• 대한화학회지
• /
• 제67권5호
• /
• pp.333-338
• /
• 2023

In this study, the H₂O reaction with SiO clusters was investigated using ab initio Monte Carlo simulations and density functional theory calculations. Three chemistry models, PBE1/DGDZVP (Model 1), PBE1/DGDZVP (Si atom), and aug-cc-pVDZ (O and H atoms), (Model 2) and PBE1/aug-cc-pVDZ (Model 3), were used. The average bond lengths, as well as the relative and reaction energies, were calculated using Models 1, 2, and 3. The average bond lengths of Si-O and O-H are 1.67-1.75 Å and 0.96-0.97 Å, respectively, using Models 1, 2, and 3. The most stable structures were formed by the H transfer from an H₂O molecule except for Si₃O₃-H₂O-1 cluster. The Si₃O₃ cluster with H₂O exhibited the lowest reaction energy. In addition, the Bader charge distributions of the Si_nO_n and (SiO)_n-H₂O clusters with n = 1-7 were calculated using Model 1. We determined that the reaction sites between H₂O and the SiO clusters possessed the highest fraction of electrons.

• 한국재료학회지
• /
• 제22권9호
• /
• pp.445-449
• /
• 2012

We investigate the effects of redox reaction on preparation of high purity ${\alpha}$-alumina from selectively ground aluminum dross. Preparation procedure of the ${\alpha}$-alumina from the aluminum dross has four steps: i) selective crushing and grinding, ii) leaching process, iii) redox reaction, and iv) precipitation reaction under controlled pH. Aluminum dross supplied from a smelter was ground to separate metallic aluminum. After the separation, the recovered particles were treated with hydrochloric acid(HCl) to leach aluminum as aluminum chloride solution. Then, the aluminum chloride solution was applied to a redox reaction with hydrogen peroxide($H_2O_2$). The pH value of the solution was controlled by addition of ammonia to obtain aluminum hydroxide and to remove other impurities. Then, the obtained aluminum hydroxide was dried at $60^{\circ}C$ and heat-treated at $1300^{\circ}C$ to form ${\alpha}$-alumina. Aluminum dross was found to contain a complex mixture of aluminum metal, aluminum oxide, aluminum nitride, and spinel compounds. Regardless of introduction of the redox reaction, both of the sintered products are composed mainly of ${\alpha}$-alumina. There were fewer impurities in the solution subject to the redox reaction than there were in the solution that was not subject to the redox reaction. The impurities were precipitated by pH control with ammonia solution, and then removed. We can obtain aluminum hydroxide with high purity through control of pH after the redox reaction. Thus, pH control brings a synthesis of ${\alpha}$-alumina with fewer impurities after the redox reaction. Consequently, high purity ${\alpha}$-alumina from aluminum dross can be fabricated through the process by redox reaction.

• 한국응용곤충학회지
• /
• 제34권3호
• /
• pp.181-190
• /
• 1995

암컷 Aedes aegypti의 난성숙과장에서 새로 나타나는 malate dehydrogenase(L-malate, $NAD^+$ oxidoreductase, EC 1.11.37, MDH)를 DEAE-Sepharose, Sulphonyl-Sepharose, Cibacron 3FGA affinity chromatography를 이용하여 분리정제하여 그 특성을 조사하였다. 분자량은 70,000 dalton정도의 dimer 형태로 되어 있으며 최적 pH는 malate-oxaloacetate반응에서는 pH 9.0~9.2, oxaloacetate-malate 반응에서는 pH 9.8~10.2이었다. 정재된 MDH는 mitochondria에 위치하고 있으며 기질로서 malate에 대한 Km값의 경우 $1.29 \times 10^{-4}$ M, oxaloacetate에 대한 Km 값은 $6.58\times 10^{-4}$M, NAD에 대한 Km값은 $0.76\times 10^{-3}$ M이며 NADH에 대한 Km 값은 $3.8\times 10^{-3}$ M 을 보이고 있으며 각각의 기질에 의한 저해현상을 보이고 있었다. 기질에 대한 Km값을 부분적으로 분리한 DEAE-sepharose에 흡착된 원형질 MDH와 비교한 결과 malate에 대한 Km 이 $8.92\times 10^{-3}$으로 상당한 차이를 보이고 있었다. 또한 정제된 MDH는 cltrate, $\alpha$-ketoglutarate, ATP 등의 대사산물에 의하여 저해작용을 받았다. ATP 및 citrate에 의한 MDH 활성도 저해는 oxaloacetate-malate반응에서 보다는 malate-oxaloacetate 반응에서 덜 일어났다. Oxaloacetate-malate 반응의 경우 ATP에 의하여저해작용이 완전히 일어났으며 malate-oxaloacetate반응에서는 cltrate에 의하여 저해작용이 일어나지 않았다. 흡혈 후 생성되는 MDH는 난소에서 합성되며 흡혈 수 난소에서 18시간 때부터 활성도가 나타나 48시간 이후 최고 활성도가 유지되는데 TCA회로의 isocitrate dehydrogenase 의 경우 난소내에서의 활성도 변화가 MDH의 변화 양상과 같았다.

• Nuclear Engineering and Technology
• /
• 제4권3호
• /
• pp.186-193
• /
• 1972

Rose $Bengal-^{131}$ /I, $Hippuran-^{131}$ /I, $H.S.A-^{131}$ /I 등을 효과적으로 합성하기 위해 표지 반응액의 pH, 염의함량, 반응액중의 완충용액의 부피 및 합성장치등에 따르는 표지 반응수율을 검토하였다. Rose $Bengal-^131{ }$I 및 $Hippuran-^{131}$ /I 의 반응수율은 PH 5.6에서, $H.S.A-^{131}$ /I 반응수율은 pH 8.5에서 각각 가장 좋았다. 반응액중에 함유된 염은 $Hippuran-^{131}$ /I의 생성반응을 크게 저해 시켰으며 H.S.A.의 표지수율은 어느 범위안에서 오히려 약간 향상시켰다. Rose $Bengal-^{131}$ /I 나 $Hippuran-^{131}$ /I 를 소규모 합성할 경우는 밀폐된 용기가 효과적이었다. 이상의 결과에 따라 더 높은 표지수율과 좋은 재현성을 얻을 수 있는 반응조건을 확립하였으며 이에 따라 환원제가 함유된 국산 $Na^{131}$ /I를 사용하더라도 Rose $Bengal-^{131}$ /I과 $Hippurn=^{131}$ /I의 표지수율을 높일 수 있었다.

• 한국환경과학회지
• /
• 제25권12호
• /
• pp.1717-1726
• /
• 2016

In this study, the reductive decolorization of three acid and basic dyes using modified zero-valent iron (i.e., acid-washed iron (Aw/Fe) and palladium coated iron (Pd/Fe)) at various pH conditions (pH 3~5) was experimentally investigated and the decolorization characteristics were evaluated by analyzing the absorbance spectra and reaction kinetics. In the case of acid dyes such as methyl orange and eriochrome black T, color removal efficiencies increased as initial pH of the dye solution decreased. However, the color removal of methylene blue, a basic dye, was not affected much by the initial pH and more than 70% of color was removed within 10 min. During the decolorization reaction, the absorbance of methyl orange (${\lambda}_{max}=464nm$) and eriochrome black T (${\lambda}_{max}=528nm$) decreased in the visible range but increased in the UV range. The absorbance of methylene blue (${\lambda}_{max}=664nm$) also decreased gradually in the visible range. Pseudo-zero order, pseudo-first order, and pseudo-second order kinetic models were used to analyze the reaction kinetics. The pseudo-second order kinetic model was found to be the best with good correlation. The decolorization reaction rate constants ($k_2$) of methylene blue were relatively higher than those of methyl orange and eriochrome black T. The reaction rate constants of methyl orange and eriochrome black T increased with a decrease in the initial pH.

• 한국환경과학회지
• /
• 제30권1호
• /
• pp.69-76
• /
• 2021

The purposes of this study were to evaluate the removal characteristics of COD, Ni, and P and to derive appropriate operating conditions for the plating wastewater according to NaOCl reaction time and pH operating conditions in the BPC unit process during the plating wastewater treatment process. As a results of evaluating the removal characteristics for raw wastewater by each BPC unit process, the removal efficiencies of COD, Ni and P in BPC 1-1 unit process were 72.8%, 99.1%, and 100.0%. Therefore, the proper reaction time of NaOCl was derived as 21.1 minutes. In order to maintain the +800 mV ORP and the reaction time of 20 minutes, the temporary injection and continuous injection of NaOCl in the BPC unit process were 13.7 mL and 18.7 mL, respectively. It was found that the temporary injection method of NaOCl reduced the chemical cost by 36.5% compared to the continuous injection method. Also, Ni showed the highest removal efficiency of 97.8% at pH 10.5. On the other hand, P showed a removal efficiency of 57.4% at pH 10.0.

• Archives of Pharmacal Research
• /
• 제14권2호
• /
• pp.118-123
• /
• 1991

Potentially dangerous nitrosamines have been shown to result from the reaction of sodium nitrogusside with several drugs under physiological conditions (pH 7.3 and $37^\circ{C})$. In each case the products were identical to those produced upon reaction with nitrous acid at much lower pH values. Reaction rates were shown to reflect a first order dependence on both amine and nitroprusside concentrations and to increase at higher pH values, approximately in proportion to concentrations of unprotonated amine. Fast reactions of sodium nitroprusside with reduced glutathione, cysteine, and ascorbate suppress but do not prevent the conversion of amines into N-nitrosamines. These results show sodium nitroprusside to be very potent nitrosating agent under physiological conditions and suggested nitrosamines may be formed during its normal pharmacological administration.

• 약학회지
• /
• 제39권1호
• /
• pp.48-54
• /
• 1995

Coupling of tetracycline(Tc) to dithiocarbamate chitosan(DTCC) via chelate bond was investigated varying reaction time, concentration, temperature, pH, and Ca(II)/Tc ratio. The amount of Tc bound to matrix increased to give a maximum and decreased as the reaction proceeded. The degree and rate of dissociation of Tc complex were affected by the reaction temperature, and pH. By running the reaction at low temperature and pH, the degree of dissociation was greatly diminished. Properties of drug-release from DTCC-Ca(II)-Tc complex were studied by batch- and flow-method and release of Tc and CA(II) by flow method followed nearly zero-order. DTCC-Ca(II)-Tc showed very prolonged antimicrobial activity compared to that of free Tc.

• 한국환경보건학회지
• /
• 제27권1호
• /
• pp.93-99
• /
• 2001

This study aims at finding out pertinent reaction conditions for treating high concentration ammonia contained in N-chemical factory wastewater with decompressed ammonia stripping method that was designed. And it also tries to investigate adsorption capability of removed ammonia to soil. The results from experiments are as follows ; 1. The removal rate of N $H_3$-N of synthetic wastewater was under 85% at pH 10 with decompressed ammonia stripping method. The reaction time in pressure 360 mmHg at pH 11 and 12 was shorter than in 460 mmHg, and the removal rate of N $H_3$-N with decompressed ammonia stripping method at 9$0^{\circ}C$ was 11~15% higher than air stripping 2. The optimum conditions for decompressed ammonia stripping with synthetic sample were shown as pH 12, temperature 9$0^{\circ}C$, internal reaction pressure 460 mmHg and reaction time 50 minutes. These conditions were applied to treat the wastewater containing organic-N 290.5mg/$\ell$, N $H_3$-N 168.9mg/$\ell$, N $O_2$-N 23.2mg/$\ell$, N $O_3$-N 252.4mg/$\ell$, T-N 735mg/$\ell$. Organic-N turned out to be removed 60%, the removal rate of N $H_3$-N IS 94%, T-N is 50%. But N $O_2$-N and N $O_3$-N were increased with 7.8% and 14.9% respectively. 3. The CO $D_{Sr}$ removal rate in decompressed ammonia stripping reaction was 42% and S $O_4$$^{2-}$ was removed 8.2%. It was turned out caused with higher pH and thermolysis. 4. In soil adsorption of ammonia desorbed from the decompressed stripping process of wastewater, the recovery rate was 76% in wet soil.

• 분석과학
• /
• 제13권1호
• /
• pp.41-48
• /
• 2000

돼지의 소장조직을 탄소반죽에 혼입시켜 과산화수소 정량 바이오센서를 제작하고, 기질농도와 pH변화가 전극의 효소반응속도에 미치는 영향을 관찰하였다. 수학적 취급이 용이하도록 매개체는 첨가하지 않았다. 관찰된 현상들을 정량적으로 처리하여 전극반응에 관련된 효소의 전기화학적 특성과 최대 반응속도를 구하였다. 또, pH에 따른 Michaelis 상수의 변화로부터 여러 가지 열역학적 파라미터를 얻고, 이를 이용하여 효소활동의 최적 pH를 구하는 방법을 고안하였다.