• 한국세라믹학회지
• /
• 제27권8호
• /
• pp.956-956
• /
• 1990

석탄회의 탄소가 첨가된 질화반응시에 생성된 AIN, SiC 그리고 Si3N4 등의 생성물 분포를 반응온도, 시간 그리고 탄소의 첨가량에 따라 검토하였다. AIN의 조성은 시료입자가 작을수록 증가하였으며 반응온도 14500~1500℃와 약 2시간의 반응시간 그리고 약 30%의 탄소 첨가량 (시료무게 기준) 에서 최대값을 나타내었다. SiC와 Si3N4 조성변화는 서로 상반된 경향을 보였으며 반응온도가 낮고 반응시간이 작으며 그리고 탄소첨가량이 증가할 수록 SiC의 조성은 Si3N4 에 비하여 크게 나타났다.

• 한국환경보건학회지
• /
• 제26권4호
• /
• pp.122-128
• /
• 2000

This study was carried out to survey trihalomethane formation potential(THMFP) levels in drinking underground water and to examine its characteristics in Kunsan area. In drinking underground water, THMFP increased with the lapse of reaction time and 96hr-THMFP was the highest of THMFPs examined. In many cases, 24hr-THMFP, 48hr-THMFP and 96hr-THMFP reflected 2hr-THMFP level due to the largest composition ratio of CHCl$_3$ decreased with the lapse of reaction of CHCl$_3$ among THM individuals. CHCl$_3$ was mostly formed within early 2hour of reaction time, but CHClBr$_2$ and CHBr$_3$ continued their formation until 48 hour. Accordingly, the composition ratio of CHCl$_3$ decreased with the lapse of reaction time while that of total Br derivatives increased. 96hr-THMFPs of drinking underground water in Kunsan area ranged from N.D.(not detected)~98.80 $\mu\textrm{g}$/$\ell$ and, in general, those of western section of Kunsan area, closer to the coast, showed the higher tendency. But, from their large range of variance, it could be considered that THMFPs differ individually even in the same section depending on such factors as the difference of water stream, circumstances of management and so on. All the parameters for water quality examined(pH, KMnO$_4$ consumption;UV$_{254}$ , TOC. Cl$^{[-10]}$ ) showed very week corelation with 96h-THMFP.

• Macromolecular Research
• /
• 제17권8호
• /
• pp.575-579
• /
• 2009

Copolymerization of L-lactide and s-caprolactone initiated by tin (II) octoate (Sn(Oct)$_2$) was carried out in supercritical chlorodifluoromethane (R22) with varying reaction conditions (time and temperature) and amounts of monomer and catalyst, under a pressure of 250 bar. The optimum conditions were a reaction time of 10 h and a temperature of 130 $^{\circ}C$, which is similar to the temperature used in bulk copolymerization system. The conversion increased from 56% to 76% by increasing the reaction time from 1 to 10 h. The molecular weight also increased to 75,900 g.mol$^{-1}$ over the same period, while the increased monomer concentration resulted in a high molecular weight of 86,400 g.mol$^{-1}$ and a monomer conversion of 84%. Raising the reaction temperature from 90 to 130 $^{\circ}C$ increased the monomer conversion as well as the poly-L-lactide-co-${\varepsilon}$-caprolactone (PLCL) molecular weight. The variation on the stannous octoate catalyst suggested that less catalyst would decrease the caprolactone content of the polymer.

• 도시과학
• /
• 제9권2호
• /
• pp.45-50
• /
• 2020

The formation characteristics of calcium carbonates are closely related to the durability and mechanical properties of cement-based materials. In this regard, a deep understanding of the reaction pathway of calcium carbonates is critical. Recently, non-classical nucleation theory was summarized and it was presumed that prenucleation clusters are present. The formation of the prenucleation cluster at undersaturated condition (≈ 0.1 ml) in the present study was investigated via electrical characteristics of an electrolytic solution. Calcium chloride dihydrate (CaCl2·2H2O) and sodium carbonate (Na2CO3) were used as starting materials to supply calcium and carbonate sources, respectively. Furthermore, the reaction pathway of calcium carbonates was investigated by time-resolved polarization and depolarization characteristics of the electrolytic solution. The time-resolved polarization and depolarization tests were conducted by switching polarity with an interval of 20 seconds for 1 hr and by measuring the variation of electrical resistance. It can be inferred from the results obtained in the present study that the reactive constituent for the formation of calcium carbonates was mostly consumed in the period possibly associated with the prenucleation and the reaction pathways may be governed by the monomer-addition mechanism.

• 신재생에너지
• /
• 제19권4호
• /
• pp.11-19
• /
• 2023

Levulinic acid (LA) derived from cellulosic biomass, serves a crucial intermediate that can be used in various chemical conversions. This study focused on optimizing the production of LA using two types of pretreated rice husk (de-ashed and delignificated cellulosic biomass) in a batch reaction system through catalytic conversion with sulfuric acid. To determine the optimal conditions, the conversions of glucose and α-cellulose were examined to compare the effects of pretreatment on the rice husk. The experimental parameters covered a broad spectrum, including temperatures ranging from 140℃ to 200℃, a reaction time was up to 600 minutes, and a substrate to catalyst (acid solution) ratio of 100 g/L. The highest LA yield was 44.8%, achieved from de-ashed rice husk with 3.0 wt.% of sulfuric acid at 180℃ and with a reaction time of 180 minutes. In the case of the delignificated rice husk, a LA yield of 43.6% was obtained with 3.0 wt.% of sulfuric acid at 200℃ and with reaction time of 30 minutes.

• Journal of Astronomy and Space Sciences
• /
• 제25권4호
• /
• pp.481-490
• /
• 2008

반작용휠은 인공위성의 기동 및 자세제어에 사용되는 주요 구동기 중의 하나로 회전체의 속도를 변화시켜 발생하는 토크로 위성의 자세제어를 수행하므로 정밀한 자세제어를 위해서는 정확한 회전속도의 측정이 요구된다. 타코 펄스를 이용한 고속 회전모터의 대표적인 속도 측정방법에는 Elapsed-time측정방법과 Pulse-count측정방법의 두 가지가 있으며 이 연구에서는 반작용휠의 속도 측정을 하는 동안 발생할 수 있는 속도 측정의 오차 및 정밀도를 두 가지 방법에 대해 분석, 비교하였다. 그 결과 Pulse-count측정방법은 반작용휠의 등속 구동 시 회전속도에 상관없는 일정한 오차를 가지는데 비해 Elapsed-time측정방법은 회전속도가 작을수록 오차가 줄어드나 저속일 때 오차가 현저히 커질 수 있음을 해석적으로 확인하였다.

• 한국광학회지
• /
• 제7권4호
• /
• pp.314-321
• /
• 1996

본 논문에서는 은염 재료를 이용한 홀로그래픽 위상형 회절격자 제작에서 각 단계별 화학처리에 대하여 고찰하고 표백방법중 반전표백이 화학적으로 일어날 수 없는 반응이라는 결과를 얻었으며 표백에 대한 새로운 해석을 하였다. 표백방법과 표백액의 종류에 따라 진행되는 화학반응. 반응생성물, 그 특성과 굴절율 변조형태에 대하여 실험 고찰하였다. 노광량이 현상 반응의 촉매로 작용하여 현상시간에 미치는 영향에 대하여 실험하고 최적의 현상 반응시간을 구하여 노광량 50-350[.mu.J/$cm^{2}$] 범위에서 70% 이상의 높은 회절효율을 갖는 회절격자를 제작하였다. 현상액의 농도, 노광량과 현상시간 등 화학적 처리 조건의 상관관계의 실험을 통해 고정된 노광량과 일정하게 정해진 화학적 처리시간만으로는 회절효율을 향상시킬 수 없다는 실험적 결론을 얻었다.

• 대한화학회지
• /
• 제54권6호
• /
• pp.744-748
• /
• 2010

Fluoroquinolone 항생제의 중요한 중간체인 2,3,4,5-tetrafluorobenzoic acid를 tetrachloride phthalic anhydride에서 출발 하여 imidation, fluorination, hydrolysis과 decarboxylation단계를 거쳐서 합성하였다. Imdation 단계에서는 상전이 촉매를 이용하여 98.2%의 수율로 합성하였으며, fluorination 단계에서는 81.3%, 가수분해 단계에서는 88.6%, 마지막으로 decarboxylation단계에서는 81.6%의 수율로 합성하였다.

• 공업화학
• /
• 제4권2호
• /
• pp.324-334
• /
• 1993

천연고분자인 chitin은 인체에 무해무독하며 생분해성이 있는 것으로 알려져 있다. 이 chitin을 탈아세틸화시켜 얻은 chitosan에 propionyl group을 도입하여 porous bead의 형태로 제조하고 이들의 흡수성수지로서의 가능성을 검토하였다. 실험에 사용된 propionyl chitosan porous bead의 합성은 chitosan을 acetic acid 수용액에 녹인 후 emulsion을 이용한 방법으로 아실화 반응을 일으켜 제조하였으며, crosslinked propionyl chitosan porous bead는 ethyleneglycol diglycidyl ether로 부분가교시킨 chitosan을 사용하여 상기와 같은 방법으로 제조하였다. 이때 propionic anhydride의 몰수와 반응시간 그리고 반응온도를 변화시킨 결과, propionyl chitosan의 합성조건은 propionic anhydride 5 moles, 반응시간 10시간 그리고 반응온도가 $22^{\circ}C$일 때 흡수능이 가장 좋은 것을 알 수 있었다. 제조된 porous bead에 대하여 증류수 및 생리식염수, 각종 염용액, 인공뇨 및 인공혈액에 대한 흡수도를 검토하였고, 흡수속도 및 보수력에 대한 교환 사항을 검토하였으며, 나아가 가교에 따른 기계적 강도의 변화를 고찰하였다.

• 대한안전경영과학회지
• /
• 제23권3호
• /
• pp.97-102
• /
• 2021

This study developed a scenario to understand the reaction rate and operational time according to RTI value of rate of rise detector in each type in case of fire mattress. In the results of analyzing the reaction rate and operational time of detector in each scenario, in case when installing a single detector, the elevated temperature per minute was raised to 8℃/min ~ 9℃/min. In case when installing two detectors, it was raised to 9℃/min ~ 10℃/min. In case when installing three detectors, it was raised to 10℃/min. The horizontal distance between detector and mattress was 1.8m~2.5m. Whenever the number of detectors was increased, the horizontal distance was decreased. The operational time of detector was within maximum 540 seconds and minimum 420 seconds. As the research tasks in the future, there should be the researches on the effects of reaction rate of detector on the evacuation in case of fire through the result value of RSET by setting up the latency until the detector operates, and the researches on the safety by understanding if the operational time of detector is suitable for the evaluation standard of performance-centered design.