• Title/Summary/Keyword: refinery

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An Empirical Study on the Performance of the Medium-Sized Distributor's Offsetting Investment and Relationship Commitment with Large-sized Manufacturing Firm in the Marketing Channel (유통경로상의 상쇄투자와 관계결속이 경로구성원의 성과에 미치는 영향)

  • 이수동;이영건
    • Journal of Distribution Research
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    • v.4 no.2
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    • pp.1-20
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    • 1999
  • This study aims to provide distributors with several implications on the channel strategy by testing factors which influence on the offsetting investment. Medium-sized distributor facing a relatively inferior power can cause profit vulnerability from large manufacurer's opportunistic behaviors. At the same time, we tested the relationship commitment to the relation with manufacturer as another alternative strategy taken by medium-sized distributer. For this research, samples from dealers in oil-petroleum refinery industry were selected and the data was collected using mail survey. The data was analyzed utilizing validity test, reliability test, factor analysis, correlation analysis and LISREL. The major analyzed results are as follows: First, the offsetting investment of preventing loss from manufacturer's opportunism didn't affect medium-sized distributor's sales empirically. Second, the hypothesis that the more the medium-sized distributor's transaction specific assets which they invest in the transactional relationship with manufacturer, the more the safeguard against the expected opportunism of manufacturer was not supported by the results. Third, the more use of coercive power by the manufacturer, the more increase in the perception of expected opportunism of manufacturer by the medium-sized distributor, it make stimulates offsetting investment as safeguard by medium-sized distributor and it has negative effect on developing commitment. Finally, the large manufactures dealing with a medium-sized distributor firm which had a reputation of fairness didn't make offsetting investment as a response for distributor's opportunism.

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Water-Methanol and Water-Acetonitrile Mixture Analysis using NIR Spectral Data and Iterative Target Transform Factor Analysis

  • Na, Dae-Bok;Hur, Yun-Jeong;Park, Young-Joo;Cho, Jung-Hwan
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1289-1289
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    • 2001
  • Water-methanol and water-acetonitrile mixtures are frequently used as HPLC solvent system and strong hydrogen bonding is well-known. But a detailed aspect of water-methanol and/or water-acetonitrile mixtures have not been shown with direct spectral evidence. Recently, near infrared spectroscopy and chemometric data refinery have been successfully combined in many applications. On the basis of factor analytical methods, the spectral features of water-methanol and water-acetonitrile mixtures were studied to reveal the detail of mixtures. Water-methanol and water-acetonitrile mixtures were prepared with varying concentration of each constituent and near infrared spectral data were acquired in the range of 1100-2500nm with 2-nm interval. The data matrices were analysed with ITTFA(Iterative Target Transform Factor Analysis) algorithm implemented as MATLAB codes. As a result, the concentration profiles of water, methanol and water-methanol complex were resolved and the spectra of water-methanol complexes were calculated, which cannot be acquired with pure complexes. A similar result was obtained with NIR spectral data of water-acetonitrile mixtures. Moreover, pure spectra of hydrogen-bonding complexes of water-methanol and water-acetonitrile can be computed, while any other usual physical methods cannot isolated those complexes for acquiring pure component spectra.

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A Case Study on Health Impact Assessment from Petroleum Refinery Plant Operation - Human Risk Assessment due to Chemicals Inhalation - (석유정제시설 운영에 대한 건강영향평가 사례 연구 - 화학물질 흡입에 따른 인체 위해도 평가 -)

  • Myung, Nho-Il;Lee, Young-Soo;Shin, Dae-Yewn
    • Journal of Environmental Impact Assessment
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    • v.19 no.3
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    • pp.259-270
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    • 2010
  • We conducted human risk assessment for exposure to inhalation of chemical substances emitted from the storage tanks of petroleum refineries. To assess human risk, this study calculated chemical emissions from the external floating roofs on storage tank at petroleum refineries, as well as concentrations thereof in the ambient air using the K-SCREEN model, and then determined risk in accordance with the Reference Concentration (RfC) values and Inhalation Unit Risk criteria developed by the US Environmental Protection Agency. The results indicated that non-carcinogenic chemicals have a hazard quotient of less than 1, meaning they have an insignificant effect on human health for residential areas near the storage tanks. Among the known carcinogens, the hazard risk for benzene slightly exceeded $10^{-6}$, indicating the need for corrective reduction measures. The methodology for health impact assessment devised herein provides findings useful in decision making for policy makers and the general public with respect to construction of industrial complexes. However, the methodology proposed herein does have limitations, including discrepancy in results induced by use of U.S. data (due to the lack of usable domestic data). More systematic studies from related researchers will be needed to address these issues and produce more reliable outcomes.

The Development of UV-IR Combination Flame Detector (UV-IR 복합형 화재감지장치 개발)

  • 이복영;권오승;정창기;박상태
    • Journal of the Korean Society of Safety
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    • v.16 no.1
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    • pp.1-8
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    • 2001
  • All objects emit thermal radiation and this radiation is the basis of the techniques used to detect flames. The usual phenomena occurring in the initial stage of the fire are generally invisible products of a combustion and visible smoke. Liquid or gaseous materials do not undergo a smoldering stage so that fires develop very rapidly. Also, the heat generated by the initial flames is usually not sufficient to activate a heat detector. In this case the most effective criterion for automatic fire detection is the flame. According to the fire regulation of korea, the compulsory standard provided that a flame detector shall be installed in a place that the attachment height of detector is higher than 20 m, chemical plants, hangar, refinery, etc.. The results of the research and development are discriminated between a flame and other radiant emitters, developed a UV detector tube contains an inert gas which absorbs UV radiation, developed PZT pyroelectric element is based on the use of photovoltanic cell, developed IR band-pass filter that only allow a 4.3 $\mu\textrm{m}$ radiation wavelength to reach the sensors and developed UV-IR combination flame detector combined into a single detection device.

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Fungal Secretome for Biorefinery: Recent Advances in Proteomic Technology

  • Adav, Sunil S.;Sze, Siu Kwan
    • Mass Spectrometry Letters
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    • v.4 no.1
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    • pp.1-9
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    • 2013
  • Fungal biotechnology has been well established in food and healthcare sector, and now being explored for lignocellulosic biorefinery due to their great potential to produce a wide array of extracellular enzymes for nutrient recycling. Due to global warming, environmental pollution, green house gases emission and depleting fossil fuel, fungal enzymes for lignocellulosic biomass refinery become a major focus for utilizing renewal bioresources. Proteomic technologies tender better biological understanding and exposition of cellular mechanism of cell or microbes under particular physiological condition and are very useful in characterizing fungal secretome. Hence, in addition to traditional colorimetric enzyme assay, mass-spectrometry-based quantification methods for profiling lignocellulolytic enzymes have gained increasing popularity over the past five years. Majority of these methods include two dimensional gel electrophoresis coupled to mass spectrometry, differential stable isotope labeling and label free quantitation. Therefore, in this review, we reviewed more commonly used different proteomic techniques for profiling fungal secretome with a major focus on two dimensional gel electrophoresis, liquid chromatography-based quantitative mass spectrometry for global protein identification and quantification. We also discussed weaknesses and strengths of these methodologies for comprehensive identification and quantification of extracellular proteome.

Design Analysis to Enhance Rotordynamic Stability of High-Speed Lightweight Centrifugal Compressor - Part I: Effects of Bearing Designs (프로세스 고속 경량 원심 압축기의 로터다이나믹 안정성 강화를 위한 설계해석 - Part I: 베어링 설계의 영향)

  • Lee, An Sung
    • Tribology and Lubricants
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    • v.29 no.6
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    • pp.386-391
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    • 2013
  • Part I of this study analyzed the effects of tilting pad bearing designs to reduce the stiffness of the bearings used in a process high-speed lightweight centrifugal compressor intended for a domestic refinery use. This was done in an attempt to enhance the robustness of its rotordynamic stability against possible aerodynamic cross-coupled stiffness. The bearing design variables reviewed were the clearances, LBPs, LOPs, and preloads. The results showed that there was practically no difference between the LBP and LOP designs in terms of the bearing stiffness, because the compressor rotor was lightweight and the bearings had relatively high preloads. Increasing both the machined and assembled clearances in bearing designs has resulted in the bearing stiffness being greatly reduced. In addition, it has been confirmed that an additional reduction in the bearing stiffness can be obtained for given fixed machined clearances by decreasing the preloads, i.e., by increasing the assembled clearances.

A Rotordynamic and Stability Analysis of Process Gas Turbo-Compressor in accordance with API 617 Standard (API 617 규격에 의거한 프로세스 가스 터보압축기의 로터다이나믹 해석 및 안정성 검토)

  • Kim, Byung-Ok;Lee, An-Sung
    • The KSFM Journal of Fluid Machinery
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    • v.12 no.5
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    • pp.47-53
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    • 2009
  • A rotordynamic and detailed stability analysis in accordance with API 617 standard were performed with a turbo-compressor, which is one of key rotating machinery in refinery, petroleum, and power plants. The system is composed of rotor shaft, impeller, sleeve hub, balance drum, and coupling hub. The rotor system is supported by tilting pad bearings, which has 5 pads and pad on loading condition. The rotordynamic analysis specified by API 617 includes the critical speed map, mode shape analysis, Campbell diagram, unbalance response analysis, and stability analysis. In particular, the specifications of stability analysis consist of a Level 1 analysis that approximates the destabilizing effects of the labyrinth seals and aerodynamic excitations, and Level 2 analysis that includes a detailed labyrinth seal aerodynamic analysis. The results of a rotordynamic analysis and stability analysis can evaluate the operating compressor health and can be utilized as a guide of its maintenance, repair and trouble solution.

A Study on Implementation of Risk Based Inspection Procedures to a Petrochemical Plant (RBI 절차의 석유화학 플랜트 적용에 관한 연구)

  • Song, Jung-Soo;Shim, Sang-Hoon;Kim, Ji-Yoon;Yoon, Kee-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.3
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    • pp.416-423
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    • 2003
  • During the last ten years, the need has been increased for reducing maintenance cost for aged equipments and ensuring safety, efficiency and profitability of petrochemical and refinery plants. RBI (Risk Based Inspection) methodology is one of the most promising technologies satisfying the need in the field of integrity management. In this study, a user-friendly software, realRBl for RBI based on the API 581 code was developed. This software has modules for evaluating qualitative and semi-quantitative risk level, analyzing quantitative risks using the potential consequences of a failure of the pressure boundary, and assessing the likelihood of failure. A quantitative analysis was performed for 16 columns in a domestic NCC (Naphtha Cracking Center) plant whose operating time reaches about 12 years. Each column was considered as two equipment parts by dividing into top and bottom. Generic column failure frequencies were adjusted based on likelihood data. After determining release rate, release duration and release mass for each failure scenario, flammable/explosive and toxic consequences were assessed. Current risks for 32 equipment parts were evaluated and risk based prioritization were determined as a final result.

Recent Trends of the Development of Photobioreactors to Cultivate Microalgae (미세조류 배양을 위한 광생물반응기 개발의 기술동향)

  • Kim, Jong-Tye;Ahn, Dong-Gyu;Park, Jong-Rak;Park, Jeong-Woo;Jeong, Sang-Hwa
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.2
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    • pp.125-132
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    • 2011
  • This paper describes current status and future prospects of the mass production of microalgae biomass. Microalgae have attracted considerable attention since they not only effectively fix $CO_2$ gas during their metabolic process but also have the great potential to be utilized for producing valuable substances as a kind of efficient light-harvesting cell factories. In this review, we outline various types of photobioreactors employed for mass production of biomass by culturing microalgae in a well controlled way and give an overview about the present state of affairs, both domestic and international, in the field of the microalgal culturing technologies.

Computer modeling of crack propagation in concrete retaining walls: A case study

  • Azarafza, Mehdi;Feizi-Derakhshi, Mohammad-Reza;Azarafza, Mohammad
    • Computers and Concrete
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    • v.19 no.5
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    • pp.509-514
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    • 2017
  • Concrete retaining walls are the most common types of geotechnical structures for controlling instable slopes resulting from lateral pressure. In analytical stability, calculation of the concrete retaining walls is regarded as a rigid mass when its safety is required. When cracks in these structures are created, the stability may be enforced and causes to defeat. Therefore, identification, creation and propagation of cracks are among the important steps in control of lacks and stabilization. Using the numerical methods for simulation of crack propagation in concrete retaining walls bodies are among the new aspects of geotechnical analysis. Among the considered analytical methods in geotechnical appraisal, the boundary element method (BEM) for simulation of crack propagation in concrete retaining walls is very convenient. Considered concrete retaining wall of this paper is Pars Power Plant structured in south side in Assalouyeh, SW of Iran. This wall's type is RW6 with 11 m height and 440 m length and endurance of refinery construction lateral forces. To evaluate displacement and stress distributions (${\sigma}_{1,max}/{\sigma}_{3,min}$), the surrounding, especially in tip and its opening crack BEM, is considered an appropriate method. By considering the result of this study, with accurate simulation of crack propagation, it is possible to determine the final status of progressive failure in concrete retaining walls and anticipate the suitable stabilization method.