• Title/Summary/Keyword: red-mud

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Flowing and Strength Properties of Ternary System Inorganic Composite According to the Change of W/B and Addition Ratio of Na2SiO3 (3성분계 무기결합재의 W/B 및 규산나트륨 첨가율 변화에 따른 유동 및 강도특성)

  • Bae, Sang-Woo;Moon, Ji-Hwan;Lee, Yun-Seong;Lee, Kang-Pil;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.49-50
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    • 2011
  • This study tried to utilize basic data for developing the cement substitute material through ternary system inorganic composite properties of flowing and strength. W/B and addition ratio of Na2SiO3 have been changed in ternary system inorganic composite combined blast furnace slag, red mud and fly ash. As to the experimental result inorganic composite, the flowing and intensity improvement effect was showed to be bigger than W/B according to the addition ratio change of the Na2SiO3. When particularly the Na2SiO3 addition ratio was 6%, the rapid flowing and strength improvement effect was confirmed.

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Hydrocarbon Synthesis of Waste Lignocellulosics by Liquefaction Reaction of Thermochemical Deoxyhdrogenolysis Method (II) (목질폐재(木質廢材)의 열(熱)-화학적(化學的) 탈(脫)산소-수소첨가반응(환원반응)에 의한 액화(液化)탄화수소의 합성 (II))

  • Lee, Byung-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.19 no.4
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    • pp.80-84
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    • 1991
  • Lignocellulosic biomass including acetosolv ricestraw and spruce lignin were liquefied and converted into liquid hydrocarbons by catalytic hydroliquefaction reaction. These experimental works were carried out in 1-liter-capacity autoclave using 50% tetralin and m-cresol solution respectively as soluble solvent and Ni. Pd. Fe and red mud as catalyst. $H_2$ gas was supplied into the reactor for escaltion of deoxhydroenolysis reaction. Catalyst concentrations were 1 % of raw material based on weight. The ratio between raw materials and soluble solvent are 1g and 10cc. The reaction conditions are 400-$700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure. The highest yield of hydrocarbon, so called "product oil" showed 32% and 5.5% of lowest char formation when red mud was used as catalyst. The product oil yields from those of other catalysts were in the range of 20-29%. The influence of different initial hydrogen pressures was examined in the range d 30-50 atms. A minimum pressure of 35 atms was necessary to obtain a complete recovery of souble solvent for recycling.

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A basic study for stabilization of heavy metal contaminated tailings by inorganic binders (무기고화제를 이용한 중금속 오염 광미의 안정화 처리를 위한 기초연구)

  • Min, Kyoung-Won;Kim, Tae-Poong;Lee, Hyun-Cheol;Seo, Eui-Young
    • Journal of Industrial Technology
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    • v.29 no.A
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    • pp.55-60
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    • 2009
  • Stabilization treatment is one of processes for wastes and their components to reduce their toxicity and migration rates to surroundings. Inorganic binders such as calcium hydroxide, blast furnace slag and red mud were tested for their potential applicability to in-situ stabilization of heavy metal contaminated tailings in the abandoned metal mines. Columns(150mm dia. ${\times}$ 450mm length) filled with mixtures of inorganic binders and tailing from the Geumjang mine with various mixing ratios of binders to tailings, 5%, 7% and 9% were applied artificial rainfall tests for 28 days. Effluents from columns filled with calcium hydroxide and tailing showed high pH's of ~12.5 and a increasing trend of concentration in Pb and Zn with a significant decrease in permeability in terms of elapsed days. Those with burning slag and tailing showed pH's of ~8.5 and significantly low concentrations in heavy metals with a stable permeability. In case of red mud, effluents showed significantly low concentrations in heavy metals but a decreased permeability with pH's of ~10.5. Conclusively, this basic study suggests burning furnace slag be a potential stabilizer for effective treatment of heavy metal contaminated mine tailings.

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The Effect on the Marine Water and Sediment Quality by the Use of Nano-S 1. Result of Water Tank Experiment (Nano-S가 해양수질 및 저질에 미치는 영향에 관한 연구 1. 실내수조실험 결과)

  • Cho, Hyeon-Seo;Cho, Chon-Rae;Jang, Young-Nam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.3
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    • pp.158-163
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    • 2005
  • The purpose of this study was to observe the effect on the marine environment by the use of Nano-S. Nano-S was made to apply to improve the red tide bloom. The experiment was performed at round tank with volume of 180 L. Each tank was filled with an aggravated sediment about $14{\pm}1cm$ hight and sea water. The water flow-rate of tank was established on the rate of 6.25 L/hr. Sea water level was fitted to 40 cm, therefore the filled water was about 150 L. The sediment was stabilized during one week. Then the Nano-S and the red mud were added into each tank 0 kg(control), 1 kg(tank A), 2 kg(tank B), 5 kg(tank C) and 10 kg(tank D) each other. The quantity was fulfilled with 0 kg(control), 2.75 kg(tank A), 5.51 kg(tank B), 13.77 kg(tank C) and 27.55 kg(tank D) per square meter of sediment. The experiment was performed during 30 days. Water and sediment samples were collected from each tanks on the before 1hour and after 1, 3, 6, 12 hour and 1st, 3th, 5th, 7th, 10th, 15th, 30th day of the experiment period. The change of water and sediment quality was analyzed before and after applying the Nano-S and the red mud.

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The Light Quality Dependence of Photoresponse of Mud Fish (Misgurunus mizolepis $G{\"{u}}nther$)and the Chromophores Photogenerating Active Oxygen in its Skin Tissues (미꾸라지 광반응의 광질 의존성과 피부조직의 내생 광증감제)

  • Boo, Yong-Chool;Jung, Jin
    • Korean Journal of Environmental Agriculture
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    • v.11 no.3
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    • pp.253-260
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    • 1992
  • A photoresponse that results in organisms dispersing from a region of bright light. generally termed photodispersal, is frequently observed in some fishes notably including mud fish (Misgurunus mizolepis G${\"{U}}$NTHER). The primary assumption for this study was that the photodispersion may result from the behavioral strategies of fishes aimed to avoid illumination conditions that could injure the cells in skin tissues via photodynamic sensitization reactions. Here we present some preliminary results that seem to support this assumption : (1) the locomotive action of dark-adapted mud fish was triggered by the onset of illumination with light : (2) blue light (400-500nm) was much more effective in bringing about the locomotive activity than yellow (550-650nm) and red (650-800nm) lights : (3) two blue light absorbing pigments, which photogenerate activated oxygen species, were separated from the skin tissues of mud fish, one of these being identified as riboflavin.

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Comparison of Removal Efficiency of Mn-loaded Natural Zeolites and Red Mud for the Catalytic Ozonation of 2-Butanone

  • Park, Youna;Lee, Jung Eun;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.328-334
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    • 2022
  • For the study of environmental application of natural zeolites (NZ) and red mud (RM), which are discharged from various industrial fields, the catalytic ozonation of 2-butaone (methyl ethyl ketone, MEK) was performed using the Mn-loaded NZ prepared according to the Mn content of 1, 3, 5, 7, and 10 wt%. By the addition of Mn to NZ, the BET (Brunaure-Emmett-Teller) specific surface area of Mn/NZ catalysts decreased while the ratio of Mn3+/[Mn3++Mn4+] intensively increased. Besides, the addition of Mn component to NZ increased the ratio of adsorbed oxygen (Oadsorbed) toward lattice oxygen (Olattice), Oadsorbed/Olattice from 0.076 of NZ to 0.465 of 10 wt% Mn/NZ according to the amount of Mn. It is known that the proportion of two species, Mn3+ and Oadsorbed, would greatly affect the catalytic activity. However, the balancing between the paired species, Mn3+ vs. Mn4+ and Oadsorbed vs. Olattice might be more essential for the catalytic ozonation of MEK at room temperature. Among the Mn-loaded NZ catalysts, the 3 wt% Mn/NZ showed the best activity for the removal of MEK and ozone. The 5, 7, and 10 wt% Mn/NZ catalysts are slightly inferior to the 3 wt% Mn/NZ. Compared to the pristine NZ, the Mn/NZ catalysts showed better activity for the catalytic ozonation of MEK. In addition, the 3 wt% Mn/NZ was confirmed to have the most available acid sites among them by the analysis of NH3-TPD (temperature programmed desorption). This might be the major reason for the best catalytic activity of 3 wt% Mn/NZ together with the adjusted distribution ratios of Mn3+/Mn4+ and Oadsorbed/Olattice. Considering the result of 3 wt% Mn/NZ, the 3 wt% Mn/RM was prepared to perform the catalytic activity for the removal of MEK and ozone, but the efficiency of 3 wt% Mn/RM was significantly lower than that of the 3 wt% Mn/NZ.

Properties of Alkali Activated Inorganic Binder using Replacement Materials Alkali Activator with Red Mud (알칼리 자극제 대체재로써 레드머드를 사용한 알칼리 활성 무기결합재의 특성)

  • Park, Sun-Gyu
    • Proceedings of the Korea Contents Association Conference
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    • 2014.11a
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    • pp.139-140
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    • 2014
  • 최근 건선산업에서 문제점으로 지적되고 있는 것은 제조과정 중 이산화탄소를 다량 방생시키는 시멘트의 사용이다. 이는 알칼리활성 무기결합재로 대체함으로써 시멘트보다 이산화탄소 배출량을 저감할 수 있지만 고가의 알칼리 자극제를 다량 사용하기 때문에 경제적 측면 및 사용성을 고려하지 않으면 사용할 수 없기 때문에 이에 대한 대체재에 관한 연구가 필요한 실정이다. 이에 본 연구에서는 고로슬래그를 기반으로 하는 알칼리 활성 무기결합재에 알칼리 자극제의 사용량을 저감하기 위해 레드머드를 사용하고, 레드머드에 적합한 알칼리 자극제의 종류와 사용방법에 대하여 연구하고자 하였다.

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Development of Multi-functional Ceramics for Removal of Heavy Metals in Acid Wastewater using Industrial By-product (산업부산물을 활용한 산성폐수 내 중금속 제거용 다기능성 세라믹 소재의 개발)

  • Kim, Dong-Hee;Yim, Soo-Bin
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.277-284
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    • 2012
  • This study developed a new ceramics in which natural zeolite was mixed and calcined with industrial by-product such as converter slag, red mud, and fly ash and evaluated the feasibility of the ceramics for removal of heavy metals in acid wastewater. The removal rate of heavy metal by ceramics increased in the order of ZS (zeolite and slag) > ZR (zeolite and red mud) > ZF (zeolite and fly ash) ceramics. The alkalinity increment and coherence of ceramics were increased in the order of ZS > ZR > ZF ceramics. The mixing ratio of natural zeolite to industrial by-product for maximum removal efficiency of heavy metal was 1:1 for ZS ceramics and 1:3 for ZR and ZF ceramics. The order of removal efficiency of heavy metal was observed to be ZS > ZR > ZF ceramics under the mixing ratio of 1:1 for ZS ceramics and 1:3 for ZR and ZF ceramics. The removal efficiency of heavy metal by ZS ceramics with 1:1 mixing ratio was Al 100%, Cd 54.6%, Cr 99.9%, Cu 98.7%, Fe 99.9%, Mn 42.2%, Ni 59.9%, Pb 99.8%, Zn 87.6%, respectively. In addition, the removal capacity of heavy metal by ZS ceramics was observed to be Al 2.01 mM/g, Cd 0.27 mM/g, Cr 1.02 mM/g, Cu 0.83 mM/g, Fe 0.95 mM/g, Mn 0.41 mM/g, Ni 0.55 mM/g, Pb 0.25 mM/g, Zn 0.70 mM/g, respectively. The comparative evaluation in the light of removal capacity, alkalinity increment, and coherence of ceramics showed the ZS ceramics had higher feasibility as a media than others for removal of heavy metals in acid wastewater.

Histological Studies on the Spleen of Mud Turtle (Amyda sinensis) (韓國産 자라(Amyda sinensis)의 脾臟組織에 關하여)

  • Chung, Ho Sam;Lee, Kyung Ro
    • The Korean Journal of Zoology
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    • v.18 no.3
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    • pp.127-130
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    • 1975
  • Histological studies on the spleen of mud turtle(Amyda sinensis) in Korea were made and the results obtained were as follows: 1. Smooth muscle cells are absent in the capsule of the spleen, although reticular, elastic and collagenous fibers are presnet as in the spleen of other mammals. 2. The trabeculs of the spleen tissue are more highly developed than those of frog and do not extend as deeply into the splenic pulp as the trabecula of mammals. 3. The structure of blood system in the spleen is found to be similar to that of mammals. Particularly, the central arteries of spleen are more highly developed, but the splenic sinus appears to be less developed than that of mammals. 4. The ratio of red pulp and white pulp in the splenic pulp appears to be 1. 5. More hemopoietic cells are seen in the spleen of turtle than in the spleen of mammals.

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MASS MORTALITYS OF OYSTER DUE TO RED TIDE IN JINHAE BAY IN 1978 (1978년 진해만 적조와 양식굴의 대량폐사)

  • CHO Chang Hwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.12 no.1
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    • pp.27-33
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    • 1979
  • In early August 1978, a huge red tide occurred off Chilcheon Is, , at the mouth of Jinhae Bay. It expanded rapidly into the central part and then soon covered all the bay except the innermost part of the bay. After staying for a week it disappeared, and thereafter several small scale red tides partially occurred and disappeared untill the end of August. It differed from the red tides hitherto recorded from this bay in respect of the dominant plankter, the geographical extent and the severe damaging effect to local oyster resources. During the red tide period, nevertheless, no oyster damage was found. In September, however, oyster mortailty was found from all rafts and longlines in the bay. Except the inner most part of the bay the oyster farms were completely destroyed. Of the oyster Production in the winter 1978, $96\%$ of an estimated yield of 5,879 tons (shucked meat) was lost and it was estimated to be 2,275 million won, equivalent to $US\$$ 4.55 million. The dominant species was a dinoflagellate, Ceratium fusus and it constituted about $45\%$ of the total phytoplankton. Cell count showed $7.0\times10^4\;cells/\iota$ and chlorophyll-a, $50mg/m^3$ during red tide peak. No oxygen was found ill the bottom waters in September. Sulphides in bottom waters and in the superficial mud increased to 15 and 8-fold respectively in September compared with July ana August. Precipitation from January to May of 1978 was about a third in comparison with the past ten years average but rainfall ill June was two and half-fold more than normal year, and thereafter drought persisited till September Air and water temperatures were also higher, and sunny days continued for a long time without strong winds. Therefore, water was calm for a long time after the red tide extinguished. The result indicated that the occurrence of the Ceratium red tide occurred in that year which was characterized by the combination of the formation of almost anoxic bottom water before the red tide occurrence, high air temperature and the calmness after a great quantity of rainfall in June. The mass mortality of oysters was presumed not to be directly related with the red tide but with the depression of dissolved oxygen in the environmental waters at the bottom due to settling of the red tide organisms.

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