• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.585-592
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• 2003

The purpose of this paper is to investigate purification characteristic of soil-bentonite landfill liner and to develop of desirable liner system. In this study, column tests for soil-bentonite, reactive soil-bentonite and existing bentomat and reactive bentomat were carried out under the high pressure with water and leachate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.4 no.4
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• pp.398-403
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• 2003

The purpose of this paper is to investigate purification characteristic of soil-bentonite landfill liner and to develop a desirable liner system. In order to clarify the purification characteristics, high pressure column tests using soil-bentonite, reactive soil-bentonite and reactive bentomat were carried out in the presence of water and leachate. The test results indicated that the significant amount of NH$_3$-N, Pb and Cu was removed through the reactive soil-bentonite liner system.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.10a
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• pp.545-552
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• 2002

The purpose of this paper is to investigate permeability characteristic of soil-bentonite landfill liner and development of desirable liner system. In this study, permeability tests for soil-bentonite, reactive soil-bentonite and apply bentomat and reactive mat are carried out under the low and high water pressure. According to test result, additional amount of bentonite decreases the coefficient of permeability up to the bentonite mixture ratio of 15%. Therefore, the permeability test for landfill liner's indicated that the use of general water would be in more safe side because the liner system show low permeability duet decrease effect of porous by suspended soild(SS). The permeability of leachate for Zeolite mixture ratio 0, 5, 10% with bentonite mixture ratio 15% showed negligible variation in the permeability with general water. Therefore, Zeolite could be used as a successful that is available purification material for the treatment of leachate, without changing the of landfill liners. Also odious smell could be removed by adding smell amount of Zeolite to the leachate. It was revealed that the bentomat and reactive mat installed in soil-bentonite layer effectively improved the permeability as well as purification of the leachate.

• Journal of Soil and Groundwater Environment
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• v.17 no.4
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• pp.73-80
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• 2012

The objectives of this research were to study the applicability and limitations of permeable reactive barrier (PRB) for the removal of tetrachloroethylene (PCE) from the groundwater. PRB column tests were conducted using reactive material with Moringa Oleifera Mass - Bentonite (Mom-Bentonite). Most of the PCE in the groundwater was degraded and/or captured (sorpted) in the zone containing activated material (MOM-Bentonite). The removal rate of PCE from the groundwater was 90% and 75% after 30 days and 180 days, respectively. The effect of micro-organisms on the long-term permeability and reactivity of the barrier is not well understood. MOM-Bentonite PRB system in this research has the potential to be developed into an environmentally and economically acceptable technology for the in situ remediation of PCE-contaminated groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.168-171
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• 2003

This research was conducted to assess the performance of the mixed reactive materials with sand, iron filings, and HDTMA-bentonite for trichloroethylene (TCE) and chromate removal under controlled groundwater flow conditions. TCE and chromate removal rates with the mixtures of iron filing/HDTMA-bentonite were highest among four columns due to reduction by iron filings and sorption by HDTMA-bentonite. The greater capacity of the mixed iron filing/HDTMA-bentonite compared HDTMA-bentonite was due to an enhanced chromate reduction in addition to chromate sorption. The presence of chromate caused greater inhibition of TCE removal in the column with iron filings, while the presence of TCE caused less inhibition of TCE. Also, nitrate caused the decrease in TCE removal relative to chloride. Nitrate ions may also significantly affect TCE reduction rates by competing for electrons with the chlorinated compounds. The anion and co-existed contaminants competing effects should be considered when designed permeable reactive barriers (PRBs) composed of zero valent iron for field applications to remediate TCE and chromate.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.67-70
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• 2002

Remediation of groundwater contaminated with chlorinated organics, nitro aromatics, and heavy metals using zero valent iron (ZVI) filings has paid considerable attention in recent years. When the contaminants of high concentration leaked abundantly in subsurface environment, permeable reactive barrier technology using iron filing is taken a long time for the remediation of contaminated groundwater, The problem of contaminant shock is able to be solved using surfactant (hexadecyltrimethylammonium, HDTMA) modified bentonite (SMB) as immobilizing material. Therefore, the purpose of this research was to develop the combined remediation technology using conventional permeable reactive and immobilizing barrier for the enhanced decontamination of chlorinated compounds. Four column experiments were conducted to assess the performance of the mixed reactive materials with Ottawa sand, iron filing, and HDTMA-bentonite for trichloroethylene (TCE) removal under controlled groundwater flow conditions. TCE reduction rates with sand/iron filing/HDTMA-bentonite were highest among four column due to dechlorination of TCE by iron filing and sorption of TCE by SMB.

• Korean Journal of Soil Science and Fertilizer
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• v.42 no.4
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• pp.239-248
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• 2009

In this investigation, we observed surface morphology and porosity of a macroporous adsorbent made of Na-bentonite and Ca-bentonite as structure formation materials and grounded waste paper as macropore forming material for the development of a permeable reactive barrier to remove heavy metals in groundwater. Therefore, we selected minerals having higher cation exchange capacity among 2:1 clay minerals and other industrial minerals because sintering can significantly influence cation exchange capacity, resulting in drastic decrease in removal of heavy metals. The results showed that the increasing sintering temperature drastically decreased CEC by less than 10 % of the indigenous CEC carried by the selected minerals. One axial compressibility test results showed that the highest value was obtained from 5% newspaper waste pulp for both structure formation materials of Na-bentonite and Ca-bentonite although there were not much difference in bulk density among treatments. The pore formation influenced by sintering temperature and period contributes removal of heavy metals passing through the sintered macroporous media having different water retention capacity.