• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1254-1254
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• 2001

Near infrared spectroscopy (NIRS) was applied to determination of the lipid content of compost during compost fermentation of tofu(soybean-curd) refuse. The reflected rays in the wavelength range between 800 and 2500 nm were measured at 2 nm intervals. The absorption of lipid observed at 4 wavelengths, 1208, 1712, 2312 and 2352 nm on the second derivative spectra. To formulate a calibration equation, a multiple linear regression analysis was carried out between the near-infrared spectral data and on the lipid content in the calibration sample set (sample number, n=60) obtained using a Soxhlet extraction method. The calibration equation for prediction of lipid, the value of the multiple correlation coefficient (R) was 0.975 when using the wavelengths of 1208 and 1712nm. To validate the calibration equation obtained, the lipid content in the validation sample set (n=35) not used for formulating the calibration equation were calculated using the calibration equations, and compared with the values obtained using the Soxhlet extraction method. Good agreement were observed between the results of the Soxhlet extraction method and those values of the NIRS method. The simple correlation coefficient (r) and standard error of prediction (SEP) were 0.964 and 0.815 %, respectively. Then, the NIRS method was applied to a compost fermentation in which the time course the lipid content were measured and good results were obtained. The study indicates that NIRS is a useful method for process management of the compost fermentation of tofu refuse.

• 한국지진공학회논문집
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• 제22권7호
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• pp.391-399
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• 2018

The site coefficients in the common requirements for seismic design codes, which were promulgated in 2017, were reevaluated and the standard design spectrum for soil sites were newly proposed in order to ensure the consistency of the standard design spectra for rock and soil sites specified in the common requirements. Using the 55 ground motions from domestic and overseas intraplate earthquakes, which were used to derive the standard design spectrum for rock sites, as rock outcropping motions, site response analyses of Korean soil were performed and its ground-motion-amplification was characterized. Then, the site coefficients for soil sites were reevaluated. Compared with the existing site coefficients, the newly proposed short-period site coefficient $F_a$ increased and the long-period site coefficient $F_v$ decreased overall. A new standard design spectrum for soil sites was proposed using the reevaluated site coefficients. When compared with the existing design spectrum, it could be seen that the proposed site coefficients and the standard design spectrum for soil sites were reasonably derived. They reflected the short-period characteristics of earthquake and soil in Korea.

• 한국해안해양공학회지
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• 제15권1호
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• pp.11-20
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• 2003

본 논문에서는 규칙파 모델을 이용하여 유공케이슨 방파제로부터의 불규칙파의 반사를 계산하는 몇 가지 방법들을 검토한다. 첫 번째 방법은 불규칙파를 파고 및 주기가 각각 불규칙파의 제곱평균제곱근 파고 및 유의주기와 같은 규칙파로 근사하는 것이다. 두 번째는 불규칙파 스펙트럼의 각 주파수 성분에 대하여 규칙파 모델을 반복적으로 사용하는 것이다. 파의 주기는 성분파의 주파수에 따라 결정되며, 모든 주파수에 대해서 제곱평균제곱근 파고를 사용한다. 세 번째 방법은 두 번째 방법과 같으나, 각 성분파의 에너지에 해당하는 파고를 사용한다. 이전 연구자들의 실험 결과와 비교해 본 결과, 두 번째 방법이 가장 타당하며, 주파수 평균 반사율과 반사파 스펙트럼 모두 실험치와 양호한 일치를 보였다.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2006년도 춘계학술대회 논문집
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• pp.341-343
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• 2006

The current spectral shape matching method (SSMM), developed by Ahn and Shanmugam (2004), relies on the assumption that the path radiance resulting from scattered photons due to air molecules and aerosols and possibly direct-reflected light from the air-sea interface is spatially homogeneous over the sub-scene of interest, enabling the retrieval of water-leaving radiances ($L_w$) from the satellite ocean color image data. This assumption remains valid for the clear atmospheric conditions, but when the distribution of aerosol loadings varies dramatically the above postulation of spatial homogeneity will be violated. In this study, we present the second version of SSMM which will take into account the horizontal variations of aerosol loading in the correction of atmospheric effects in SeaWiFS ocean color image data. The new version includes models for the correction of the effects of aerosols and Raleigh particles and a method fur computation of diffuse transmittance ($t_{os}$) as similar to SeaWiFS. We tested this method over the different optical environments and compared its effectiveness with the results of standard atmospheric correction (SAC) algorithm (Gordon and Wang, 1994) and those from in-situ observations. Findings revealed that the SAC algorithm appeared to distort the spectral shape of water-leaving radiance spectra in suspended sediments (SS) and algal bloom dominated-areas and frequently yielded underestimated or often negative values in the lower green and blue part of the electromagnetic spectrum. Retrieval of water-leaving radiances in coastal waters with very high sediments, for instance = > 8g $m^{-3}$, was not possible with the SAC algorithm. As the current SAC algorithm does not include models for the Asian aerosols, the water-leaving radiances over the aerosol-dominated areas could not be retrieved from the image and large errors often resulted from an inappropriate extrapolation of the estimated aerosol radiance from two IR bands to visible spectrum. In contrast to the above results, the new SSMM enabled accurate retrieval of water-leaving radiances in a various range of turbid waters with SS concentrations from 1 to 100 g $m^{-3}$ that closely matched with those from the in-situ observations. Regardless of the spectral band, the RMS error deviation was minimum of 0.003 and maximum of 0.46, in contrast with those of 0.26 and 0.81, respectively, for SAC algorithm. The new SSMM also remove all aerosol effects excluding areas for which the signal-to-noise ratio is much lower than the water signal.

• 한국지반공학회논문집
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• 제32권8호
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• pp.5-14
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• 2016

싱크홀 발생의 주요 원인인 하수관거 배면의 공동 탐지를 위해 비파괴검사 방법 중 하나인 충격반향법을 적용한 실내 모형 실험을 수행하였다. 콘크리트 하수관의 모의를 위해 얇은 두께의 콘크리트 평판 시험체를 제작하였고 주변지반은 모래로 조성하였으며 공동의 모사를 위해 스티로폼 박스를 모래에 매립하였다. 콘크리트 판 배면이 공동인 경우와 완전히 모래에 밀착된 경우로 나누어 실험이 진행되었으며 일정한 타격 강도의 유지를 위해 새롭게 제작된 타격 장치를 사용하여 획득 자료의 신뢰성을 높였다. 측정된 반사파는 고속 푸리에 변환과 국소 푸리에 변환을 사용하여 주파수 특성 및 시간 특성을 분석하였다. 그 결과, 푸리에 스펙트럼의 형상으로는 공동의 유무를 판별할 수 없는 것으로 나타났다. 본 연구에서는 공진 시간이라고 명한 새로운 지표를 제안하였다. 이는 공진 주파수가 일정 강도를 초과하는 지속 시간으로 정의하였다. 공진 시간은 공동의 유무를 효과적으로 예측하는 것으로 나타났다. 나아가 공동유무를 구분할 수 있는 공진 시간을 제시하였다. 실제 현장 조건에서의 검증과 보다 광범위한 적용성의 확보를 위해 다양한 지반 조건에 대한 추가 실험과 실제 하수관에 대한 현장 실험 등을 진행할 예정이다.

• Bulletin of the Korean Chemical Society
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• 제7권2호
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• pp.137-142
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• 1986

The luminescence spectra of $Ru(bpy)_3^{2+}$ in poly(methacrylic acid) (PMA) solutions varied sensitively with pH. At pH < 5.5, the emission intensity increased with pH up to 4 times, while it decreased with pH beyond the pH. The enhanced emission intensity was accompanied by blue-shift of the emission maxima as much as 15 nm. The enhancement of emission intensity was attributed to the restricted rotational mobility of ligand of the cation bound to densely coiled PMA molecules at pH < 5.5. The sharp decrease in emission intensity with increasing pH near pH 5.6 was accounted for conformational transition of the polymer to more extended structure, which was also revealed in viscosity measurement. The enhancement of emission intensity became higher as NaCl concentration of the solution increased. The binding constant of $Ru(bpy)_3^{2+}$ with two carboxylate groups of PMA was calculated as $2{\times}10^5\;M^{-1}$ in 0.1 M NaCl at pH 5.2. The pH dependence of luminescence quenching rate of $Ru(bpy)_3^{2+}$ by $Cu^{++}$ also showed maximum near pH 5, and the rate was more than $10^3$ times higher than that in water, whereas the maximum enhancement of quenching rate (about 20 times) in poly(acrylic acid) (PAA) solution occurred at pH 4.5. On the other hand, the pH dependence for neutral water soluble nitrobenzene (NB) exhibited opposite trend to that of $Cu^{++}$. The quenching constant vs pH curve for $MV^{++}$ was composite of those for $Cu^{++}$ and NB. The anomalous high quenching rate for $Cu^{++}$ in PMA solution at pH < 5.5 was attributed to the binding of $Ru(bpy)_3^{2+}$ and $Cu^{++}$ to the same region of PMA, when it conforms densely coiled structure in the pH range. The observation of mininium quenching rate for NB near pH 5.5 indicated that the $Ru(bpy)_3^{2+}$ bound to the densely coiled PMA is not accessible by NB, which is in bulk water phase. The composite nature of the pH dependence of quenching rate for $MV^{++}$ in PMA solution was attributed to the smaller binding affinity of the cation to PMA, compared to that of $Cu^{++}$. The sharp, cooperative conformational transition with pH observed in PMA was not revealed in PAA. But, the pH dependence of quenching rates in this polymer reflected increased charge density and, thus, binding of cations to the polymer, and expansion of the polymer chain with pH.