Kim, Jung-Ho;Sung, Jong-Hyun;Kim, Choong-Gyum;Lee, Sea-Hyun;Kim, Han-Soo
Journal of the Korean Recycled Construction Resources Institute
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v.6
no.4
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pp.229-235
/
2018
In this study, recycled aggregate and natural aggregate were mixed in advance using an aggregate mixing facility that was developed to improve the quality of recycled aggregate concrete. Then the mixed aggregate was applied and concrete characteristics before and after a mix were considered. Based on the findings extracted, this study aimed to suggest a new direction for quality stabilization and application activation of recycled aggregate. The test results of change rates of mortars and coarse aggregates in fresh concrete mixed by a concrete mixer, before and after mixing aggregates showed that the variations of the mortars and coarse aggregates in the concrete mixed with the aggregates beforehand were decreased than those in the concrete before mixing them. The variation of compressive strength and the mean compressive strength at the ages of 3 and 7 days showed similar results before and after the aggregates were mixed, and the strength at the age of 28 days before and after mixing them showed larger deviation than that at the ages of 3 and 7 days. The use of the mixed aggregates after mixing aggregates beforehand reduced the variation in strength and is believed that it is advantageous for long-age strength development. The above results show that the variations of coarse aggregates and compressive strength in the concrete using the mixed aggregates produced by mixing recycled aggregates and natural aggregates beforehand are reduced so it will be possible to produce the homogeneous concrete by mixing aggregates beforehand.
As demand for electric vehicles increases, the market for lithium-ion batteries is also rapidly increasing. The battery life of lithium-ion batteries is limited, so waste lithium-ion batteries are inevitably generated. Accordingly, lithium was selectively preleached from waste lithium iron phosphate (LiFePO4, hereafter referred to as the LFP) cathode material powder among lithium ion batteries, and iron phosphate (FePO4) powder was recovered. The recovered iron phosphate powder was mixed with alkaline sodium carbonate (Na2CO3) powder and heat treated to confirm its crystalline phase. The heat treatment temperature was set as a variable, and then the leaching rate and powder characteristics of each ingredient were compared after water leaching using Di-water. In this study, lithium showed a leaching rate of approximately 100%, and in the case of powder heat-treated at 800 ℃, phosphorus was leached by approximately 99%, and the leaching residue was confirmed to be a single crystal phase of Fe2O3. Therefore, in this study, lithium, phosphorus, and iron components were individually separated and recovered from waste LFP powder.
In this study the nanofiltration (NF) membrane treatment of a nitric acid waste solutions containing $Pb^{+2}$ heavy metal ion discharging from the etching processes of an electronics and semiconductors industry has been studied for the purpose of recycling of nitric acid etching solutions. Three kinds of NF membranes (General Electric Co. Duraslick NF-4040 membrane, Dow Co. Filmtec LP-4040 membrane and Koch Co. SelRO MPS-34 4040 membrane) were tested for their separation efficiency (total rejection) of $Pb^{+2}$ ion and membrane stability in nitric acid solution. NF experiments were carried out with a dead-end membrane filtration laboratory system. The membrane permeate flux was increased with the increasing storage time in nitric acid solution and lowering pH of acid solution because of the enhancing of NF membrane damage by nitric acid. The membrane stability in nitric acid solution was more superior in the order of Filmtec LP-4040 < Duraslick NF-4040 < SelRO MPS-34 4040 membrane. The total rejection of Pb+2 ion was decreased with the increasing storage time in nitric acid solution and lowering the pH of acid solution. The total rejection of $Pb^{+2}$ ion after 4 months NF treatment was decreased from 95% initial value to 20% in the case of Duraslick NF-4040 membrane, from 85% initial value to 65% in the case of SelRO MPS-34 4040 membrane and from 90% initial value to 10% in the case of Filmtec LP-4040 membrane. These results showed that SelRO MPS-34 4040 NF membrane was more suitable for the treatment of an acidic etching waste solutions containing heavy metal ions.
Lee, Chang Hyung;Jung, In Kwon;Lee, Yong Moo;Oak, Sung Hyun;Choi, Hyeong Ki
Applied Chemistry for Engineering
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v.10
no.1
/
pp.118-123
/
1999
The recycle of the polycarbonate(PC)/acrylonitrile-butadiene-styrene(ABS) separated from the instrument panel (In-Panel) of the automotive was investigated. The small amount of polyurethane(PU) foam contained in the separated PC/ABS decreased the mechanical properties of the recycled PC/ABS. However, it is found that the PU foam formed the dispered phase of small particles at high temperature ($260^{\circ}C$) under high shear of the twin extruder, whereas it formed the big particles at low extrusion temperature ($220^{\circ}C$). The mechanical properties of the recycled PC/ABS extruded at high temperature was better than those at low temperature, which enabled the recycled PC/ABS seperated from In-Panel to be applied to the radiator grille without the addition of the compatibilizers or virgin PC/ABS. This was ascribed to the smaller particle sizes of the PU foam formed at high extrusion temperature under high shear.
Since late of 2000, KIER has developed a novel pyrolysis process for production of fuel oils from polymer wastes. It could have been possible due to large-scale funding of the Resource Recycling R&D Center. The target was to develop an uncatalyzed, continuous and automatic process producing oils that can be used as a fuel for small-scale industrial boilers. The process development has proceeded in three stages bench-scale unit, pilot plant and demonstration plant. As a result, the demonstration plant having capacity of 3,000 tons/year has been constructed and is currently under test operation for optimization of operation conditions. The process consisted of four parts ; feeding system, cracking reactor, refining system and others. Raw materials were pretreated via shredding and classifying to remove minerals, water, etc. There were 3 kind of products, oils(80%), gas(15%), carbonic residue(5%). The main products i.e. oils were gasoline and diesel. The calorific value of gas has been found to be about 18,000kcal/$m^3$ which is similar to petroleum gas and shows that it could be used as a process fuel. Key technologies adopted in the process are 1) Recirculation of feed for rapid melting and enhancement of fluidity for automatic control of system, 2) Tubular reactor specially-designed for heavy heat flux and prevention of coking, 3)Recirculation of heavy fraction for prevention of wax formation, and 4) continuous removal & re-reaction of sludge for high yield of main product (oil) and minimization of residue. The advantages of the process are full automation, continuous operation, no requirement of catalyst, minimization of coking and sludge problems, maximizing the product(fuel oil) yield and purity, low initial investment and operation costs and environment- friendly process. In this presentation, background of pyrolysis technology development, the details of KIER pyrolysis process flow, key technologies and the performances of the process will be discussed in detail.
Journal of the Korean Institute of Landscape Architecture
/
v.34
no.2
s.115
/
pp.113-127
/
2006
As the local self-government are stabilized and the environmental value is becoming more important among local residents, the occurrence of the anti-movements against waste treatment facilities is getting more frequent. Opposing to build the reuse facilities of wastes takes place because of concerning of health and hygiene, as well as matters of unclear policy making process. However, these facilities must be built in somewhere for the convenience and profit of the public. The NIMBY phenomenon against reuse facilities of wastes could be a burden for the city operation system, and it could worsen citizens' quality of life in the long run. In these lights, reuse and recycling facilities of wastes in East region are necessary facilities improving citizens' quality of life and enhancing the growth of cities in the region. However, there have been concerning of deforestation during the construction process of the facilities. The landscape design presented here for these facilities considers the features of the environmental ecosystem and tries to establish a plan to preserve the natural environment of the City of Ichon. This paper presents methods minimizing adverse effects of the facilities on the existing environments and promoting the city image with integrating culture, tourism, landscape and environment of the city. The landscape design makes efforts to harmonize natural environments in the site, human activities and culture. Well-being park was aimed to lead healthy and energetic outdoor activities of local residents. Ecological park was aimed to enhance the ecological functions of the forests and restore the valley ecology. Culture park was aimed to capture the city identity by creating a place that contains all the variety of meanings of the City of Ichon.
Kim, Sun-Lim;Chi, Hee-Youn;Kim, Jung-Tae;Hur, On-Sook;Kim, Deog-Su;Suh, Sae-Jung;Kim, Hyun-Bok;Cheong, Ill-Min
KOREAN JOURNAL OF CROP SCIENCE
/
v.56
no.4
/
pp.349-360
/
2011
The objectives of present study were to characterize the peptides which were isolated from Korean fermented soybean paste, chungkukjang, and to determine their antioxidant activities. Four fractions were collected from the methanol extract of chungkukjang by using a recycling preparative HPLC. Among fractions, Fr-2 was identified to be highly potent free radical scavenging activity in the assay of 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and nitroblue tetrazolium(NBT)-reduction inhibition. Base on antioxidant effects, fraction Fr-2 was employed for the refraction with a prep-column and separated into five fractions of which two fractions were identified to have higher antioxidant activity. To confirm the amino acid constituents of antioxidant fractions Fr-2-2 and Fr-2-3 were analyzed, and eight kinds of amino acids such as aspartic acid, threonine, serine, glutamic acid, glycine, lysine, histidine, and arginine were identified as the constituent amino acids. Antioxidant activities of the separated peptides were further assessed cell viability with 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl terazolium bromide (MTT), and fluorescence-activated cell sorting (FACS) analysis of H4IIE cells treated with hydrogen peroxide (H2O2). Chungkukjang peptides have shown their ability to protect H4IIE rat hepatoma cells against H2O2- induced oxidative stress by concentration and time-dependent manner. Therefore, These results indicated that fermented soybean paste chungkukjang will be promoted the antioxidant and radical scavenging activities, and beneficial for health. The antioxidant peptide fractions Fr-2-2 and Fr-2-3 were denominated as P-NICS-1 and P-NICS-2, respectively. However, further studies were required to clarify their amino acid sequences and molecular properties, and physiological significances.
Sheng, Silu;Jia, Han;Topiol, Sidney;Farinas, Edgardo T.
Journal of Microbiology and Biotechnology
/
v.27
no.3
/
pp.507-513
/
2017
Bacillus subtilis spores can be used for protein display to engineer protein properties. This method overcomes viability and protein-folding concerns associated with traditional protein display methods. Spores remain viable under extreme conditions and the genotype/phenotype connection remains intact. In addition, the natural sporulation process eliminates protein-folding concerns that are coupled to the target protein traveling through cell membranes. Furthermore, ATP-dependent chaperones are present to assist in protein folding. CotA was optimized as a whole-cell biocatalyst immobilized in an inert matrix of the spore. In general, proteins that are immobilized have advantages in biocatalysis. For example, the protein can be easily removed from the reaction and it is more stable. The aim is to improve the pH stability using spore display. The maximum activity of CotA is between pH 4 and 5 for the substrate ABTS (ABTS = diammonium 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate). However, the activity dramatically decreases at pH 4. The activity is not significantly altered at pH 5. A library of approximately 3,000 clones was screened. A E498G variant was identified to have a half-life of inactivation ($t_{1/2}$) at pH 4 that was 24.8 times greater compared with wt-CotA. In a previous investigation, a CotA library was screened for organic solvent resistance and a T480A mutant was found. Consequently, T480A/E498G-CotA was constructed and the $t_{1/2}$ was 62.1 times greater than wt-CotA. Finally, E498G-CotA and T480A/E498G-CotA yielded 3.7- and 5.3-fold more product than did wt-CotA after recycling the biocatalyst seven times over 42 h.
Park, Jongsung;Lim, Cheolhyun;Kim, Wooram;Park, Byungwook;Lee, Jin-seok;Lee, Sukho
Current Photovoltaic Research
/
v.8
no.1
/
pp.39-43
/
2020
In this study, we predict the generation of end-of-life photovoltaic modules when Feed in Tariff applied, in Republic of Korea. Based on the installation of photovoltaic modules, we prepared three different senarios in order to estimate the generation of end-of-life photovoltaic modules. The senarios are i) early worn-out, ii) mid worn-out and iii) late-worn out senario. We selected the mid worn-out senario to estimated the amount of end-of-life photovoltaic modules in this study. Establishment of the end-of-life module generation scenario predicted generation of end-of-life photovoltaic module, and forecasted generation amount of end-of-life module to which Feed in Tariff was applied in consideration of installed photovoltaic modules installed by Feed in Tariff support. The generation of Feed in Tariff-applied end-of-life modules increased from 2021 to 2025 compared to without Feed in Tariff, and since then, the Feed in Tariff-applied end-of-life modules were generated as waste modules during the relevant period (2021 ~ 2025).
Transactions of the Korean hydrogen and new energy society
/
v.22
no.2
/
pp.152-160
/
2011
The electromagnetic characteristics of FCEVs (fuel cell electric vehicles) are much different from the existing combustion engine cars as well as hybrid, plug-in-hybrid, and pure electric vehicles due to the high voltage/current generated by a fuel cell stack which uses a compressed hydrogen gas reacted with oxygen. To operate fuel cell stack efficiently, BOP (Balance of Plant) which is consisted of many motors in water pump, air blower, and hydrogen recycling pump as well as inverters for these motors is essential. Furthermore, there are also electric systems for entertainment, information, and vehicle control such as navigation, broadcasting, vehicle dynamic control systems, and so on. Since these systems are connected by high voltage or general cables, EMC (Electromagnetic compatibility) analysis for high voltage and general cable of FCEV is the most important element to prevent the possible electric functional safety errors. In this paper, electromagnetic fields by high voltage and general cables for FCEVs is studied. From numerical analysis results, total time harmonic electromagnetic field strength from high voltage and general cables have difference of 13~16 dB due to ground effect by impedance matching. The EMI results of FECV at 10 m distance shows difference of 41 dB at 30 MHz and 54 dB at 230 MHz compared with only general cable routing.
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