• Title/Summary/Keyword: recycle$CO_2$

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100 kW급 용융탄산염 연료전지 발전시스템 개발

  • Im, Hui-Cheon;Kim, Do-Hyeong;Seo, Hye-Gyeong;Park, Seong-Yeon;An, Gyo-Sang
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.140-148
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    • 2005
  • The molten carbonate fuel cell (MCFC) is endowed with the high potential especially in future electric power generation industry by its own outstanding characteristics. KEPCO (KEPRI) started a 100 kW MCFC system development program in 1993 and has been executed 100kW system develpilot plant successfully completed first phaseopment by 2005 on the basis of successful results of 25kW system development. In this program, the components and mechanical structure for 100 kW stack and system construction were completed on last year and now system pre - commissioning was being executed. A 100 kW MCFC power plant was constructed at the site of Boryeong Thermal Power Plant. A 100 kW MCFC system has characterized as a high pressure operation mode, CO2 recycle, and externally reforming power generation system. The 100 kW MCFC system consisted with stacks which was made by two 50 kW sub-stacks, 90 cells with 6,000 cm2 active area and BOP including a reformer, a recycle blower, a catalytic burner, an inverter, and etc. The system has been operated from 13th of September on this year and produced 50 kW AC under atmospheric pressure condition and expected to operate by the end of this year.

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System Development of a 100 kW Molten Carbonate Fuel Cell IV(System commisioning for operation (100 kW급 용융탄산염 연료전지 시스템 개발 IV(MCFC 시스템 시운전))

  • Lim, Hee-Chun;Ahn, Kyo-Sang
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1681-1683
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    • 2005
  • The molten carbonate fuel tell(MCFC) is endowed with the high potential especially in future electric power generation industry by its own outstanding characteristics. KEPCO(KEPRI) started a 100 kW MCFC system development program in 1993 and has been executed 100kW system develpilot plant successfully completed first phaseopment by 2005 on the basis of successful results of 25kW system development. In this program, the components and mechanical structure for 100 kW stack and system construction were completed on last year and now system pre-commissioning was being executed. A 100 kW MCFC power plant was constructed at the site of Boryeong Thermal Power Plant. A 100 kW MCFC system has characterized as a high pressure operation mode, $CO_2$ recycle, and externally reforming power generation system. The 100 kW MCFC system consisted with stacks which was made by two 50 kW sub-stacks, 90 cells with 6,000 cm2 active area and BOP including a reformer, a recycle blower, a catalytic burner, an inverter, and etc. The system will be operated under 3 atm pressure condition and expected to last over 5,000 hours by the end of this year.

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A Study on the Clearance Level(draft) for the Steel Scrap from the KRR-1 & 2 Decommissioning (연구로 1,2호기 해체 철재폐기물의 규제해제농도기준(안) 도출을 위한 연구)

  • 홍상범;이봉재;정운수
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.1
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    • pp.60-67
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    • 2004
  • The exposure dose form recycling of a large amount of the steel scrap from the KRR-1&2 decommissioning activities was evaluated, and also the clearance level(draft) was derived. The maximum individual dose and collective dose were evaluated by modifying internal dose conversion factor which was based on the concept of effective dose in ICRP 60, applied to the RESRAD-RECYCLE ver 3.06 computing code, IAEA Safety Series 111-P-1.1 and NUREG-1640 as the assessment tool. The result of assessment for individual dose and collective dose is 23.9 $\mu$Sv per year and 0.11 man$.$Sv per year respectively. The clearance levels were ultimately determined by extracting the most conservative value form the results of the generic assessment and specific assessment methodologies. The result of clearance level for radionuclides( $Co^{60}$ , C $s^{l37}$) is less than 1.14${\times}$10$^{-1}$ Bq/g to comply with the clearance criterion(maximum individual dose : 10 $\mu$Sv per year, collective dose : 1 man$.$Sv per year) provided for Korea Atomic Energy Act and relevant regulations.s.

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A Study on Prevention of Fouling Formation by Reduction Reaction of CaSO4 in a Biomass Circulating Fluidized Bed Combustion (바이오매스 순환유동층 연소에서 CaSO4 환원반응에 의한 파울링 발생 방지 연구)

  • Seong-Ju Kim;Sung-Jin Park;Sung-Ho Jo;Se-Hwa Hong;Yong-Il Mun;Tae-Young Mun
    • New & Renewable Energy
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    • v.19 no.1
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    • pp.1-11
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    • 2023
  • A large amount of carbon monoxide (CO) is generated in circulating fluidized bed combustion, the process whereby a hot cyclone separates unburned fuel. However, calcium sulfate (CaSO4), when combined with a high CO content, can cause fouling on the surface of the steam tube installed inside the integrated recycle heat exchangers (INTREX). In this study, CaSO4 decomposition was investigated using 0.2-3.2 vol.% CO and 1-3 vol.% oxygen (O2) at 850℃ for 20 min in a lab-scale fluidized bed reactor. The results show that CaSO4 decomposes into CaS and CaO when CO gas is supplied, and SO2 emissions increase from 135 ppm to 1021 ppm with increasing CO concentration. However, the O2 supply delayed SO2 emissions because the reaction between CO and O2 is faster than that of CaSO4; nevertheless, when supplied with CaCO3, the intermediate product, SO2 was significantly released, regardless of the CO and O2 supply. In addition, agglomerated solids and yellow sulfur power were observed after solid recovery, and the reactor distributor was corroded. Consequently, a sufficient O2 supply is important and can prevent fouling formation on the INTREX surface by suppressing CaSO4 degradation.

A Study on the Clarance Level for the Metal Waste from the KRR-1 & 2 Decommissioning (연구로 1,2호기 해체 금속폐기물의 규제해제농도기준(안) 도출을 위한 연구)

  • 홍상범;이봉재;정운수
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.660-664
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    • 2003
  • The exposure dose form recycling on a large amount of the steel scrap from the KRR-1&2 decommissioning activities was evaluated, and also the clearance level was derived. The maximum individual dose and collective dose were evaluated by modifying internal dose conversion factor which was based on the concept of effective dose in ICRP 60, applied to the RESRAD-RECYCLE ver 3.06 computing code, IAEA Safety Series III-P-1.1 and NUREG-1640 as the assessment tool. The result of assessment for individual dose and collective dose is 23.9 ${\mu}Sv$ per year and 0.11 man$\cdot$Sv per year respectively. The clearance levels were ultimately determined by extracting the most conservative value form the results of the generic assessment and specific assessment methodologies. The result of clearance level for radionuclides($Co^60$, $Cs^137$) is less than $1.67{\times}10^{-1}$ Bq/g to comply with the clearance criterion(maximum individual dose : 10 $\muSv$ per year, collective dose : 1 man$\cdot$Sv per year) provided for Korea Atomic Energy Act and relevant regulations.

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CO2 Emissions Reduction by Utilization of Recycled Cement (재생시멘트 활용에 따른 CO2배출량 저감효과)

  • Kwon, Eun-Hee;Ahn, Jae-Cheol;Hwang, Jong-Wook;Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.78-79
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    • 2013
  • A policy for recycling waste concrete has been extensively studied, but it is still lacking to recycle and reuse as a cementitious powder, and the property has big different depending on the aggregate rates. In this study, the amount of cement powder according to the internal properties of the aggregate were mixed. From as a result, Concrete Powder to play inside the aggregate composition of the cement composition CaO rigs that causes loss of power and strength reduction due to rising real water cement ratio will affect large.

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A Comparative Experiment on the Emission Gas Characteristics of Domestic RDF (국내산(國內産) RDF의 배출(排出)가스 특성(特性) 비교실험(比較實驗))

  • Park, Myung-Ho
    • Resources Recycling
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    • v.16 no.6
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    • pp.46-51
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    • 2007
  • This study aimed at developing high-efficiency RDF(refuse derived fuels) fuel in order to use RDF energy rationally and to recycle industrial product. As most studies in this area are concentrated in large combustion apparatuses such as kilns, but this study was focused on the small-sized heating systems, applying them directly to grate type boiler which has a heating capacity of $66{\sim}132m^2$. The different kinds of fuel are experimented including RDF. Coke and Waste Tire. First, for this, we experimented and analyzed RDF to see the change in its mass and heating value. Also, four kinds of exhaust gas are sampled by gas analyzer including CO, $CO_2$, NO and $NO_2$ at different temperature. As a result, the levels of CO concentration of RDF are higher than these of coke and waste tire. But, the levels of NO, $CO_2$ and $SO_2$ concentration of RDF and coke were lower then the levels when waste tire is burned.

Removal of Cs+, Sr2+, and Co2+ Ions from the Mixture of Organics and Suspended Solids Aqueous Solutions by Zeolites

  • Fang, Xiang-Hong;Fang, Fang;Lu, Chun-Hai;Zheng, Lei
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.556-561
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    • 2017
  • Serving as an excellent adsorbent and inorganic ion exchanger in the water purification field, zeolite 4A has in this work presented a strong capability for purifying radioactive waste, such as $Sr^{2+}$, $Cs^+$, and $Co^{2+}$ in water. During the processes of decontamination and decommissioning of suspended solids and organics in low-level radioactive wastewater, the purification performance of zeolite 4A has been studied. Under ambient temperature and neutral condition, zeolite 4A absorbed simulated radionuclides such as $Sr^{2+}$, $Cs^+$, and $Co^{2+}$ with an absorption rate of almost 90%. Additionally, in alkaline condition, the adsorption percentage even approached 98.7%. After conducting research on suspended solids and organics of zeolite 4A for the treatment of radionuclides, it was found that the suspended clay was conducive to absorption, whereas the absorption of organics in solution was determined by the species of radionuclides and organics. Therefore, zeolite 4A has considerable potential in the treatment of radioactive wastewater.

Operation Characteristics of Refuse Derived Fuel Gasifier with Syngas Recycle (고형연료 가스화에 의해 생산된 합성가스의 재순환에 따른 가스화기 운전 특성)

  • Lee, Do-Yeon;Gu, Jea-Hoi;Jung, Woo-Hyun;Park, Jong-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.825-828
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    • 2009
  • 고형원료인 폐기물의 감량화 및 자원화 기술 중 가장 대표적인 기술로 폐기물의 소각(incineration)기술과 가스화(gasification)용융기술을 들 수 있다. 폐기물 가스화 기술은 폐기물 내의 탄소, 수소 성분을 가스화하여 CO, $H_2$가 주성분인 합성가스(synthesis gas, syngas)로 전환하여 불연물은 용융되어 환경적으로 무해한 슬래그로 회수하는 기술이다. 폐기물 가스화 용융 시스템으로 발생된 합성가스를 재순환하여 사용하는 합성가스 재순환시스템을 통해 가스화에 필요한 열을 시스템 내에서 대체하여 사용하는 기술개발은 폐기물 가스화 용융기술의 경제성을 높일 수 있다. 본 연구에서는 고형 폐기물 가스화반응에 의해 발생되는 합성가스를 재순환하여 폐기물 가스화 용융 시스템내의 자체 에너지원으로 활용할 수 있도록 하는 합성가스 재순환 시스템 및 버너의 운전특성을 고찰하였다. 합성가스의 재순환 장치에서의 운전 압력 제어 및 유량제어를 통해서 안정적인 합성가스 재순환 성능과 재순환버너의 연소 성능을 유지할 수 있었다. 합성가스 재순환버너에 의한 16,800 $kcal/Nm^3$ 조건 및 33,600 $kcal/Nm^3$ 조건에서 운전시에도 가스화기의 운전온도는 안정적으로 유지됨에 따라 생산된 합성가스의 가스화기 보조연료 대체 및 에너지절감이 가능한 것으로 판단된다.

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Improvement of the Cooling Radiator System for Vehicles (차량용 라디에이터의 성능향상에 관한 연구)

  • Lee, Chang-Kyoo;Lee, Sang-Woo;Huh, Yun-Kun
    • Korean Journal of Agricultural Science
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    • v.33 no.2
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    • pp.107-114
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    • 2006
  • An all-aluminum radiator made of aluminum was more excellent on environment friendliness, productivity, and cooling efficiency than the plastic tank radiator which was currently widely used in same size as above. A newly designed and manufactured radiator with all parts made of aluminium was ready to re-use without any disassembly process in recycle system so as to improve environment friendliness with low waste cost. Several manufacturing processes of the current plastic tank radiator such as O-ring inserting, and clinching of core to the tank, were eliminated on the manufacturing processes of the all-aluminium radiator, which would increase productivity and reduce production cost. Design criterion of all-aluminum radiator was presented by carrying out theoretical analysis of cooling capacity and there was no difference between analytical data and measurements. Cooling capacity of the all-aluminum radiator increased generally 13% up compared with the plastic radiator even though the pressure drop of air increased.

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