• Membrane and Water Treatment
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• 제13권4호
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• pp.201-208
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• 2022

Emulsion Liquid Membrane (ELM) is a prominent technique for the separation of heavy metal ions from wastewater due to the fast extraction and is a single-stage operation of stripping-extraction. The selection of the components (Surfactant and Carrier) of ELM is a very significant step for its preparation. In the ELM technique, the primary water- in-oil (W/O) emulsion is emulsified in water to produce water-in-oil-in-water (W/O/W) emulsion. The water in oil emulsion was prepared by mixing the membrane phase and internal phase. To prepare the membrane phase, the extractant D2EHPA (di-2-ethylhexylphosphoric acid) was used as a mobile carrier, Span-80 as a surfactant, and Paraffin as a diluent. Moreover, the internal (receiving) phase was prepared by dissolving sulphuric acid in water. Di-(2- ethylhexyl) phosphoric acid such as surfactant concentration, carrier concentration, sulphuric acid concentration in the receiving (internal) phase, agitation time (emulsion phase and feed phase), the volume ratio of the membrane phase to the receiving phase, the volume ratio of the external feed phase to the primary water-in-oil emulsion and pH of feed were studied on the percentage extraction of metal ions at 20℃. The results show that it is possible to remove 78% for As(V), 98% for Cd(II), and 99% for Pb(II). Emulsion Liquid Membrane (ELM) is a well-known technique for separating heavy metal ions from wastewater due to the fast extraction and is a single-stage operation of stripping-extraction. The selection of ELM components (Surfactant and Carrier) is a very significant step in its preparation. In the ELM technique, the primary water-in-oil (W/O) emulsion is emulsified to produce water-in-oil-in-water (W/O/W) emulsion. The water in the oil emulsion was prepared by mixing the membrane and internal phases. The extractant D2EHPA (di-2-ethylhexylphosphoric acid) was used as a mobile carrier, Span-80 as a surfactant, and Paraffin as a diluent. Moreover, the internal (receiving) phase was prepared by dissolving sulphuric acid in water. Di-(2-ethylhexyl) phosphoric acid such as surfactant concentration, carrier concentration, sulphuric acid concentration in the receiving (internal) phase, agitation time (emulsion phase and feed phase), the volume ratio of the membrane phase to the receiving phase, the volume ratio of the external feed phase to the primary water-in-oil emulsion and pH of feed were studied on the percentage extraction of metal ions at 20℃. The results show that it is possible to remove 78% for As(V), 98% for Cd(II), and 99% for Pb(II).

• Membrane and Water Treatment
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• 제3권4호
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• pp.243-252
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• 2012

Tri-n-butyl phosphate (TBP) was used as carrier for the transport of Golden yellow and Cibacron LSG dyes through a hexane bulk liquid membrane. The transport efficiency of dyes by TBP was investigated under various experimental conditions such as pH of the feed phase (dyes solution), concentration of the receiving phase (NaOH solution), concentration of TBP in membrane, rate of stirring, effect of transport time, type of solvent, dye concentration in feed phase, effect of temperature.. The maximum transport dyes occurs at ratio of 1:1 TBP-hexane At pH 3.0 0.1 (feed phase) the transport dyes decreased. At high stirring speed (300 rpm) the dyes transport from the feed phase to the strip phase was completed within 60 minutes at $27^{\circ}C$. Under optimum conditions: Feed phase 100 mg/L dyes solution at pH 1.0 0.1, receiving phase 0.1 mol/L NaOH solution, membrane phase 1:1 TBP-hexane , Stirring speed 300 rpm and temperature $27^{\circ}C$, the proposed liquid membrane was applied to recover the textile effluent.

• 대한화학회지
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• 제38권2호
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• pp.122-128
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• 1994

거대고리 리간드는 금속이온과 선택적으로 결합하는데, 이를 이용하여 에멀젼 액체막을 통한 금속이온의 이동에 관하여 연구를 수행하였다. 금속이온은 유기층에 있는 운반체에 의하여 source phase에서 recevinng phase으로 이동한다. 운반체로는 거대고리 리간드인 $DBN_3O_3$를 사용하였다. 여기에서 에멀젼 액체막을 통한 금속이온의 이동에 관한 요인과 어떤 금속이온의 선택적 분리에 관하여 검토하였다. 금속이온과 거대고리 리간드 그리고 금속이온과 recevinng phase내에 있는 음이온에 대한 안정도 상수를 금속이온의 선택적 이동에 대한 척도로 조사하였다. 납이온이 혼합 용액에서 다른 금속이온보다 높은 이동속도를 나타내었다. Recevinng phases내의 음이온이 금속이온의 이동에 중요한 역할을 한다.Recevinng phases내에 있는 $NO_3^-$을 $S_2O_3^{2-}$대치하면 이동량이 증가함을 보였는데 이는 $Pb^{2-}-S_2O_3^{2-}$상호작용이 $Pb^{2+}-NO_3^-$상호작용보다 크기 때문이다.

• Current Optics and Photonics
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• 제7권1호
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• pp.1-14
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• 2023

Wavefront-coding imaging can achieve high-quality imaging along with a wide range of defocus. In this paper, the anti-laser detection and damage performance of wavefront-coding imaging systems using different asymmetric phase masks are studied, through modeling and simulation. Based on FresnelKirchhoff diffraction theory, the laser-propagation model of the wavefront-coding imaging system is established. The model uses defocus distance rather than wave aberration to characterize the degree of defocus of an imaging system. Then, based on a given defocus range, an optimization method based on Fisher information is used to determine the optimal phase-mask parameters. Finally, the anti-laser detection and damage performance of asymmetric phase masks at different defocus distances and propagation distances are simulated and analyzed. When studying the influence of defocus distance, compared to conventional imaging, the maximum single-pixel receiving power and echo-detection receiving power of asymmetric phase masks are reduced by about one and two orders of magnitude respectively. When exploring the influence of propagation distance, the maximum single-pixel receiving power of asymmetric phase masks decreases by about one order of magnitude and remains stable, and the echodetection receiving power gradually decreases with increasing propagation distance, until it approaches zero.

• 기본간호학회지
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• 제7권1호
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• pp.42-59
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• 2000

This study was done to analyze and develop the concept of coping in patients receiving hemodialysis. The Hybrid Model of concept development was applied to develop a conceptual structure of coping in patients receiving hemodialysis, which included a field study carried out using an in-dept interview with 18 patients in the hemodialysis room of one general hospital in Seoul. Data-analysis was done in three phases as suggested by the Hybrid Model. Finally, by summarizing the results from each case, the attributes of coping, its dimensions, definition and structure were outlined. According to the results of the study, a conceptual structure of coping which centers around stressors, stress-appraisal, strategy of coping and new definitions of coping in patients receiving hemodialysis was suggested : The coping of patients receiving hemodialysis is a process that deals with physical, emotional, inter-personal, and role stress caused by hemodialysis due to renal failure. It has a series of phases which include a phase that appraises the stressful situation based on past experience of chronic disease management, one's remaining rears, the extent of family support, the extent of economic dependency, inter-personal support. education and uncertainty, and a phase of developing coping strategies that con be affected by social support and self esteem. As a result of coping, patients adapt or not to the life situation of receiving hemodialysis.

• Journal of electromagnetic engineering and science
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• 제5권1호
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• pp.26-30
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• 2005

It is important to know phase offsets of PN(Pseudo Noise) sequences in spread spectrum communications since the acquisition is equivalent to making a phase offset between a receiving PN sequence and a PN sequence of local PN generator be identical. In this paper, a phase offset enumeration method for PN sequences with error detection, and its application to the synchronization are proposed. The phase offset enumeration for an n-tuple PN sequence and its error detection are performed when one period of the sequence is received. Once the phase offset of the receiving sequence is calculated, we can easily accomplish the synchronization by initializing shift registers of a local PN generator according to the phase offset value. The mean acquisition time performance of the proposed scheme was derived analytically. Since this synchronization scheme can be realized by using simple circuit and acquires very rapid acquisition in high SNR but shows performance degradation in low SNR, it can be especially useful in indoor and office environments.

• Asian-Australasian Journal of Animal Sciences
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• 제19권10호
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• pp.1450-1454
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• 2006

Three hundred and seventy-five steers (approximately 7 mo of age and $239.0{\pm}10.4kg$) were utilized to determine the effects of trace mineral (TM) supplementation and source on performance during the on-farm backgrounding and feedlot receiving phases of beef cattle production. At their respective ranches, steers were stratified by body weight into six groups. Groups were then assigned to one of six pens and pens were randomly assigned to treatments. Treatments consisted of: 1) control (no supplemental Cu, Zn, Mn, and Co), 2) inorganic trace mineral ($CuSO_4$, $ZnSO_4$, $MnSO_4$, and $CoCO_3$), and 3) organic trace mineral (iso-amounts of organic Cu, Zn, Mn, and Co). Mineral treatments were fed in alfalfa pellets formulated to supply 360 mg of Zn, 200 mg of Mn, 125 mg of Cu, and 12.5 mg of Co per head per day from either organic or inorganic trace mineral sources. Control steers received alfalfa pellets with no additional Cu, Zn, Mn, or Co. Steers were allowed free access to harvested alfalfa-grass hay throughout the 30-d on-farm backgrounding phase. On day 30 post-weaning, steers were weighed and transported to the feedlot. Steers were blocked by treatment within ranch, stratified by initial body weight, and randomly assigned to one of 36 pens (9-12 head per pen; 12 pens per treatment). Steers remained on the same on-farm backgrounding trace mineral treatments, however, trace mineral treatments were included in the total mixed growing ration. Steers were fed a corn silage-based growing diet throughout the 28 d feedlot receiving period. There was no effect of TM supplementation on performance of steers during the on-farm backgrounding phase. By the end of the 28-d feedlot receiving phase, ADG was similar between control and trace mineral supplemented steers. Steers supplemented with organic TM had greater (p<0.05) ADG than steers supplemented with inorganic TM by the end of the 28-d feedlot receiving phase. Morbidity and mortality rates were similar across treatments.

• 한국안전학회지
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• 제29권4호
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• pp.110-115
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• 2014

It is crucial for important facilities to withstand strong earthquakes because their damage may cause undesirable socio-economic effect. A liquefied natural gas (LNG) receiving terminal is one of the lifeline facilities whose seismic safety needs to be guaranteed. Even though all operating LNG receiving terminals in Korea were seismically designed, old design codes do not guarantee to comply with the current seismic design codes. In addition, if the constructional materials have been deteriorated, the seismic capacity of facilities may be also deteriorated. Therefore, it is necessary that the seismic performance of LNG receiving terminals is evaluated and the facilities that lack of seismic capacity have to be rehabilitated. In this paper, a procedure of seismic performance evaluation of such facilities is developed such that the procedure consists of three phases, namely pre-analysis, analysis, and evaluation phases. In the pre-analysis phase, design documents are reviewed and walk-on inspection is performed to determine the current state of the material properties. In the analysis phase, a structural analysis under a given earthquake or a seismic effect is performed to determine the seismic response of the structure. In the evaluation phase, seismic performance of the structure is evaluated based on limit states. Two of the important facilities, i.e. the submerged combustion vaporizer (SMV) and pipe racks of one of the Korean LNG receiving terminals are selected and evaluated according to the developed procedure. Both of the facilities are safe under the design level earthquake.

• 대한화학회지
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• 제38권2호
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• pp.129-135
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• 1994

Acyclic polyether dicarboxylic acid는 액체막계에서 금속이온의 운반체로 연구되었다. 수소이온이 이온화될 수 있는 리간드는 금속이온의 이동에 수소이온이 반대방향으로 이동된다. 이와 같은 리간드는 pH를 변화시키면 효과적으로 금속이온을 분리할 수 있고 농축시킬 수도 있다. 금속이온의 이동은 source phase의 염기의 농도와 receiving phase의 산의 농도를 증가시키면 증가된다. Acyclic polyether dicarboxylic acids를 운반체로 사용한 경쟁이동반응에서 칼슘이온을 선택적으로 분리할 가능성이 있다.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.380-386
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• 2005

유기 붕산계 화합물과 4차 암모늄염의 혼합물을 추출제로 사용하여 에멀젼형 액막법에 의한 과당과 포도당의 분리가 회분식 반응기에서 이루어졌다. 당 분리를 위해 적합한 추출제와 최적의 실험조건을 찾기 위하여 각 당에 대하여 독립적으로 추출 실험이 수행되었다. 원료상의 당 농도, 붕산계 화합물 종류와 w/o 비와 같은 여러 변수들이 과당과 포도당 분리에 미치는 영향이 조사되었으며, 이때 원료상과 회수상에서의 최종 당 농도가 분석되었다. 원료상에서의 과당/포도당 추출률 비는 매우 높았지만, 회수상에서의 당 농도는 높지 않았다. 상업적인 당 분리를 위한 에멀젼형 액막 시스템 개발을 위해 보다 회수상으로 과당의 역추출을 강하게 추진할 수 있는 염을 찾는 것이 요구되었다.