터빈 연소기내의 압력변동에 미치는 영향 (Effect of the Unmixedness of Fuel and Air on the Pressure Fluctuations in a Model Gas Turbine Combustor)

  • 홍정구;신현동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.3264-3269
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    • 2007
  • Combustion instability is a serious obstacle for the lean premixed combustion of gas turbines, and can even cause fatal damage to the combustor and the entire system. Thus, improved understanding of the mechanisms of combustion instability is necessary for designing and operating gas turbine combustors. In this study, in order to understand the instability phenomena, an experimental study was conducted in a rearwardstep dump combustor with LPG and air. The fluctuations of pressure and heat release were measured by piezoelectric pressure sensor and High speed Intensified Charge Coupled Device (ICCD) camera respectively. Various types of combustion modes occurred in accordance with the equivalence ratio and the fuel supplying conditions. The unmixedness of the fuel and air can be controlled by changing the mixing distance ($L_{fuel}$). It is found that the unmixedness of the fuel and air affects the characteristics of flame behavior and pressure fluctuations in a lean premixed flame.

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통기식 디스크 브레이크의 방열 성능에 관한 수치적 연구 (A Numerical Study of Thermal Performance in Ventilated Disk Brake)

  • 김진택;백병준
    • Tribology and Lubricants
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    • 제17권5호
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    • pp.358-364
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    • 2001
  • Disk brake system transforms a large amount of kinetic energy to thermal energy in a short time. As the size and speed of automotive increases in recent years, the disk brakes absorbs more thermal energy. And this thermal energy can cause an unacceptable braking performance due to the high transient temperature, that is attained at the friction surface of brake disk and pad. Although these high temperatures are one of the biggest problems. In this study, the overall thermal behavior of ventilated disk brake system was investigated by numerical method. The 3-Dimensional unsteady model was simulated by using a general purpose software package “FLUENT” to obtain the temperature distributions of disk and pad. The model includes the more realistic braking method, which repeats braking and release. The effects of several parameters such as the repeated braking, inlet air velocity and thermal conductivity on the temperature distribution were investigated.

Quantitative Photocatalytic Activity under Visible Light with Mn-ACF/TiO2

  • Ye, Shu;Kim, Hyun-il;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제53권3호
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    • pp.343-348
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    • 2016
  • Manganese and $TiO_2$ grown on Activated Carbon Fiber (ACF) was synthesized by hydrothermal method. The prepared composites were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray (EDX). The catalytic behavior was investigated through the decomposition of methylene blue (MB) and methyl orange (MO) as standard dyes under visible light. The degradation performance of the degraded standard dye solutions was determined by UV-Vis spectrophotometry. This enhanced photocatalytic activity arises from the positive synergetic effect among the Mn, $TiO_2$ and ACF in this heterogeneous photocatalyst. The process contributes to the release of abundant photocatalytic sites of Mn and $TiO_2$ and improves the photocatalytic efficiency. The excellent adsorption and photocatalytic effect with the explanation of the synergetic mechanism are very useful not only for fundamental research but also for potential practical applications.

A study of human grasping ability and its application to a robot hand

  • Kim, Ilhwan;Inooka, Hikaru
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 22-24 Oct. 1991
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    • pp.1774-1778
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    • 1991
  • In this paper, we discuss the smooth hand-over of an object from a man to a robot and vice versa. In order for a robot to grasp an object or release a grasped object stably without using object model, as a man does, one of the basic approaches is the physiological method motivated by the study of human hands. So, we analyze human's grasping behavior by measuring grasp and friction forces simultaneously as a man grasps a experimental device which is designed for grasping or hand-over. Also, we investigate two methods that can predict when and bow fingers will slip upon a grasped object. And then, we propose a method of the hand-over of an object between a man and a robot by applying human's capability to a robot hand control.

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슬러지 순화조건과 접촉부하가 혐기상태에서 인과 유기물의 거동에 미치는 영향 (The Rffect of Sludge Acclimation Conditions and Contact Load on Phosphorus and Organic Substrates Behanio Under Anaerobic Conditions)

  • 박동근
    • 한국환경과학회지
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    • 제3권4호
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    • pp.427-437
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    • 1994
  • Batch experiments were performed to evaluate the effect of sludge acclimation and contact load on the behavior of phosphorus and organic substrates under anaerobic conditions. Four different sludges were acclimated in the sequencing batch reactors operated by intermittent aeration. All the experiments performed in a bench scale have shown the following results: 1. The unreleaseable phosphorus contents for four different sludges are the range of 16 mg P/g SS to 24 mg P/g SS, depending on the sludge acclimation conditions. 2. All the specific substrate uptake rates(SSUR) are expressed in the first order equation for releaseable phosphorus contents. The reaction rate coefficient k, has the values of 4.0, 8.9, and 13.8 mg COD/mg P/hr, depending on the contact load and slut식e species. 3. As reaction proceeds, the ratios of $\delta$P to -$\delta$COD at high contact load are almost constant in the range of 0.10 to 0.14, but at low contact load, they increase from 0.08 to 0.27.

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기계 화학적 반응법을 이용한 $Zn(BH_4)_2$ 분말의 합성과 열분해 특성 (Synthesis of $Zn(BH_4)_2$ powders by mechanochemical reaction and study of thermal decomposition behavior)

  • 전은;조영환
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
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    • pp.373-378
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    • 2005
  • [ $Zn(BH_4)_2$ ] ($8.4\;wt\%$ theoretical hydrogen storage capacity) powders have been successfully synthesized by mechanochemical reaction from mixtures of $ZnCl_2$ and $NaBH_4$ powders in a 1:2 molar ratio in different times. $$ZnCl_2\;+\;2NaBH_4\rightarrow\;Zn(BH_4)_2\;+\;2NaCl\;(1)$$ $Zn(BH_4)_2$ powders were characterized by X-ray diffractometry(XRD), and Furier Transform Infrared spectrometry(FT-IR). The thermal stabilities of $Zn(BH_4)_2$ powders were studied by Differential scanning calorimetry(DSC), Thermogravimetry analysis(TGA), and Mass spectrometry(MS). $Zn(BH_4)_2$ can be tested for hydrogen evolution without further purification. The reaction to yield hydrogen is irreversible, the other products being compounds of Zn, and borane. $Zn(BH_4)_2$ thermally decomposes to release borane and hydrogen gas between about 85 and $150^{\circ}C$.

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음향방출특성에 의한 탄소섬유강화 복합재의 손상파괴거동에 관한 연구 (Study on Evaluating the Damage Fracture Behavior of the Carbon Fiber Reinforced Composite Material by Acoustic Emission Characteristics)

  • 권오현
    • 한국안전학회지
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    • 제17권1호
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    • pp.1-5
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    • 2002
  • An approach for the damage of delamination which is the major concern during mechanical working for composite laminate material is proposed based on linear elastic fracture mechanics. This paper presents method evaluating of damage crack length using by average thrust force with AE characteristics. Also, the relations of AE characteristics are obtained from delamination damages. We found the onset ply of the delamination and a critical energy release rate and expressed a stress intensity factor by AEcount equation.