• Title/Summary/Keyword: refinery process

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Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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MINERAL PROCESSING and COPPER EXRACTIVE METALLURGY Complete Metal Recovery

  • Kim, J.Y.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.22-34
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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A Study on the Water Pollutant Discharge Inventories for the Improvement of Industrial Wastewater Management System: Primary Steel Manufacturing Facility and Petroleum Refining Products Manufacturing Facility (산업폐수 관리체계 개선을 위한 수질오염물질 배출목록 구축에 대한 연구: 1차 철강 제조업과 석유정제품 제조업)

  • Ahn, Taeung;Kim, Dongmin;Son, Daehee;Kim, Jaehoon
    • Journal of Korean Society on Water Environment
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    • v.36 no.5
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    • pp.453-467
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    • 2020
  • This study aimed to inventory the water pollutant discharge of wastewater from two facilities, one primary steel manufacturing facility and one petroleum refinery, both of which are located in Korea, and to identify ways to improve the wastewater treatment process through field investigation. Probability evaluation was used to inventory the substances in polluted water. The samples collected in this study included original wastewater, on processing wastewater, and treated water. The general description of wastewater occurrence, major sources, and treatment facilities were also investigated to obtain an integrated database of the pollutants created by different industrial categories. Based on our analysis of raw wastewater and final effluent, the detected pollutants were confirmed by analyzing their presence in the raw or supplemental materials, the potential of formation as byproducts, and the possibility of inclusion as impurities. The compounds detected for each category were screened via investigation of their possible sources and confirmed as the final water pollutant inventories. Thirty kinds of water pollutants were emitted by the primary steel manufacturing facility (reference in case A), including 14 specified hazardous water pollutants. The petroleum refinery (reference in case B) emitted 36 water pollutants, including 16 specified hazardous water pollutants.

A Study on the Desulfurization of Petroleum Cokes by Microwave Heating (마이크로웨이브 가열에 의한 석유 코크스의 탈황에 관한 연구)

  • Park, Min-Gyu;Kang, Tae-Won
    • Clean Technology
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    • v.8 no.1
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    • pp.11-17
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    • 2002
  • Petcokes is the final product obtained from a refinery process. This petcokes includes high percentage of inorganic and sulfur compounds. Currently, the petcokes produced from domestic refinery plants include more than 6% of sulfur. To use petcokes as valuable raw materials, the weight percentage of sulfur must be lower than 2% of sulfur. Solvent extraction, thermal desulfurization, and hydro-desulfurization have been used to remove the sulfur. In this study, we attempted new approach to remove the sulfur introducing microwave energy. Microwave increase the reaction rates by providing the fast heating and disconnecting the bonding structure of the molecules. The experiments of microwave thermal desulfurization and microwave plus hydrogen gas were carried out to remove the sulfur. We obtained 68.3% of sulfur removal rate with the 2 hours of reaction time and 1835 W of microwave powder. In the experiment of microwave with hydrogen gas, we obtained 86.4% of sulfur removal rate with the 1.5 hours of reaction time and 1835 W of microwave power. If we increase reaction time or decrease the particle size of petcokes, we expect more than 90% of sulfur removal.

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Assessment of applicability on Solidification/Stabilization of Arsenic in contaminated Soil According to the Revised Korean Standard Leaching Test for Soil (개정 토양용출시험법에 따른 비소오염토양의 고형화/안정화 공법 국내 적용성 평가)

  • Hong, Seong-Hyeok;Park, Hye-Min;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.1
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    • pp.1-5
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    • 2011
  • Arsenic is one of the most abundant contaminant found in waste mine tailings and soil around refinery, Because of its carcinogenic property, the countries like United States of America and Europe have made stringent regulations which govern the concentration of arsenic in soil. The study focuses on solidification/stabilization for removal of arsenic from soil. Cement was used to solidify/stabilize the abandoned soil primarily contaminated with arsenic (up to 68.92 mg/kg) in and around refinery. Solidified/stabilized (s/s) forms in the range of cement contents 5-30 wt % were evaluated to determine the optimal binder content. Revised Korean standard leaching tests (KSLT), toxicity characteristic leaching procedures (TCLP), Old Korea standard leaching test and revised Korea standard leaching test were used for chemical characterization of the S/S forms. The addition of 10 % cement remarkably reduced the leachability of arsenic in contaminated soil. The concentration of As in leachate of TCLP, KSLT, and old KSLT for soil are below the standard. However that in leachate of revised KSLT is above the standard. Because of extraction fluid used in revised KSLT is very strong acid. It is arsenic in s/s with binder should be exhaustingly leached. Therefore S/S process would not be available for As treatment in soil in Korea.

Application of a Thermophilic Aerobic Digestion Process to Industrial Waste Activated Sludge Treatment

  • Kim, Young-Kee;Eom, Yong-Suk;Oh, Byung-Keun;Lee, Won-Hong;Choi, Jeong-Woo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.570-576
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    • 2001
  • Thermophilic aerobic bacteria were applied in the degradation of industrial waste activated sludge (WAS) on a laboratory scale expreiment. The performance of digestion was estimated by measuring the reduction of total suspended solids (TSS), dissolved organic carbon (DOC), and total organic carbon (TOC). Among three strains of Bacillus stearothermophilus and three strains of Thermus species, B. stearothemophilus ATCC 31197 showed the best overall efficiency level for the degradation of industrial WAS, which was collected from a wastewater treatment plant in an oil refinery factory. Industrial WAS coul be successfully detraded in a batch digestion with ATCC 31197. The stability of the digestion process with ATCC 31197 was successfully verified by semi-continuous (fill-and-draw) digestion experiment. From the results of this study, it was shown that the thermophilic aerobic digestion process with ATCC 31197 could efficiently be applied to the degradation of industrial WAS.

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The development of UV falme detector (UV 화재감지장치 개발)

  • Gwon, O-Seung;Jeong, Chang-Gi;Lee, Bok-Yeong
    • Fire Protection Technology
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    • s.28
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    • pp.48-54
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    • 2000
  • The technique detects radiant energy form a flaming fire of fuels contained carbonaceous material can be applied to fast growing fires. This technique applied detectors are ultimately effective when early detecting fire alarm system is required or the smoke and heat detectors can not applied. In Korea Fire regulation, a flame detector should be install in case that the installation height is higher than 20[m], chemical plant, hangar refinery. Therefore it is really necessary that a flame detector has to be developed as soon as possible. With foundation technique of flame detector, ideal sensing element and stable circuit design, a trial UV flame detector is manufactured. The stable and reliable technique of flame detector is established through the repeateed perfomance test and modification. An early detecting fire alarm device is developed through the modification, supplement of the structure and circuit. Results of the R & D for the manufacture of an excellent flame detecting device is carried out with the establishment of technique for the mass production and the qualified manufacturing process.

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Design of Light Guide Plate for Photobioreactor (광생물 반응기를 위한 도광판 설계)

  • Park, Gi-Chan;Kim, Hun;Kim, Jong-Tye;Park, Jeong-Woo;Jeong, Sang-Hwa;Park, Jong-Rak
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.2
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    • pp.133-139
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    • 2011
  • We have performed optical design of light guide plates (LGPs) for a photobioreactor by using an illumination design tool. An LGP having light emitting diodes (LEDs) as a light source on the four sides was designed by optimizing the distribution of LGP patterns and design of another LGP, on top of which sunlight was focused by a Fresnel lens, was executed. Finally, a hybrid-solar-and-LED-lighting scheme was described. Detailed design process and optical performances of the designed LGPs are presented.

SYNTHESIS OF SILICA-COATED Au WITH Ag, Co, Cu, AND Ir BIMETALLIC RADIOISOTOPE NANOPARTICLE RADIOTRACERS

  • Jung, Jin-Hyuck;Jung, Sung-Hee;Kim, Sang-Ho;Choi, Seong-Ho
    • Nuclear Engineering and Technology
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    • v.44 no.8
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    • pp.971-976
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    • 2012
  • Silica-coated Au with Ag, Co, Cu, and Ir bimetallic radioisotope nanoparticles were synthesized by neutron irradiation, after coating $SiO_2$ onto the bimetallic particles by the sol-gel St$\ddot{o}$ber process. Bimetallic nanoparticles were synthesized by irradiating aqueous bimetallic ions at room temperature. Their shell and core diameters were recorded by TEM to be 100 - 112 nm and 20 - 50 nm, respectively. The bimetallic radioisotope nanoparticles' gamma spectra showed that they each contained two gamma-emitting nuclides. The nanoparticles could be used as radiotracers in petrochemical and refinery processes that involve temperatures that would decompose conventional organic radioactive labels.

Design Analysis to Enhance Rotordynamic Stability of High-Speed Lightweight Centrifugal Compressor - Part I: Effects of Bearing Designs (프로세스 고속 경량 원심 압축기의 로터다이나믹 안정성 강화를 위한 설계해석 - Part I: 베어링 설계의 영향)

  • Lee, An Sung
    • Tribology and Lubricants
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    • v.29 no.6
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    • pp.386-391
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    • 2013
  • Part I of this study analyzed the effects of tilting pad bearing designs to reduce the stiffness of the bearings used in a process high-speed lightweight centrifugal compressor intended for a domestic refinery use. This was done in an attempt to enhance the robustness of its rotordynamic stability against possible aerodynamic cross-coupled stiffness. The bearing design variables reviewed were the clearances, LBPs, LOPs, and preloads. The results showed that there was practically no difference between the LBP and LOP designs in terms of the bearing stiffness, because the compressor rotor was lightweight and the bearings had relatively high preloads. Increasing both the machined and assembled clearances in bearing designs has resulted in the bearing stiffness being greatly reduced. In addition, it has been confirmed that an additional reduction in the bearing stiffness can be obtained for given fixed machined clearances by decreasing the preloads, i.e., by increasing the assembled clearances.