• Title/Summary/Keyword: reaction time

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The Effect of Pulsed Ultrasound on Skin Inflammatory Reaction Induced by Ultraviolet Irradiation (자외선 조사로 유발된 피부 염증성 반응에 맥동성 초음파가 미치는 영향)

  • Lee, Jeong-Woo;Park, Su-Ji;Yoon, Se-Won
    • The Journal of Korean Physical Therapy
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    • v.23 no.4
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    • pp.53-58
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    • 2011
  • Purpose: This study aims to examine the effects of pulsed ultrasound on skin inflammatory reaction induced by ultraviolet irradiation. Methods: Twenty subjects were selected for this study. Inflammatory reaction was induced by ultraviolet irradiation in two areas of the lumbar region of the subjects. Pulsed ultrasound (3 MHz) was applied to one of the two areas of inflammatory reaction at a pulse ratio of 1:4, intensity of $0.5W/cm^2$, once a day for 5 min, and pulsed ultrasound was not applied to the other area. Wound color (chromatic red), luminance (gray) and wound contraction (area) were measured using digital imaging processing method. Results: There was a significant difference in wound color (chromatic red) in the interaction between time and area. There was a significant difference in luminance in the interaction between time and area. There was a significant difference in wound contraction between the two areas. Conclusion: These results indicate that pulsed ultrasound increased the wound contraction rate and reduced the inflammatory reaction activity such as erythema induced by ultraviolet irradiation.

Optimization of Biodiesel Production from Waste Frying Oil using Response Surface Method (Response Surface Method를 이용한 폐식용유로부터 바이오디젤 생산의 최적화)

  • 이세진;김의용
    • KSBB Journal
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    • v.17 no.4
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    • pp.396-402
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    • 2002
  • Biodiesel has attracted considerable attention during the past decade as a biodegradable, nontoxic, and renewable fuel, Several processes for the production of biodiesel have been developed, among which transesterification under alkali-catalysis gives high level yield of methyl esters in short reaction times. In this research, response surface method was applied to optimize the transesterification reaction under alkali-catalysis. It was found that reaction temperature, reaction time, and agitation rate of reactor had profound effects among the seven variables affecting on biodiesel conversion. The optimal temperature, reaction time, and agitation speed were 67$^{\circ}C$, 68 minutes, and 94 rpm, respectively. Under the optimal conditions, the experimental value of biodiesel conversion was 99.7%.

Graft Polymerization of MMA onto Sodium Alginate by Sodium Metaperiodate (메타과요오드산소다에 의한 알긴산소다의 MMA graft 중합)

  • Park, Tchun-Wook
    • Elastomers and Composites
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    • v.14 no.1
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    • pp.7-12
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    • 1979
  • Graft copolymerization of methlymethacrylate(MMA) onto sodium alginate(SA) aqueous solution by sodium metaperiodate$(NaIO_4)$ as an initiator was carried out with the variation of the reaction time, the reaction temperature and the concentrations of initiator and monomer. The results obtained were as follows: 1. SA was easily separated from the reaction mixture of homopolymer, graft polymer and sodium alginate ungrafted by the treatment of concentrated boiling $Na_3PO_4$, solution with the small amount of $Na_2SO_3$ to the mixture and then isolated as the acid form by acidifying the salts solution containing SA. 2. The amount of graft polymer was larger than that of homopolymer below $70^{\circ}C$ whereas above $70^{\circ}C$ the amount of homopolymer was larger. 3. The sum of each amount of graft polymer ana homopolymer was always increased with increase of the reaction time, the reaction temperature and the concentrations of initiator and monomer. 4. With increase of the concentration of initiator, the graft efficiency was increased below $70^{\circ}C$ while decreased above $70^{\circ}C$. 5. Graft copolymerization of MMA onto SA in aqueous solution was carried out without initiator.

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Afterpolymerization and Depolymerization of Poly-${\varepsilon}$-caproamide in Solid State (고체상태에서 Poly-${\varepsilon}$-caproamide의 후중합 및 해중합에 관한 연구)

  • Jung-Ji Moon;Dong-ho Lee;Tae-oan Ahn
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.450-454
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    • 1973
  • The afterpolymerization and depolymerization of poly-${\varepsilon}$-caproamide in solid state have been studied under two different reaction conditions, nitrogen flow and sealed state. The degree of polymerization ($\bar{P}$) of nylon 6 increased with the increase in reaction time and temperature, and then reacted finally an equilibrium. In the presence of oxygen, $\bar{P}$ decreased by increasing the reaction time due to the oxidation reaction. Under certain reaction condition, the change of $\bar{P}$ for different initial degree of polymerization ($\bar{P}_0$) tendered toward unity in equilibrium.

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Effect of Reaction Conditions of Pyrolysis on the Characteristics of Sludge Char (열분해 조건에 따른 슬러지 Char 특성 변화)

  • Cha, Jin-Sun;Park, Young-Kwon
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.851-856
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    • 2011
  • In this study, char was produced via pyrolysis of sewage sludge and the effects of reaction conditions(temperature, heating rate, reaction time) on characteristics of char were investigated. As temperature increased from $300^{\circ}C$ to $800^{\circ}C$, the surface area of sludge char increased in general but decreased at $700^{\circ}C$ temporarily. The effect of heating rate on specific surface area and pore volume of char was not large. Meanwhile, specific surface area and pore volume increased with reaction time but average pore diameter decreased.

Real-Time Detection of DNA Hybridization Assay by Using Evanescent Field Microscopy

  • Kim, Do-Kyun;Choi, Yong-Sung;Murakami, Yuji;Tamiya, Eiichi;Kwon, Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.85-90
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    • 2001
  • The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and other application area. So, the improvement of DNA detection system is very important for the determination of this hybridization reaction. In this study, we report the characterization of the probe and target oligonucleotide hybridization reaction using the evanescent field microscopy. First, we have fabricated DNA chip microarray. The particles which were immobilized oligonucleotides were arranged by the random fluidic self-assembly on the pattern chips, using hydrophobic interaction. Second, we have detected DNA hybridization reaction using evanescent field microscopy. The 5'-biotinylated probe oligonucleotides were immobilized on the surface of DNA chip microarray and the hybridization reaction with the Rhodamine conjugated target oligonucleotide was excited fluorescence generated on the evanescent field microscopy. In the foundation of this result, we could be employed as the basis of a probe olidonucleotide, capable of detecting the target oligonucleotide and monitoring it in a large analyte concentration range and various mismatching condition.

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Effect of the Heating Temperature on the Alkali-activation Reaction of Calcined Kaolin Powder (열처리 카올린 분말의 알칼리활성화 반응에 미치는 가열온도의 영향)

  • Kim, Sung Gon;Song, Tae Woong
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.601-607
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    • 2012
  • The alkali-activation reaction of two types of typical kaolin calcined at various lower temperatures was investigated at room temperature and at elevated temperatures. For the assessment of the reactivity, the temperature increase and the setting time of pastes prepared with calcined kaolin and sodium/potassium hydroxide solution were measured. Unlike raw kaolin, calcined kaolin samples prepared at various temperature showed an alkali-activation reaction according to the different aspects of the changes in the mineral phases. The reactivity with alkaline solutions was exceedingly activated in the samples calcined at $600-650^{\circ}C$, but the reactivity gradually decreased as the temperature increased in a higher temperature range, most likely due to the changes in the crystal structure of the dehydrated kaolin. The activation effect of the calcination treatment was achieved at reaction temperatures that exceeded $60^{\circ}C$ and was enhanced as the temperature increased. The reactivity of the calcined kaolin with an alkaline solution was more enhanced with the solution of a higher concentration and with a solution prepared from sodium hydroxide rather than potassium hydroxide.

A Study on DME Conversion rate using New Catalyst (신 촉매를 이용한 DME 전환율에 관한 연구)

  • Jeong, I.S.
    • Journal of the Korean Society of Mechanical Technology
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    • v.13 no.2
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    • pp.123-128
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    • 2011
  • It has been stand high in estimation to converse from Carbon dioxide to Dimethyl Ether in new alternative fuel energy division in 21C, especially Using of DME in point of view of transportation fuel has been discussed of a new clean energy which is very lower of exhaust gas than gasoline and diesel energy. In this paper it is used ZSM-5 and I developed new catalyst by addition of cerium to control acidity. The new catalyst was proved high conversion rate, when it was conversed from methanol to DME, there wasn't any additional material except DME and water, and I overlooked reaction temperature, reaction time, amount of catalyst, amount of added cerium, effect of water content in methanol, reaction temperature by making change of reaction time. I have conclude that conversion rate to DME was increased as increased of catalyst amounts. The best catalyst condition of without additional product was treated poisoning from ZSM-5 to 5% cerium and new catalyst was not effected in purity of fuel methanol.

Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling (Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도)

  • Sohn, Ho-Sang;Jung, Kwang-Hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

Effect of Maillard reaction with xylose, yeast extract and methionine on volatile components and potent odorants of tuna viscera hydrolysate

  • Sumitra Boonbumrung;Nantipa Pansawat;Pramvadee Tepwong;Juta Mookdasanit
    • Fisheries and Aquatic Sciences
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    • v.26 no.6
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    • pp.393-405
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    • 2023
  • The aim of this research was to enhance the flavor of visceral extracts from skipjack tuna. Flavor precursors and the optimum condition for the Maillard reaction were determined. The flavor extract was prepared from the tuna viscera using Endo/Exo Protease controlled in 3 factors; temperature, enzyme amounts and incubation time. The optimal condition for producing tuna viscera protein hydrolysate (TVPH) was 60℃, 0.5% enzyme (w/w) and 4-hour incubation time. TVPH were further processed to tuna viscera flavor enhancer (TVFE) with Maillard reaction. The Maillard reactions of TVFE were conducted with or without supplements such as xylose, yeast extract and methionine. The Maillard volatile components were analyzed with gas chromatography-mass spectrometry. Sixteen volatiles such as 2-methylpropanal, methylpyrazine, 2,5-dimethylpyrazine, dimethyl disulfide and 2-acetylthaizone were newly formed via Maillard reaction and the similarity of volatile contents from TVPH and TVFE were virtualized using Pearson's correlation integrated with heat-map and principal component analysis. To virtualize aromagram of TVPH and TVFE, odor activity value and odor impact spectrum (OIS) techniques were applied. According to OIS results, 3-methylbutanal, 2-methylbutanal, 1-octen-3-ol 2,5-dimethylpyrazine, methional and dimethyl trisulfide were the potent odorants contributed to the meaty, creamy, and toasted aroma in TVFE.