• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.483-486
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• 2008

본 연구에서는 디스크 이동식 열분해 실증 설비를 이용하여 폐타이어 열분해 반응을 수행하였고, 생성된 열분해 생성물들의 특성을 분석하였다. 폐타이어 열분해 반응은 약 $550^{\circ}C$에서 90분간 진행되었고, 반응 결과 Recovered Oil, Carbon Black, Non Condensing Gas(NC Gas)가 생성되었다. 폐타이어 열분해 생성물의 수율은 Recovered Oil $40{\sim}50%$, Carbon Black 30$\sim$35%, NC Gas 10$\sim$15%, Steel 10$\sim$15%로 나타났다. 폐타이어 열분해 반응 후 생성된 Recovered Oil은 비점 및 특성 분석 결과 상업용 중유와 비슷한 성질을 나타냈고, 폐타이어 열분해 반응의 또 다른 생성물인 Carbon Black은 특성 분석 결과 고정 탄소 비율이 낮은 반면 회분과 휘발분의 비율이 높아 상업용으로 사용하기 위해서는 적절한 정제 과정이 필요함을 알 수 있었다.열분해 과정 중에 생성된NC Gas는 GC/MS를 이용하여 성분 분석을 수행한 결과, $CO_2$, $CH_4$를 비롯하여 주로 탄화수소류로 이루어졌으며, 대부분이 연료 가스로 구성되어 있어 열분해 반응의 열원으로서 사용이 가능하였다.

• Advances in materials Research
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• 제13권3호
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• pp.221-232
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• 2024

Waste tire management and recycling have grown to be significant issues because they bring up a global environmental concern. Thus, turning recycled waste tires into useful products may help tackle the environmental issue. This research aims to study and compare the effect of recycled carbon black (rCB) and commercial carbon black (CB) at certain 15 vol. % of filler loading on the mechanical, thermal, morphology and electrical properties of epoxy/CB composites. For this project, epoxy resin, diethyltoluenediamine (DETDA), recovered carbon black (rCB) and commercial carbon black (CB) graded N330, N550, N660 and N774 were mixed and compared accordingly to the formulation determined. The CB content was dispersed in the epoxy matrix using the mechanical mixing technique. The distribution and dispersion of CB in the epoxy matrix affect the characteristics of the conductive composites. rCB content at 15 vol% was selected at fixed content for comparison purposes due to the optimum value in electrical conductivity results. The flexural strength results followed the sequence of rCB>N774>N660>N550>N330. As for electrical conductivity results, epoxy/N330 exhibited the highest conductivity value, while the others achieved a magnitude of X10^-3 due to the highest external surface area of N330. In terms of thermal stability, epoxy/N330 and epoxy/N774 were slightly more stable than epoxy/rCB.

• Geomechanics and Engineering
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• 제23권1호
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• pp.31-38
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• 2020

Soil-cement stabilization is a type of ground improvement method which has been used to improve the engineering properties of soil. The unconfined compression test is the commonly used method to evaluate the quality of the stabilized soil due to its simplicity, reliability, rapidity and cost-effectiveness. The main objective of this study was to evaluate the effect of recovered carbon black (rCB) on the strength characteristic of cement-stabilized sand. Various rCB contents and water to cement ratios (w/c) were examined. The unconfined compression test on stabilized sand with different curing times was also conducted for a reconstituted specimen. From the test result, it was found that the compressive strength of cement-stabilized sand increased with the increase of the rCB content up to 3% and the curing time and with the decrease of the w/c ratio, showing that the optimum rCB concentration of the tested stabilized sand was around 3%. In addition, a prediction equation was suggested in this study for cement-stabilized sand with rCB as a function of the w/c ratio and rCB concentration at 14 and 28 days of curing.

• Elastomers and Composites
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• 제40권2호
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• pp.112-118
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• 2005

실란 커플링제가 카본블랙과 점토로 보강된 천연 고무 가황물의 회복 특성에 미치는 영향에 대해 연구하였다. Bis-(3-(triethoxysilyl)-propyl)-tetrasulfide (TESPT)를 실란 커플링제로 사용하였다. 실란 커플링제가 함유된 가황물은 실란 커플링제가 함유되지 않은 가황물에 비해 전반적으로 빠른 회복 거동을 보였다. 그러나, 점토 함량이 높은 가황물의 경우 $-20^{\circ}C$보다 낮은 온도에서는 실란 커플링제가 함유된 가황물이 실란 커플링제가 함유되지 않은 가황물에 비해 느리게 회복되었다. 실란 커플링제가 함유된 가황물과 실란 커플링제가 함유되지 않은 가황물의 회복량 차이는 점토 함량이 증가할수록 감소하였다. 실험 결과는 가교 밀도, 모둘러스, 그리고 결합 고무량으로 설명하였다.

• Geomechanics and Engineering
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• 제33권3호
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• pp.261-269
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• 2023

In this study, the compressive strength of cement stabilized soil was predicted using the electrical resistivity measurement. The effects of the water to cement (w/c) ratio and recovered Carbon Black (rCB) contents were examined. A series of electrical resistivity and compressive strength tests were conducted on two types of stabilized soil after 28 days of curing. Multiple nonlinear regression (MNLR) analysis was used to evaluate the relationship between the compressive strength and the electrical resistivity in terms of the rCB, C_u (uniformity coefficient), and w/c ratio. The results showed that the w/c ratio and C_u have a strong influence on the compressive strength and electrical resistivity of the cement stabilized soil compared to the rCB content. The use of a small amount of rCB led to a decrease in the void space in the specimen and was attributed to the increase strength and decrease electrical resistivity. A high w/c ratio also induced a low electrical resistivity and compressive strength, whereas 3% rCB in the cemented soil provided the optimum strength for all w/c ratios. Finally, a prediction equation for the compressive strength using the electrical resistivity measurement was suggested based on its reliability, time effectiveness, non-destructiveness, and cost-effectiveness.

• 자원리싸이클링
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• 제31권5호
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• pp.52-58
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• 2022

태양광 폐실리콘 웨이퍼에서 회수한 실리콘과 카본블랙을 활용하여 탄화규소 분말을 제조하였다. 태양광 발전시장에서 결정질 실리콘 모듈이 90% 이상을 차지한다. 태양광 모듈의 사용기한이 도래함에 따라 환경과 경제적인 측면에서 실리콘을 회수하고 활용하는 기술은 매우 중요하다. 본 연구에서는 태양광 폐패널에서 회수한 실리콘을 탄화규소 원료로 활용하기 위하여, 순도 95.74% 폐실리콘 웨이퍼로부터 정제과정을 거쳐 99.99% 실리콘 분말을 회수하였다. 탄화규소 분말 합성특성을 살펴보기 위하여, 정제된 99.99% 실리콘 분말과 탄소분말을 혼합한 후, Ar 분위기에서 열처리(1,300℃, 1,400℃, 1,500℃)과정을 수행하였다. 실리콘과 탄화규소 분말의 특성을 입도분포, XRD, SEM, ICP, FT-IR 및 Raman 분석기를 사용하여 분석하였다.

• 한국수소및신에너지학회논문집
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• 제13권2호
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• pp.101-109
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• 2002

This work was focused on the thermal decomposition of methane into hydrogen and carbon black without emitting carbon dioxide. Extensive experimental investigation on the thermal decomposition of methane has been carried out using a continuous flow reaction system with tubular reactor. The experiments were conducted at the atmospheric pressure condition in the wide range of temperature ($950-1150^{\circ}C$) and flow rate (250 - 1500 ml/min) in order to study their dependency on hydrogen yield. During the experiments the carbon black was successfully recovered as an useful product. Undesirable pyrocarbon was also formed as solid film, which was deposited on the inside surface of tubular reactor. The film of pyrocarbon in the reactor wall became thicker and thicker, finally blocking the reactor. The design of an efficient reactor which can effectively suppress the formation of pyrocarbon was thought to be one of the most important subjects in the thermal cracking of methane.

• 자원리싸이클링
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• 제19권5호
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• pp.44-49
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• 2010

태양전지산업으로부터 배출되는 Si waste로부터 탄소환원법을 사용하여 SiC 분말을 제조하였다. 태양광 산업의 실리콘 웨이퍼 가공 공정에서 다량의 실리콘 및 오일 포함된 폐액이 발생한다. 환경과 경제적인 측면에서 폐액으로부터 실리콘 성분을 재회수하는 기술의 개발은 매우 중요하다. 본 연구에서는 폐 실리콘를 milling하여 나노화한 후 카본 블랙과 혼합하고 진공분위기에서 $1,350^{\circ}C$로 열처리하여 100 nm크기의 균일한 입도를 갖는 SiC 분말을 제조하였다. 폐실리콘과 생성물의 물리적 특성을 SEM, XRD, 입도분석 그리고 원자 흡수 분광기를 사용하여 분석하였다.

• 한국수소및신에너지학회논문집
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• 제31권5호
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• pp.453-458
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• 2020

In this study, ethylene-propylene-diene monomer (EPDM) rubbers reinforced with various particle size of carbon black were prepared and tested. We followed recently published CSA/ANSI CHMC2 standard "the test methods for evaluating material compatibility in compressed hydrogen applications-polyemr". Measurement of change in hardness, tensile strength and volume were performed after exposure to maximum operating pressure, 87.5 MPa, for 168 hours (1 week). Once EPDM was exposed to high-pressure hydrogen, the samples experience volume increase and degradation of the physical properties. Also, after the dissolved hydrogen was fully eliminated from the specimens, the hardness and the tensile properties were not recovered. The rubber reinforced with smaller sizes of carbon black particles showed less volume expansion and decrease of physical properties. As a result, smaller particle size of carbon black filler led to more resistance to high-pressure hydrogen.

• 자원리싸이클링
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• 제30권5호
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• pp.49-56
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• 2021

본 연구에서는 Black Ash법을 이용하여 홍천 자철광으로부터 회수된 황산스트론튬 (SrSO₄)으로부터 탄산스트론튬 (SrCO₃)을 제조하였다. Carbothermic 반응 단계에서는 황화스트론튬 (SrS)을 제조하기 위해 1273 K의 Ar 가스 분위기의 석영반응기를 사용하여 SrSO₄를 탄소와 같이 반응시켰다. 이후 353 K에서 carbothermic 반응으로 회수된 잔사의 수침출 및 298 K에서 탄산나트륨 (Na₂CO₃)를 이용한 침출액의 탄산화 반응을 통해 SrCO₃을 제조하였다. 본 연구결과로부터 Black Ash법 활용 시 국내산 자철광 내 함유된 스트론튬 (Sr)으로 부터 고순도 탄산스트론튬 제조가 가능함을 실험적으로 증명하였다.