• 제목/요약/키워드: reactive behavior

검색결과 276건 처리시간 0.023초

Molecular Dynamics Simulation of Contact Process in AFM/FFM Surface Observation

  • Shimizu, J.;Zhou, L.;Eda, H.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.61-62
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    • 2002
  • In order to clarify the contact mechanism between specimen surface and probe tip in the surface observation by the AFM (atomic force microscope) or the FFM (friction force microscope), several molecular dynamics simulations have been performed. In the simulation, a 3-dimensional simulation model is proposed where the specimen and the probe are assumed to consist of mono-crystal line copper and a carbon atom respectively and the effect of cantilever stiffness is also taken into considered. The surface observation process on a well-defined Cu{100} is simulated. The influences of cantilever stiffness on the reactive force images and the behavior of probe tip were evaluated. As a resuIt, several phenomena similar to those observed by the actual surface observation experiment, such as double-slip behavior and dispersion in the stick-slip wave period were observed.

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Weak Interactions Between Organic Molecules and Alkali Metal Ions Present in Zeolites Help Manipulate the Excited State Behavior of Organic Molecules

  • Ramamurthy, V.
    • Journal of Photoscience
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    • 제10권1호
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    • pp.127-148
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    • 2003
  • Zeolite is a porous highly interactive matrix. Zeolitic cations help to generate triplets from molecules that possess poor intersystem crossing efficiency. Certain zeolites act as electron acceptors and thus can spontaneously generate radical cations. Zeolites also act as proton donors and thus yield carbocations without any additional reagents. These reactive species, radical cations and carbocations, have long lifetime within a zeolite and thus lend themselves to be handled as ‘regular’ chemicals. Internal structure of zeolites is studded with cations, the counter-ions of the anionic framework. The internal constrained structure and the cations serve as handles for chemists to control the behavior of guest molecules included within zeolites.

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스퍼터링 증착조건이 TiN막의 마모특성에 미치는 영향 (Effect of Sputtering Deposition Conditions on Tribological Characteristics of TiN films)

  • 류준욱;유재욱;임대순
    • Tribology and Lubricants
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    • 제11권1호
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    • pp.37-43
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    • 1995
  • Sputtering parameters such as N$_{2}$ flow percentage and bias voltage in reactive TiN film deposition by RF magnetron sputtering system were selected to investigate the effects of sputtering deposition conditions on tribological characteristics of TiN films. Wear scar of the steel ball damaged by TiN films was measured by SEM to understand wear behavior of deposited TiN films. Crystallization and induced strain of TiN were detected by XRD. Wear mode changed from plastic to brittle with increasing N$_{2}$ ratio. Wear scar by sliding with TiN film deposited at around 27% N$_{2}$ ratio was maximum. The results indicate that bias voltage affects tribological behavior by formation of high density film and internal stress.

Fall arresting system

  • Leamon, T.S.;Malone, C.;Son, D.H.
    • 대한인간공학회지
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    • 제10권1호
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    • pp.23-28
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    • 1991
  • A major inhibition of past work in a slip/fall accident study has been due to the lack of a facility and a methodology to experimentally investigate such behavior without expowting human subjects to the natural danger of injury resulting from a fall. In order to carry out a slip/fall research, a unique facility must be created specially to investigate falling and slipping behavior. One component of this facility will be used to focus a research towards experimental investigations of the basic mechanisms involved in falls. Especially, this compo- nent must be designed, developed, and fabricated to provide passive, reactive support at the point of loss of ba- lance. This component must allow both normal and reduced friction surfaces to be designated to investigate human falling in the experimental conditions. This study will address how a fall arresting system was designed and it would be implemented in actual case of a slip/fall study.

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The Uptake of Solvent in Polymeric Thin Membranes By a Relaxation-Sorption Coupled Mechanism

  • Song, Kyu-Min;Hong, Won-Hi
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 추계 총회 및 학술발표회
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    • pp.43-44
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    • 1995
  • The diffusion behavior of liquid into polymer has been described by Fick's law, but the departure from Fickian diffusion is frequently found. In this study, 'noble' expressions for the rates of relaxation and sorption are introduced to eliminate these limitations. The ralaxation-sorption coupled mechanism model are based on the possibility of contacting liquid molecule and the active site which has the numerical concept of free volume. The concept has an analogy of reaction rate expressed by the possibility of collision with molecules and used in adsorption and reactive extraction etc. The new model simulated by Rungc-Kutta method for initial-value problem and Fickian diffusion is caompared with experimental data. The results show that the ralaxation-sorption coupled mechanism is able to account well for Fickian and non-Fickian sorption behavior including sigmoid and two-stage. In addition, this model has a chance of expansion to multi-component sorption with ease.

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Morphology and Thermal Oxidation Behavior of Graphene Supported on Atomically Flat Mica Substrates

  • 고택영;심지혜;류순민
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.459-459
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    • 2011
  • Graphene has many fascinating material properties such as high electron mobility, high optical transparency, excellent thermal conductivity, superior Young's modulus, etc. Several studies have recently found that single-layer graphene is chemically more reactive than few-layer graphene when supported on silicon dioxide substrates with sub-nm roughness. In this study, we have investigated the influence of substrates on chemical reactivity of graphene. Morphology and thermal oxidation behavior of graphene on atomically flat mica substrates were studied by atomic force microscopy (AFM) and Raman spectroscopy compared to graphene on SiO2/Si substrates. Notably, oxidation of single-layer graphene proceeds more slowly on mica than SiO2/Si. Detailed analysis led to a conclusion that deformation along the out-of-plane direction enhances reactivity of graphene.

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SILO 구조의 제작 방법과 소자 분리 특성 (Fabrication and characterization of SILO isolation structure)

  • 최수한;장택용;김병렬
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
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    • pp.328-331
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    • 1988
  • Sealed Interface Local Oxidation (SILO) technology has been investigated using a nitride/oxide/nitride three-layered sandwich structure. P-type silicon substrate was either nitrided by rapid thermal processing, or silicon nitride was deposited by LPCVD method. A three-layered sandwich structure was patterned either by reactive ion etch (RIE) mode or by plasma mode. Sacrificial oxidation conditions were also varied. Physical characterization such as cross-section analysis of field oxide, and electrical characterization such as gate oxide integrity, junction leakage and transistor behavior were carried out. It was found that bird's beak was nearly zero or below 0.1um, and the junction leakages in plasma mode were low compared to devices of the same geometry patterned in RIE mode, and gate oxide integrity and transistor behavior were comparable. Conclusively, SILO process is compatible with conventional local oxidation process.

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Effect of Microstructure on Corrosion Behavior of TiN Hard Coatings Produced by Two Grid-Attached Magnetron Sputtering

  • Kim, Jung Gu;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • 제5권1호
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    • pp.15-22
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    • 2006
  • The introduction of two-grid inside a conventional process system produces a reactive coating deposition and increases metal ion ratio in the plasma, resulting in denser and smoother films. The corrosion behaviors of TiN coatings were investigated by electrochemical methods, such as potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in deaerated 3.5% NaCl solution. Electrochemical tests were used to evaluate the effect of microstructure on the corrosion behavior of TiN coatings exposed to a corrosive environment. The crystal structure of the coatings was examined by X-ray diffractometry (XRD) and the microstructure of the coatings was investigated by scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM). In the potentiodynamic polarization test and EIS measurement, the corrosion current density of TiN deposited by two grid-attached magnetron sputtering was lower than TiN deposited by conventional magnetron type and also presented higher Rct values during 240 h immersion time. It is attributed to the formation of a dense microstructure, which promotes the compactness of coatings and yields lower porosity.

집합조직이 존재하는 TiN 코팅 층의 마찰, 마멸, 내부식 특성에 관한 연구 (Study on the Frictional Behavior, Wear and Corrosion Resistance of Textured TiN Coated Layers)

  • 김희동;김인수;성동영;이민구
    • 소성∙가공
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    • 제12권4호
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    • pp.394-400
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    • 2003
  • TiN coated films exhibit excellent mechanical properties such as high wear, erosion and corrosion resistances and a high thermal stability. Therefore, they are widely applied to a coating material in tools, ornaments, parts and semiconductors. However, the fracture of TiN coated films frequently occurs. The distribution of preferred orientations, i.e., texture, of TiN coated films strongly influences the fracture behavior of these films. In the present study. various TiN coating layers having different textures were prepared by the reactive ion physical vapor deposition and the texture dependence of friction coefficient, erosion and corrosion in these coating layers was investigated. The sample depicting the (115) texture parallel to the coating layer normal displayed a flatter surface than that observed from the sample having the (111) texture. The friction coefficient of TiN thin films was hardly dependent on the texture of coated samples. The samples having (115) texture displayed higher wear, erosion and corrosion resistances than the samples having (111) texture.

스케줄링 가능성 분석을 위한 UML 기반의 실시간 내장형 시스템 모델링 (A tudy on UML based Modeling of a Real-Time Enbedded Systems for analysing Schedulability)

  • 이재익;강순주;서대화
    • 한국정보과학회:학술대회논문집
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    • 한국정보과학회 1998년도 가을 학술발표논문집 Vol.25 No.2 (1)
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    • pp.573-575
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    • 1998
  • 실시간 내장형 시스템(real-time embedded system)의 반응 동작(reactive behavior)을 정확하게 분석하기 위해서 상태차트(statechart)에 바탕을 둔 객체 지향 모델링 방법론들이 많이 사용되고 있다. 하지만 이들 방법론들은 경성 실시간 시스템(hard real-time system)이라면 반드시 고려해야할 스케줄링 가능성분석(scheduability analysis)에 필요한 시간에 대한 정보와 시간 제약을 정확히 나타내지 못하는 문제점이 있다. 본 논문에서는 최근 OMG(Object Management Group)에서 객체 지향개발의 기준으로 채택된 UML(Unifies Modeling Language) ver1.1을 사용하여 실시간 내장형 시스템의 반응 동작과 시스템의 시제 동작(temporal behavior)을 모델링하여, 모델링된 시스템이 스케줄링 가능성 분석이 효과적으로 이루어지는 방안을 제안한다.