• Title/Summary/Keyword: reference electrode

Search Result 282, Processing Time 0.028 seconds

SOx Sensor Using NASICON Solid Electrolyte (NASICON 고체 전해질을 사용한 SOx 가스 감지센서)

  • Choi, Soon-Don;Lee, Kwang-Beum
    • Journal of Sensor Science and Technology
    • /
    • v.5 no.4
    • /
    • pp.25-34
    • /
    • 1996
  • A SOx sensor using NASICON electrolyte was developed for monitoring of air pollution. The following galvanic cell with $Na_{2}SiO_{3}(Pt)$ reference electrode was assembled : Pt | $Na_{2}SiO_{3}$ | NASICON | $Na_{2}SO_{4}$ | Pt, $SO_{2}$, air $Na_{2}SO_{4}$ was used as an indicator electrode to protect NASICON electrolytes from chemical reaction with $SO_{2}$. The EMFs were measured after injecting $SO_{2}$ in the initial concentrations range of $5{\sim}95ppm$ at $400{\sim}550^{\circ}C$. The measured and calculated potentials were in good agreement above $500^{\circ}C$. However, the cells were unstable below $500^{\circ}C$, most likely due to incomplete attainment of chemical equilibrium. Response time was within 10 min. Based on the stability and response time of this cell, the NASICON solid electrolyte with $Na_{2}SiO_{3}(Pt)$ as the reference electrode and $Na_{2}SO_{4}$ (Pt)as the indicator electrode showed the possibility of a reliable, inexpensive commercial solid-state SOx sensor.

  • PDF

Proposition for 4 Channel Frontal Lobe Electrode Configuration and Study on EOG Removal from Measured EEG (4채널 전두엽 전극 배치법의 제안과 측정된 뇌파에서의 안전도 제거에 관한 연구)

  • 신수인;조진호;김명남
    • Journal of Korea Multimedia Society
    • /
    • v.6 no.1
    • /
    • pp.167-175
    • /
    • 2003
  • In this paper, a new electrode configuration and EOG removal method are proposed in order to measure EEG effectively on the frontal lobe and remove EOG in the measured raw EEG. The method of measuring EEG is proposed using four electrodes and a ground electrode on the frontal lobe with a reference electrode at the left earlobe. And also, the separation method using ICA is proposed for EOG removal from the measured EEG, Through the experiments of measuring EEG it was demonstrated that a subject can attach the electrodes by himself easily to measure his own EEG without any assistant and the proposed methods were suitable for removing EOG signal from the measured EEG.

  • PDF

Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.19 no.2
    • /
    • pp.56-66
    • /
    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

  • PDF

Electrochemical Oxidation of Ethanol at Nickel Hydroxide Electrodes in Alkaline Media Studied by Electrochemical Impedance Spectroscopy

  • Kim, Jae-Woo;Park, Su-Moon
    • Journal of the Korean Electrochemical Society
    • /
    • v.8 no.3
    • /
    • pp.117-124
    • /
    • 2005
  • Electrochemical oxidation of ethanol at nickel electrodes has been studied in 1 M KOH solution containing 0.20M ethanol using electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data, and the results were used to model the oxidation of ethanol as well as the passivation of the electrode. The maximum rate of oxidation of $Ni(OH)_2$ to NiOOH was observed at about 0.37V vs. Ag/AgCl reference electrode, while the maximum rate of ethanol oxidation at the Ni electrode was observed at about 0.42V, The charge-transfer resistance for oxidation of the electrode itself became smaller in the presence of ethanol than in its absence. These results suggest that the $\beta-Ni(OH)_2/\beta-NiOOH$ redox couple is acting as an effective electron transfer mediator far ethanol oxidation. The kinetic parameters also were obtained by the experimental and simulated results.

Detection of Protein Molecules by Electrical Current Response Using Two-Electrode Method

  • Lyu, Hong-Kun;Woo, Sung-Ho;Han, Yoon-Soo;Lee, Hee-Ho;Shin, Jang-Kyoo
    • Journal of Sensor Science and Technology
    • /
    • v.20 no.2
    • /
    • pp.90-95
    • /
    • 2011
  • In order to protect human lives from disease, various biosensors having the potential to analyze a variety of biomolecules have been utilized. Biosensors constitute one of the most promising ways to monitor and detect various biomolecules corresponding to diseases. In this study, we demonstrate that the reaction of streptavidin molecules with biotin on a gold electrode can be detected using the twoelectrode method with a gold electrode and a platinum reference electrode. We also show the characteristics of the electrical current response. While detecting 2-${\mu}M$ streptavidin molecules dissolved in phosphate buffered saline(PBS) solution, we found that an analytical biosensor can operate on the principle of detecting an antigen-antibody reaction event of protein molecules using the two-electrode method. We think that the "potential step" method might be useful to detect the occurrence of any antigen-antibody reactions and can be combined with other devices or ICs such as BJTs, MOSFETs, and OP-amps for the detection of biomolecules of diseases.

Measurement and Analysis of the Dangerous Voltage Around Grounding Electrode for Safety in Substation Ground (변전소 접지설계를 위한 접지전극 주변의 위험전압 측정과 분석)

  • Son, Seok-Geum;Kim, Jae-Chul
    • The Transactions of the Korean Institute of Electrical Engineers P
    • /
    • v.60 no.4
    • /
    • pp.214-219
    • /
    • 2011
  • The substation grounding design,"IEEE Guide for Safety in AC Substation Grounding (ANSI / IEEE Std 80)"has been widely used. Substation grounding design and substation grounding resistance of grounding network site to predict the voltage at the risk of a very important task, which is a ground fault current due to the influx of the ground network and due to rise in the Earth's potential can be applied to human dangerous Voltage within safe tolerances be configured to be the ground because the network. IEEE Std. 80 for the substation construction safety equipment on the ground securing the ground electrode and the mesh around the boundary potential distribution in terms of risk analysis by the touch voltage and the reference was to clean up the definition and the basic steps of the voltage of the voltage limits the risk of peripheral grounding electrode Suppression by the simulator through a new secure from dangerous voltage design techniques were presented.

Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.745-748
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

Recent Improvement of Luminous Efficacy for AC-PDP with Tilted Facing Electrode

  • Ok, Jung-Woo;Kim, Deok-Won;Lim, Jeong-Hwan;Kim, Dong-Hyun;Lee, Ho-Jun;Park, Chung-Hoo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.65-68
    • /
    • 2008
  • In this study, in order to improve luminous efficacy of AC-PDP, the new facing discharge structure has been suggested. The suggested structure has tilted facing electrode. It shows lower discharge current, higher luminance and luminous efficacy compared with those of reference structure with coplanar electrode structure.

  • PDF

Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성)

  • Kim, Hyun-Cheol;Gu, Han-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11b
    • /
    • pp.529-532
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

Development of Three-dimensional Chamber-type Glucose Sensor Using Micromachining Technology (마이크로머시닝 기술을 이용한 3차원 마이크로 챔버형 글루코스 센서의 개발)

  • Kim Sung Ho;Kim Chang Kyo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.6 no.1
    • /
    • pp.24-28
    • /
    • 2005
  • A micromachined biochip with a three dimensional silicon chamber was developed for the construction of biosensors. Anisotropic etching was used fur the formation of the chamber on the p-type silicon wafer(100) and then was glued to the Pyrex glass bottom-substrate with pre-deposited platinum electrode. The electrochemical characterization of its Pt electrode and Ag/AgCl reference electrode was investigated.

  • PDF