• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4A
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• pp.787-794
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• 2006

Generally, high performance concrete has characteristics such as low water-cementitious material ratio, lots of unit binder powder, thus the heat of hydration, autogenous shrinkage are tend to be increased. This study is to investigated the effect of the expansive additive and shrinkage reducing agent on the shrinkage properties of high performance concrete as a study to develop the reduction technology of the concrete shrinkage. Test results showed that the expansive additive and shrinkage reducing agent were effective the reduction of shrinkage of high performance concrete. Especially, the using method in combination with expansive additive and shrinkage reducing agent was more effective than the separately using method of that. Also, it analyzed that the combination of expansive additive of 5% and shrinkage reducing agent of 1% was the most suitable mixture, considering to the fluidity, strength and shrinkage properties.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2007.11a
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• pp.57-60
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• 2007

This study is to discuss the effect of the liquid type high early strength agent considering early strength, developing strength, and economics of the concrete using admixtures. The powder type high early strength agent does not helpful because the field application is not available such as the problem of mixing process and rack of economics. To make up these subjects, the plain mixture contains the standard type AE water reducing agent, and the types of the agents are the standard type AE water reducing agent(P),liquid type high early strength agent(AD),poly carboxylate high early strength type AE water reducing agent(E1), and naphthalene + melamine high early strength type AE water reducing agent(E2). As the Contents of the agents, E1 and E2 is two types each cases, and P is one type to satisfy the target fluidity and air content, AD is three types as 0.5, 1.0,and 1.5%. In the case that AD is mixed, the fluidity is decreased, but air content is increased. For increasing strength of the early age, using OPC is more effective than FA and BS for increasing the early strength of the concrete, and if the air content is secure as plain, the effect of the developing strength can be increased because the air content is increased about 2% in the case that AD is used.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.505-508
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• 2004

This paper investigated the setting and compressive strength of concrete with the combination of mineral and chemical admixture. According to test results, plain concrete with high early strength development type AE water reducing agent(HEAEWRA) and $10\%$ of CKD respectively had earlier setting time than concrete with AE water reducing agent by $0.5\~1.5$ hours. Setting time of concrete with retarding type AE water reducing agent(RAEWRA) and FA $30\%$, BS $60\%$ respectively retarded by as much as $4\~7.5$ hours compared with plain concrete. Plain concrete with HEA WRA, $10\%$ of CKD and RAEWRA had higher strength than that of AE water reducing agent by as much as 5MPa at 28days. From the result of the paper, it is found that the combination of mineral admixture and setting accelerating or retarding agent can reduce the hydration heat cracks by setting time difference and hydration heat reduction effects.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.156-157
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• 2017

It is possible in the case of the chemical admixtures for concrete currently being used in actual work sites to omit quality evaluation and replace it with the scores of the admixture manufactures; this can create a problem of decline in reliability in quality on the work site. Therefore this study sought to analyze the degree of influence changes in the solid content rate of lignin- and naphthalene-based water-reducing agents have on the fundamental characteristics of cement mortar. The results showed that in fresh mortar, the flow and amount of air decreases with decrease in the solid content ratio. In hardened mortar, the condensation strength had hardly any effect on the use of lignin-based water-reducing agent, but naphthalene-based water-reducing agent increased with the decrease in the solid content ratio.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.73-76
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• 2009

In ultra-high-strength concrete, chemical shrinkage is larger than drying shrinkage due to using a large amount of cement and admixtures, and this is a factor deteriorating the quality of structures. Thus, we need a new technology for minimizing the shrinkage strain of ultra-high-strength concrete. So, this study have prepared super-high-strength concrete with specified mixing design strength of over 100MPa and have evaluated a method of reducing chemical shrinkage by using expander and shrinkage-reducing agent. According to the results of this study, with regard to the change in length by chemical shrinkage, an expansion effect was observed until the age of seven days. The expansion effect was higher than previous research that used only expander or shrinkage reducing agent. In addition, ultra-high-strength concrete showed a shrinkage rate that slowed down with time, and the effect of the addition of expander material on compressive strength was insignificant. That is shown that required more database to be accumulated through experimental research for the shrinkage strain of members.

• Journal of the Korean Society of Industry Convergence
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• v.13 no.2
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• pp.99-106
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• 2010

The effects of additive and shrinkage reducing agent on the drying and autogenous shrinkage of high strength concrete are investigated in this study. As results, when the ratio of W/B(low water to binder ratio) increase, the compressive strength is decreased. Comparing with PC(portland cement) concrete, the strength is 2.8%, 3.2% and 3.8% lower respectively than that of PC when concrete mixing ratio is 0.2%, 0.3% and 0.4% in 28 days curing. Drying shrinkage strain of PC concrete showed $-650{\times}10^{-6}$ in 91 days curing. When SR(shrinkage reducing agent) of 0.2%, 0.3% and 0.4% is mixed, the drying shrinkage strains are 21%, 34% and 41% lower than those of PC in 91 days curing. Autogenous shrinkage strain of PC concrete appeared $-480{\times}10^{-6}$ in 56 days curing. When SR of 0.2%, 0.3% and 0.4% is mixed, the autogenous drying shrinkage strain are 12.5%, 19.8% and 33.3% lower than those of PC in 56 days curing. In cases of using the mineral and shrinkage agent or only using a shrinkage reducing agent also appeared same reducing effects for drying shrinkage and autogenous shrinkage.

• Journal of Fashion Business
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• v.15 no.2
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• pp.120-130
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• 2011

This study is a fundamental research on the natural Polygoum tinctoria dyeing to quantify scientifically and satisfy the reproducibility of the procedure. By dyeing the silk fabrics, the establishment of accurate dyeing method was sought. At the same time, we tried to modify the traditional dyeing methods, broaden the methods, and apply the dyeing variously. The dyeability and color changes were compared and reviewed according to the changes in the reducing temperature, reducing time, concentration of the reducing agent, dyeing temperature, dyeing time, concentration of NaOH, and the number of repetition of dyeing. The optimum conditions in the dyeing procedure are as follows: Added concentration of the reducing agent is 3g/${\ell}$. Reducing temperature is $60^{\circ}C$. Reducing time is 40minutes. Dyeing temperature is $30^{\circ}C$. Added concentration of NaOH is 1g/${\ell}$. Dyeing time is 30minutes.

• Journal of the Korea Institute of Building Construction
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• v.16 no.6
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• pp.561-569
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• 2016

Concrete is cheap, easy to deal with, and the quality is satisfactory. Also, it is one of the easiest materials to get because chemical composition of cement is similar to chemical composition of surface. On the other hand, it is so vulnerable to transform because of weak binding capacity and low binding energy that it produces cracks. Cracks decline durability, usability, safety of structures and damage exterior. In order to decline drying shrinkage crack, this study used shrinkage reducing typed Superplasticizer, which is combination of and water-reducing agent for convenience, different with existing study using AE agent, water-reducing agent, shrinkage reducing agent,. Considering SRS field application possibility, this study planned to mix concrete and mortar generally used in ready-mixed concrete company and did basic experiment depending on a change of SRS content ratio and admixture. Based on the experiment result. It is judged that SRS admixture 2% is proper ratio when Given the intensity and length change. Also mass combination will conduct follow-up studies.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.102-108
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• 2016

The purpose of this study is to examine the reduction effect of shrinkage reducing agent for drying shrinkage induced cracking and suggest the method of controlling the cracking in concrete box culvert for power transmission. Based on drying shrinkage cracking mechanism, it is necessary to perform the numerical analysis, which involves shrinkage reducing effect of shrinkage reducing agent. From the numerical results, it is found that cracking behavior for longitudinal direction and transverse direction due to differential drying shrinkage of box culvert can occur and the experimental observation of concrete cracks support the numerical predictions. The shrinkage reducing agent reduced the concrete cracking by 40~50%, which shows the methodology of controlling of drying shrinkage cracks in box culverts in real construction site.

• Journal of Powder Materials
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• v.27 no.3
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• pp.233-240
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• 2020

Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH₄) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.