• Journal of the Korea Concrete Institute
• /
• v.22 no.3
• /
• pp.287-295
• /
• 2010

In this study, ordinary Portland cement was used and the air void was minimized by using minute quartz as the filler. In addition, steel fibers were used to mitigate the brittle failure problem associated with high strength concrete. This study is in progress to make an Ultra-high strength powdered concrete (UHSPC) which has compressive strength over 300 MPa. To increase the strength of concrete, we have compared and analyzed the compressive strengths of the concretes with different mix proportions and curing conditions by selecting quartz sand, dolomite, bauxite, ferro silicon which have diameters less than 0.6 mm and can increase the bond strength of the transition zone. Ultra-high strength powdered concrete, which is different from conventional concrete, is highly influenced by the materials in the mix. In the study, the highest compressive strength of the powdered concrete was obtained when it is prepared with ferro silicon, followed in order by Bauxite, Dolomite, and Quartz sand. The amount of ferro silicon, when the highest strength was obtained, was 110%, of the weight of the cement. SEM analysis of the UHSPC showed that significant formation of C-S-H and Tobermorite due to high temperature and pressure curing. Production of Ultrahigh strength powdered concrete which has 28-day compressive strength upto 341MPa has been successfully achieved by the following factors; steel fiber reinforcement, fine particled aggregates, and the filling powder to minimize the void space, and the reactive materials.

• Applied Chemistry for Engineering
• /
• v.10 no.3
• /
• pp.419-426
• /
• 1999

In this study, the reaction rate constant, activation energy, total crosslinking density, elastic constant, cure properties ($t_5,\;t_{90}$), modulus, and abrasion resistance of rubber compounds were investigated as a function of cure temperatures, cure systems and reinforcing filler loadings. Reaction rate constants showed strong dependence on thc carbon black loading, cure temperature and cure system, and increased sharply with increasing the reaction temperatures. The lowest activation energy was obtained in the efficient cure (EC) system which corresponds to the high level of sulfur to accelerator ratio, and the activation energy was decreased with decreasing the carbon black loadings. The change of carbon black loadings directly affects the modulus and abrasion resistance, but the change of cure system showed various effects on the rubber compounds. Increased carbon black loadings showed the high modulus, improved abrasion resistance and short scorch time but decrease in crosslinking density and elastic constant. Higher crosslinking density and elastic constant were shown in the EC cure system regardless of carbon black loadings, but scorch timc ($t_5$) was not affected by the change of the ratio of sulfur to accelerator. Rapid optimum cure time ($t_{90}$) were showen in the EC cure system. Also, the equivalent cure curve coefficient of rubber compound was 0.96 for conventional cure (CC) system, and 0.94 for semi-efficient cure (SEC) and EC system regardless carbon black loadings. As regarding the abrasion resistance, wear volume showed the logarithmic increase for the loaded weight.