• Title/Summary/Keyword: reformer

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Optimization of Fuel-cell stack design using CFD-ACE (CFD-ACE를 이용한 연료 전지 냉각판의 최적 설계)

  • 홍민성;김종민
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.10a
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    • pp.14-18
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    • 2003
  • Feul-cell system consists of fuel reformer, stack and energy translator. Among these parts, slack is a core part which produces electricity directly. In order to set a stack module, fabrication of appropriate stack, design of water flow path in stack, and control of coolant are needed. Especially, water or air is used as a coolant to dissipate heat. The different temperature of each electric cells after cooling and the high temperature of the stack affect the performance of the stack, Therefore, it is necessary that the relationship between coolant, healing rate, width of slack, properties of stack, and the shape of water flow path must be understood. For the optimal design, the computational simulation by CFD-ACE has been conducted and the resulting database has been constructed.

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Restraint of carbon deposition in diesel ATR using fuel atomizer (연료 미립화기를 이용한 디젤 자열개질기 내 탄소침적 억제)

  • Yoon, Sang-Ho;Kang, In-Yong;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.67-70
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    • 2007
  • Diesel autothermal reforming has several problems such as carbon deposition in reforming reactor, sulfur poisoning of catalyst, difficulty of aromatics decomposition and mixing problems of reactants(diesel, steam, oxygen). Severe carbon deposition causes the rapid performance degradation of reformer. Carbon deposition is formed from ethylene, carbon precursor. Ethylene was generated at the homogeneous reaction zone of the reactor entrance. This phenomenon is closely linked to the mixing of reactants. In this investigation, we try to minimize the ethylene generation at the reactor entrance atomization technique.

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Operating Characteristics of $1Nm^3/hr$ class Natural Gas Fuel Processor for Residential Fuel cells (가정용 연료전지 $1Nm^3/hr$급 천연가스 연료처리장치의 운전 특성)

  • Shin, Jang-Sik;Shin, Seock-Jae;Lee, Seung-Young;Yang, Hye-Kyong;Sung, Bong-Hyun;Kim, Doo-Hoon;Park, Jong-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.19-22
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    • 2007
  • In this study, we investigated operating characteristics of natural gas fuel processor for polymer electrolyte membrane fuel cells (PEMFCs). The fuel processor consists of a natural gas reformer, a water-gas shift reactor, a heat-exchanger and a burner, in which the overall integrated volume is exactly(exceptionally) small, namely, about 10L except outer insulation. The producted hydrogen is $1Nm^3/hr$ and the maximum thermal efficiency is ${\sim}76%$(low heating value) at full operating load. A compact and highly efficient $1Nm^3/hr$ class natural gas fuel processor was developed at UNISON is an advantage for application in residential PEMFCs co-generation systems.

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Hydrogen Generation Characteristics of SMART Process with Inherent $CO_2/H_2$ Separation (CO$_2/H_2$ 원천분리 SMART 공정의 수소생산특성)

  • Ryu, Ho-Jung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.55-58
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    • 2007
  • To check the feasibility of SMART (Steam Methane Advanced Reforming Technology)system, an experimental investigation was conducted. A fluidized bed reactor of diameter 0.052 m was operated cyclically up to the $10^{th}$ cycle, alternating between reforming and regeneration conditions. FCR-4 catalyst was used as the reforming catalyst and calcined limestone (domestic, from Danyang) was used as the $CO_2$ absorbent. Hydrogen concentration of 98.2% on a dry basis was reached at $650^{\circ}C$ for the first cycle. This value is much higher than $H_2$ concentration of 73.6% in the reformer of conventional SMR (steam methane reforming) system. However, the hydrogen concentration decreased because the $CO_2$ capture capacity decreased as the number of cycles increased.

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Operational Optimization of Anodic/cathodic Utilization for a Residential Power Generation System to Improve System Power Efficiency (가정용 연료전지 시스템의 전기 효율 향상을 위한 연료/공기 이용률 운전 최적화)

  • Seok, Donghun;Kim, Minjin;Sohn, Young-Jun;Lee, Jinho
    • Journal of Hydrogen and New Energy
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    • v.24 no.5
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    • pp.373-385
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    • 2013
  • To obtain higher power efficiency of Residential Power Generation system(RPG), it is needed to operate system on optimized stoichiometric ratios of fuel and air. Stoichiometric ratios of fuel/air are closely related to efficiency of stack, reformer and power consumption of Balance Of Plant(BOP). In this paper, optimizing stoichiometric ratios of fuel/air are conducted through systematic experiments and modeling. Based on fundamental principles and experimental data, constraints are chosen. By implementing these optimum values of stoichiometric ratios, power efficiency of the system could be maximized.

Fabrication and Chacterization of Planar Solid Oxide Fuel Cell (평판형 고체산화물 연료전지 제조 및 특성 연구)

  • Song, Rak-Hyun;Lee, Byun-Rok;Kim, Chang-Soo;Shin, Dong-Ryul
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1700-1702
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    • 1996
  • Solid oxide fuel cell(SOFC) is an electrochemical energy device which converts the free energy of fuel gas directly to electric energy. SOFC has several diratinct advantages over other types of fuel cells: no use of noble metals, no requirement of a reformer, no problem of liquid electrolyte management, and no problem of corrosion by liquid electrolyte. In this study, we have investigated the cell components and the single cell of the planar SOFC fabricated by composite plate process, in which green films of electrolyte, anode and cathode were co-fired. The planar SOFCs were tested and the cell performance characteristics wag evaluated by using electrochemical methods.

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Investigation of the Water Gas Shift from Reforming Gas for CO Removal (일산화탄소 저감을 위한 개질가스의 전이반응 연구)

  • Kim, Seong-Cheon;Youn, Moon-Jung;Chun, Young-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.10
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    • pp.855-859
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    • 2007
  • Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

Atmospheric and Pressurized Operation of a 25 kW MCFC Stack (25 kW급 용융 탄산염 연료 전지 스택의 상압 및 가압 운전)

  • Koh, Joob-Ho;Seo, Hai-Kung;Lim, Hee-Chun
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.264-269
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    • 2000
  • As a part of the ongoing effort towards commercial application of high-temperature fuel cell power generation systems, we have recently built a pilot-scale molten carbonate fuel cell power plant and tested it. The stack test system is composed of diverse peripheral units such as reformer, pre-heater, water purifier, electrical loader, gas supplier, and recycling systems. The stack itself was made of 40cells of $6000cm^2$ area each. The stack showed an output higher than 25kW power and a reliable performance at atmospheric operation. A pressurized performance was also tested, and it turned out the cell performance increased though a few cells have shown a symptom of gas crossover. The pressurized operation characteristics could be analyzed with numerical computation results of a stack model.

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Operating Characteristics of Pilot Scale Multi-Staged Waste Pyrolysis & Gasification System (파일럿 규모의 폐기물 다단열분해 가스화시스템의 운전특성)

  • Lee, Jeong-Woo;Yu, Tae-U;Bang, Byeong-Ryeol;Moon, Ji-Hong;Lee, Jae-Uk;Park, Sang-Shin;Kim, Nack-Joo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.331-335
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    • 2009
  • A novel multi-staged waste pyrolysis & gasification system of pilot scale (~1 ton/day) is designed and constructed in Korea Institute of Industrial Technology. The pyrolysis & gasification system is composed of pyrolysis & gasification system, syngas reformer, syngas cleaning system, gas engine power generation system and co-combustion system. For each unit process, experimental approaches have been conducted to find optimal design and operating conditions. As a result, We can produce syngas with a calorific value of ~4000 kcal/$Nm^3$ and cold gas efficiency of the system is more than 55 % in case of waste plastic and oxygen as a gasifying agent.

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Heat and mass transfer characteristics in steam reforming reactor (수증기 개질 반응기 내의 열 및 물질전달 특성에 관한 연구)

  • Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.56-63
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    • 2006
  • In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reforming reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. From various parametric studies, significance of heat transfer is emphasized in steam reforming reaction.

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