• Title/Summary/Keyword: reactive behavior

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Effect of nitrogen doping on properties of plasma polymerized poly (ethylene glycol) film

  • Javid, Amjed;Long, Wen;Lee, Joon S.;Kim, Jay B.;Sahu, B.B.;Jin, Su B.;Han, Jeon G.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.286-288
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    • 2014
  • This study deals with the catalyst free radio frequency plasma assisted polymerization of ethylene glycol using nitrogen as reactive gas to modify the surface chemistry and morphology. The deposited film was characterized through various analysis techniques i.e. surface profilometry, Forier transform infrared spectroscopy, water contact angle and UV-visible spectroscopy to analyze film thickness, chemical structure, surface energy and optical properties respectively. The surface topography was analyzed by Atomic force microscopy. It was observed that the ethylene oxide behaviour and optical transmittance of the film were reduced with the introduction of nitrogen gas due to higher fragmentation of monomer. However the hydrophilic behavior of the film improved due to formation of new water loving functional groups suitable for biomedical applications.

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Fabrication of Aluminum/Aluminum Nitride Composites by Reactive Mechanical Alloying

  • Yu, Seung-Hoon;Shin, Kwang-Seon
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1294-1295
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    • 2006
  • Various reactions and the in-situ formation of new phases can occur during the mechanical alloying process. In the present study, Al powders were strengthened by AlN, using the in-situ processing technique during mechanical alloying. Differential thermal analysis and X-ray diffraction studies were carried out in order to examine the formation behavior of AlN. It was found that the precursors of AlN were formed in the Al powders and transformed to AlN at temperatures above $600^{\circ}C$. The hot extrusion process was utilized to consolidate the composite powders. The microstructure of the extrusions was examined by SEM and TEM. In order to investigate the mechanical properties of the extrusions, compression tests and hardness measurements were carried out. It was found that the mechanical properties and the thermal stability of the Al/AlN composites were significantly greater than those of conventional Al matrix composites.

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Influence of High-energy Milling and Sintering Cycle on Obtaining of TiAl from Elemental Ti and Al Powders

  • Esteban, P.G.;Gordo, E.;Ruiz-Navas, E.M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.727-728
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    • 2006
  • The present work studies the influence of high-energy milling (HEM) and sintering cycle of Ti and Al powders on the obtainment of TiAl. This study shows that HEM modifies the diffusion processes during the sintering stage. The samples were obtained by cold uniaxial and isostatic pressing, pre-sintered at different temperatures, and heated up to the sintering temperature. This study also shows the effect of powder additions processed by HEM on the sintering behavior of elemental Ti and Al powders.

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Numerical analysis of crack propagation in cement PMMA: application of SED approach

  • Ali, Benouis;Abdelkader, Boulenouar;Noureddine, Benseddiq;Boualem, Serier
    • Structural Engineering and Mechanics
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    • v.55 no.1
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    • pp.93-109
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    • 2015
  • Finite element analysis (FEA) combined with the concepts of linear elastic fracture mechanics (LEFM) provides a practical and convenient means to study the fracture and crack growth of materials. In this paper, a numerical modeling of crack propagation in the cement mantle of the reconstructed acetabulum is presented. This work is based on the implementation of the displacement extrapolation method (DEM) and the strain energy density (SED) theory in a finite element code. At each crack increment length, the kinking angle is evaluated as a function of stress intensity factors (SIFs). In this paper, we analyzed the mechanical behavior of cracks initiated in the cement mantle by evaluating the SIFs. The effect of the defect on the crack propagation path was highlighted.

Room Temperature Deposition and Heat Treatment Behavior of ATO Thin Films by Ion Beam Sputtering (이온빔 스퍼터링에 의한 ATO 박막의 실온 증착 및 열처리에 따른 특성변화)

  • 구창영;김경중;김광호;이희영
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1025-1032
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    • 2000
  • 산화분위기에서의 반응성 이온빔 스퍼터링법으로 Sn과 Sb 금속 타겟을 사용하여 실온에서 ATO 박막을 증착하였다. Sb 첨가량, 박막의 두께 및 열처리가 ATO 박막의 전기적 특성과 광학적 특성에 미치는 효과를 연구하고자 하였다. 제조된 ATO 박막의 두께는 약 1500$\AA$과 1000$\AA$으로 조절하였으며, Sb 농도는 10.8wt% 또는 14.9wt%임이 XPS 분석에 의하여 확인되었다. 증착한 박막의 열처리는 40$0^{\circ}C$~$600^{\circ}C$의 온도범위에서 산소 또는 forming gas(10% H$_2$-90% Ar) 분위기에서 30분간 수행하였다. 이렇게 제조된 ATO 박막은 Sb의 첨가량, 두께 및 열처리 조건에 따라 다양한 전기 비저항 값과 가시광선 대역에서의 광투과도를 나타내었다.

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Integrated Stability Analysis for Power Systems Using Energy Function (에너지함수에 의한 통합안정도해석)

  • Moon, Young-Hyun;Lee, Eung-Hyuk;Lee, Yoon-Seop;Oh, Yong-Taeg;Kim, Baik
    • Proceedings of the KIEE Conference
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    • 1996.11a
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    • pp.77-79
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    • 1996
  • This paper presents an integrated stability analysis by the direct energy function method based on Equivalent Mechanical Model(EMM) which reflects the system behavior related to both angle and voltage stabilities. Actually, angle and voltage stability are intimately related in power system, so complete decoupling of these stability analysis is not possible in general, particularly in stressed power systems. In this paper, it is shown that a identical energy function can be used for angle and voltage stability analysis. The proposed energy function reflects the line resistances and reactive powers under the constraints of the same R/X ratio. The energy margin between UEP and SEP presents a good collapse proximity index in both types of stability analysis.

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The Effect of Titanium and Copper Coatings on the Modulus of Rupture of Alumina (티타늄 및 구리증착이 알루미나 곡강도에 미치는 영향)

  • 황하룡;이임렬
    • Journal of the Korean institute of surface engineering
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    • v.27 no.1
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    • pp.29-35
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    • 1994
  • The effects of coating of 3$\mu\textrm{m}$ thickness on the mechanical property of alumina after heat treatment at 100$0^{\circ}C$ for 30minutes under $10^{-6}$torr vacuum was quantified in terms of modulus of rupture(MOR) using Weibull plot. While the copper coating did not change MOR of alumina due to the nonwetting behavior of Cu on $Al_2O_3$, the reactive titanium metal coating caused a noticeable 29% reduction in averaged MOr strength. This was related with the combined effects of microcracks in coating formed during heat treatment and good bonding character between Ti and $Al_2O_3$. The effect of cosputtering of Ti and Cu, bilayer coatings of Cu/Ti and Ti/Cu were also investigated. It was found that Ti, cosputtered, Cu/ti and Ti/Cu coatings reduced MOR strength of alumina in the order listed. This was correlated with the amount of Ti at coating/alumina inter-face associated with a coated layer or segregation of Ti during heat treatment.

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An Improved Control Approach for DSTATCOM with Distorted and Unbalanced AC Mains

  • Singh, Bhim;Solanki, Jitendra
    • Journal of Power Electronics
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    • v.8 no.2
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    • pp.131-140
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    • 2008
  • This paper presents a new control approach of DSTATCOM (distribution static compensator) for compensation of reactive power, unbalanced loading and harmonic currents under unbalanced non-sinusoidal ac mains. The control of DSTATCOM is achieved using Adaline based current estimator based on LMS algorithm to maintain source currents real and undistorted. The dc bus voltage of voltage source converter (VSC) working as DSTATCOM is maintained at constant voltage using a proportional-integral (PI) controller. The DSTATCOM system alongwith proposed control scheme is modeled in MATLAB to simulate the behavior of the system. The practical implementation of the DSTATCOM is carried out using dSPACE DS1104 R&D controller having TMS320F240 as a slave DSP. Simulated and implementation results are presented to demonstrate the effectiveness of the DSTATCOM with Adaline based control to meet the severe load perturbations with different types of loads (linear and non-linear) under distorted and unbalanced AC mains.

Dual Surface Modifications of Silicon Surfaces for Tribological Application in MEMS

  • Pham, Duc-Cuong;Singh, R. Arvind;Yoon, Eui-Sung
    • KSTLE International Journal
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    • v.8 no.2
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    • pp.26-28
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    • 2007
  • Si(100) surfaces were topographically modified i.e. the surfaces were patterned at micro-scale using photolithography and DRIE (Deep Reactive Ion Etching) fabrication techniques. The patterned shapes included micro-pillars and microchannels. After the fabrication of the patterns, the patterned surfaces were chemically modified by coating a thin DLC film. The surfaces were then evaluated for their friction behavior at micro-scale in comparison with those of bare Si(100) flat, DLC coated Si(100) flat and uncoated patterned surfaces. Experimental results showed that the chemically treated (DLC coated) patterned surfaces exhibited the lowest values of coefficient of friction when compared to the rest of the surfaces. This indicates that a combination of both the topographical and chemical modification is very effective in reducing the friction property. Combined surface treatments such as these could be useful for tribological applications in miniaturized devices such as Micro-Electro-Mechanical-Systems (MEMS).

Ag(100) 기판위에 증착된 Nb Cluster에 관한 STM연구

  • 윤홍식;유미애;한권환;이준희;양경득;여인환
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.140-140
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    • 2000
  • The initial growth mode of Nb on Ag(11) in sub-monolayer regime and the influence of subsequent 520K annealing are studied using UHV Scanning Tunneling Microscopy. E-beam evaporated Nb is deposited onto the substrate at RT, and STM measurements are carried out at RT and 78 K. With Nb being immiscible in bulk Ag, 3D islands formation begins at early stage and no particular ordered structure is found. After annealing to 520K, most of islands are disappeared from terrace. There exist 2 possibilities. : (1) Diffusion of Nb into the 2nd or 3rd layer of Ag substrate or (2) agglomeration of Nb on Ag at higher temperature. A model will be given to explain the evidence. In addition, we investigated the change of STM image according to bias voltage depending on island size. Possible physical mechanism responsible for such behavior together with interaction between Nb islands and reactive gases will be also discussed.

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