• 한국염색가공학회지
• /
• 제16권2호
• /
• pp.34-40
• /
• 2004

This study was conducted to remove the reactive dyes by the Ozone demand flask method which are one of the main pollutants in dye wastewater, Ozone oxidation of three kinds of the reactive dyes was examined to investigate the reactivity of dyes with ozone, Trihalomethane formation potentials(THMFPs), competition reaction and ozone utilization on various conditions for single- and multi-solute dye solution. Concentration of dyes was decreased continuously with increasing ozone dosage in the single-solute dye solutions. THMFPs per unit dye concentration were gradually increased with increase of ozone dosage. By the result of THMFPs change with reaction time, THMFPs were rapidly decreased within 1 minute in single-solute dye solutions. Dey were increased after 1 minute of reaction time, and then they were consistently decreased again after longer reaction time. Competition quotient values were calculated to investigate the preferential oxidation of individual dyes in multi-solute dye solutions. Competition quotients$(CQ_i)$ and values of the overall utilization efficiency, no$_3$, were increased at 40mg/1 of ozone dosage in multi-solute dye solutions.

• 한국염색가공학회지
• /
• 제19권3호
• /
• pp.26-36
• /
• 2007

This study was carried out to treat the aqueous solutions containing reactive dyes(RB19, RR120 and RY179) by the Ozone demand flask method and adsorption process using activated carbon fiber(ACF) which are one of the main pollutants in dye wastewater. Ozone oxidation of three kinds of the reactive dyes was examined to investigate the reactivity of dyes with ozone, competition reaction and ozone utilization on various conditions for single- and multi-solute dye solution. Concentration of dyes was decreased continuously with increasing ozone dosage in the single-solute dye solutions. Competition quotient values were calculated to investigate the preferential oxidation of individual dyes in multi-solute dye solutions. Competition quotients(CQi) and values of the overall utilization efficiency, ${\eta}O_3$, were increased at 40mg/l of ozone dosage in multi-solute dye solutions. ACF(A-15) has much larger specific surface area$(1,584m^2/g-ACF)$ in comparison with granular activated carbon adsorbent (F400, $1,125m^2/g-GAC$), which is commonly used, and most of pores were found to be micropores with pore radius of 2nm and below. It was found that RB19 was most easily adsorbed among the dyes in this study. In the case of PCP (p-chlorophenol) and sucrose, which are single component adsorbate, adsorption capacities of ACF(A-15) were in good agreement with the batch adsorption measurement, and saturation time predicted of ACF columns for these components was also well agreed with practically measured time. But in the case of reactive dyes, which have relatively high molecular weight and aggregated with multi-components, adsorption capacities or saturation time predicted were not agreed with practically measured values.

• 한국토양비료학회지
• /
• 제43권3호
• /
• pp.275-282
• /
• 2010

The laboratory column experiments were used to transport of metal elements by infiltration-related dispersion and/or diffusion in mine tailing of the Guryong gold mine. The mine tailing shows the neutral pH (for a pore water) and contains quartz, chlorite, pyrite and calcite. Both a non-reactive solute ($Cl^-$ of 100 mg $L^{-1}$) and a reactive solute (1N HCl), were injected continuously through columns. The breakthrough curve in the non-reactive experiment reached at a maximum under 1.5 pore volumes (PV). The longitudinal dispersion (0.607 cm) and hydrodynamic dispersion coefficient ($1.96{\times}10^{-7}cm^{2}sec^{-1}$) were calculated by the slope. In the reactive experiment, the plateau curve was appeared in the pH values of 5.3, 4.5 and 1.7. The releases of metal elements such as Fe, Mn, Al, Cu, Zn, Pb, and Cd were observed to be related to the pH buffering. High concentrations of Mn, Cd and Zn were observed at the first pH plateau (4 PV and pH 5.3), whereas Fe, Cu, Al and Pb were released as the pH decreased to 4.0 or less. The resulting order of metals mobility, based on the effluent water, is Mn=Cd>Zn>Cu>Fe>Al>Pb.

• 한국환경과학회지
• /
• 제7권6호
• /
• pp.753-759
• /
• 1998

In physical and reactive extraction of acrylic acid using various solvents the equilibrium characteristics of extraction were investigated. The degree of extraction in reactive extraction with Tri-n-octylamine(TOA) was 1.5~3 times than that in physical extraction. Distribution ratio was constant in methyl isobutyl ketone(MIBK) and n-butylacetate(n-BAc) but was increased with increasing the concentration of acrylic acid in benzene and chloroform. It can be explained by formation of dimers. Maximum extraction leadings of acrylic acid were three in benzene and were two in MIBK, chloroform and n-BAc, and it was found that acrylic acid was extracted as the form of $A_3$R In benzene and $A_2R$ in MIBK, chloroform and n-BAc. In effect of solvent, the degree of extraction was increased as he difference of solubility parameter of solvent and solute was decreased, and as dielectric constant of solvent was increased.

• Membrane and Water Treatment
• /
• 제14권2호
• /
• pp.95-106
• /
• 2023

In the developing country like India, groundwater is the main sources for household, irrigation and industrial use. Its contamination poses hydro-geological and environmental concern. The hazardous waste sites such as landfills can lead to contamination of ground water. The contaminants existing at such sites can eventually find ingress down through the soil and into the groundwater in case of leakage. It is necessary to understand the process of migration of pollutants through sub-surface porous medium for avoiding health risks. On this backdrop, the present paper investigates the behavior of pollutants' migration through porous media. The laboratory experiments were carried out on a soil-column model that represents porous media. Two different types of soils (standard sand and red soil) were considered as the media. Further, two different solutes, i.e., non-reactive and reactive, were used. The experimental results are simulated through numerical modeling. The percentage variation in the experimental and numerical results is found to be in the range of 0.75- 11.23 % and 0.84 - 1.26% in case of standard sand and red soil, respectively. While a close agreement is observed in most of the breakthrough curves obtained experimentally and numerically, good agreement is seen in either result in one case.

• 한국수자원학회논문집
• /
• 제31권3호
• /
• pp.347-360
• /
• 1998

균열 암반 매질에서의 지하수 흐름과 오염물질 이송에 대한 수치모의 실험이 hydromechanic 모형과 추계적 그리고 이산적 3차원 균열망 모형에 바탕을 둔 비정상상태 흐름 수치 모형을 이용하여 수행되었다. 오염물질 이송에 대한 수치모의 실험에서 random walk의 일종인 particle following 알고리즘이 사용되었다. 이 연구의 목적은 지하 깊은 곳에 위치한 Hot dry rock에서의 지열 개발을 위해 프랑스 Soultz sous Foret 지역에 설치된 두개의 깊은 착정인 GPK1과 GPK2 사이에서의 tracer test 반응을 1995년에 실행된 유체순환 현장 실험으로 부터 얻어진 자료를 이용하여 예측하는 것이다. 모의 실험 결과 비반응입자(nonreactive particles)에 대한 평균 이송시간은 두 착정 사이에서 약 5일이었다.

• 공업화학
• /
• 제7권1호
• /
• pp.203-213
• /
• 1996

평형 추출장치를 사용하여 유기산의 물리추출과 반응추출에서 추출도에 미치는 추출제의 종류와 농도, 용매의 영향을 조사하였다. 사용된 유기산은 아크릴산과 메타크릴산이었고, 추출제로는 n-octylamine(OA)과 di-n-octylamine(DOA), tri-n-octylamine(TOA)및 tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336)을 사용하였다. 실험결과 반응추출에서 추출도는 물리추출의 경우보다 2~9배 정도 증가 되었으며, 유기산의 추출도에 미치는 추출제의 영향은 OA, TOMAC, DOA 및 TOA의 순서로 추출도가 증가하였으며, 또한 추출제의 농도가 증가할수록 추출도가 증가하였다. 용매의 영향은 종래의 용매의 유전상수보다는 용해도인자에 의한 용매선택 방법이 신뢰성이 있었고, 용질과 용매의 용해도인자의 차이가 작을수록 추출도가 증가하여 케로진, 크실렌, 클로로포롬, MIBK 및 n-BAc의 순서로 좋아졌다.

• 자원환경지질
• /
• 제42권6호
• /
• pp.561-574
• /
• 2009

본 연구에서는 농업지역에서의 양수, 관개, 탈질작용을 고려한 불포화대 및 포화대 지하수 흐름 및 용질이동 모델인 VSFRT2D(Variably Saturated Flow and Reactive Transport model)를 개발하였다. VSFRT2D는 Richards equation을 지하수 흐름 지배방정식으로 이용하며, Thornthwaite 방법을 이용하여 강수가 일어나지 않을 때 지표면 증발산량 계산 절차를 포함하는 새로운 모델을 개발함으로써 기존의 불포화대 모델을 개선하였다. 또한 Monod kinetics에 기반한 생분해 기작을 네 개의 비선형 오염물 거동식과 세 종류의 미생물 거동식을 이용함으로서 탈질작용을 이 모델에 반영하였다. 개발된 모델을 질산성질소로 오염된 홍성 지역의 현장 관측 자료에 적용하였다. 본 연구에서는 강수, 양수, 증발산, 관개, 비료 투여 및 다양한 생분해 과정들이 지하수 흐름 및 오염물 거동에 미치는 효과들을 확인하기 위하여 각각의 과정을 개별적으로 나누어서 수치 모의한 후 각각의 결과를 상호 비교하였다. 수치 모의 결과 이 지역에서의 질산성 질소 농도 변화는 생분해에 의한 영향은 매우 미미하게 나타났다. 반면에 관개에 의한 양수, 강수, 질소 비료 시비에 의해서는 크게 영향을 받았다.

• Membrane and Water Treatment
• /
• 제9권6호
• /
• pp.385-392
• /
• 2018

Poly vinyl chloride (PVC) was chemically modified, and used for ultrafiltration to analyze the performance. Non-solvent induced phase separation (NIPS) method was used to prepare membranes. The neat PVC membrane was casted and used as a control membrane. Modified membrane was prepared by reacting PVC with ethanolamine (EA) in the casting solution (labeled as CM-PVC). Pure water permeability (PWP) was evaluated by measuring pure water flux. Humic acid was used as model foulant solute to analyze flux and rejection ability of membranes. Flux and rejection data of neat and modified membranes were compared to prove the improvement in the filtration performance. The experimental results showed that for PVC and CM-PVC, PWP was calculated to be ~64 and ${\sim}143L/m^2{\cdot}h$, respectively, and the rejection of humic acid was found to be 98% and 100%, respectively. TGA was carried out to analyze the effect of chemical modification on the thermal stability of polymer. FT-IR analysis was another characterization technique used for the comparative study.

• 농업과학연구
• /
• 제23권2호
• /
• pp.250-260
• /
• 1996

Observed results of the adsorption between two competing anions for the shared sorption sites represent that the adsorption phenomena may depends on the characteristics of anion and available sorption sites in a given conditions. In binary systems, adsorption of one species can significantly influence the fate of the other anion, resulting in control of the extent of solute-adsorbate distributions throughout soil profile. And the proton-donation mechanisms by organic anions having a carboxyl as a functional group can also influence the adsorption of inorganic anions onto the hydroxylated sites of Fe and Al oxides. However, study of competitive adsorption of specifically adsorbed anions illustrates some of difficulties which arise in interpretation of reactions at oxide/aqueous solution interfaces. At least two factors prevented a simple analysis of reactions. First, at any pH value the maximum amount of adsorbate taken up at the surface depends on the identity of the anion. Second, it was necessary to postulate the sorption sites where the anion can be adsorbed. Hence, anions having non-specific adsorption characteristics are less capable for sorption sites, compared to those of specific adsorption characteristics, even though competition complies both ordinary and electrostatic interactions for sorption sites. Therefore, competition among chemical species in soil matrix can be of major significance in determining the effective mobility of any reactive anions with sorption sites.