• Title/Summary/Keyword: reaction index

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Influence of Changing Combustor Pressure on Combustion Characteristics and Local Reaction Intensity in the CH4/Air Flames (메탄/공기 화염에서 연소실 압력변동이 연소특성과 국소 반응강도에 미치는 영향)

  • Kim, Jong-Ryul;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.365-372
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    • 2009
  • The influence of combustor pressure on the local reaction characteristics of $CH_4$/air flames was investigated by measurements of local chemiluminescence intensity. Induced flow flames are often applied to the industrial boiler systems and incinerator in order to improve heat transfer and prevent exhaust gas leakage. In order to investigate combustion characteristics in the induced flow pattern, the combustor pressure index($P^*$) was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. Relationship between local reaction intensity and pressure index have been investigated by simultaneous $CH^*$, $C^*_2$ and $OH^*$ intensity measurements. It could be observed that flame length became longer with decreasing $P^*$ from $CH^*$ chemiluminescence intensity of axial direction. The mean value of $C^*_2$ and $CH^*$ chemiluminescence intensities, which indicates reaction intensity in the $CH_4$/air flames, decreased with decreasing pressure index for ${\Phi}{\leq}1$, but increased with decreasing pressure index for ${\Phi}$>1. $C^*_2/CH^*$ intensity ratio, which can be a good marker to demonstrate local equivalence ratio, was almost same for ${\Phi}{\leq}1$ regardless of pressure index change, while they showed high level for lower pressure index for ${\Phi}$>1 conditions.

Generation of Graded Index Profile of Poly(methyl methacrylate) by a Photochemical Reaction

  • Yun, Hyun-Chu;Im, Sang-Hyuk;Suh, Duck-Jong;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
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    • v.11 no.4
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    • pp.236-240
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    • 2003
  • Fabrication of a graded index profile was possible via photochemical reaction of cinnamoyl groups with 350 nm wavelength UV light to form crosslinked structures. Such structural change may induce the change in the refractive index. In order to generate graded index profile in the PMMA polymer optical fiber (POF) with cinnamoyl groups by photochemistry, a methyl methacrylate monomer containing a cinnamoyl functional group in the side chain were prepared. This monomer was then copolymerized with methyl methacrylate with various compositions not only to utilize advantages of poly(methyl methacrylate) but also to overcome the drawbacks of the cinnamate homopolymer. Changes of refractive indices were investigated with various contents of cinnamoyl group and varying irradiation time. Large change in the refractive index (${\Delta}{\approx}0.01$) and its proper profile shape ($g{\approx}2.2$) can be obtained by changing irradiation time.

The Investigation of Influence of Chlorinated Hydrocarbons on $NO_x$ Formation from Methane Flames (메탄 화염에서 염화 탄화수소 화합물이 질소산화물 생성에 미치는 영향 조사)

  • Jang, Kyoung;Jang, Bong-Choon;Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.13 no.1
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    • pp.10-16
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    • 2008
  • Numerical simulations of freely propagating premixed flames burning mixtures of methane and chlorinated hydrocarbons in fuel are performed at atmospheric pressure in order to understand the effect of chlorinated hydrocarbons on the formation of nitrogen oxide. A detailed chemical reaction mechanism is used, the adopted scheme involving 89 gas-phase species and 1017 elementary forward reaction steps. Chlorine atoms available from chlorinated hydrocarbons inhibit the formation of nitrogen oxides by lowering the concentration of radical species. The reduction of NO emission index calculated with thermal or prompt NO mechanism is not linear and is probably related to the saturation effect as $CH_3Cl$ addition is increased, In the formation or consumption of nitrogen oxide, the $NO_2$ and NOCl reactions play an important role in lean flames while the HNO reactions do in rich flames. The molar ratio of Cl to H in fuel has an effect on the magnitude of NO emission index.

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Characteristics of Maltose Formation in Heterogeneous Enzyme Reaction System Utilizing Swollen Extrusion Starch as a Substrate (팽윤 Extrusion 전분을 기질로 한 불균일상 효소반응계에서의 Maltose 생성 반응 특성)

  • Kim, Dong-Sun;Park, Dong-Chan;Cho, Myung-Jin;Lee, Yong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.22 no.3
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    • pp.283-289
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    • 1994
  • The production of maltose utilizing swollen extrusion starch seems to have many technical advantages, such as, high reaction rate and high yield, production of high purity concentrated maltose, and low energy consumption, over the conventional method utilizing liquefied starch. The characteristics of maltose formation in heterogeneous enzyme reaction system comtaining swollen extrusion starch was investigated using fungal $\alpha $-amylase. The influence of extrusion conditions on structure of extruded starch, such as, degree of gelatinization, water absorption index, and water solubility index was analyzed. The relationship between the structural features and maltose forming reaction was investigated, and the result was analyzed in terms of surface reaction of insoluble extruded swollen starch. The characteristics of maltose formation from swollen sxtrusion starch was compared using endo-type fungal $\alpha $-amylase and exo-type $\beta $anylase, and the structural trasformation of extruded starch was also observed to clarify the reaction mechanism.

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The Effect of Temperature and pH on Bromate Formation by Ozonation (오존처리시 Bromate생성에 미치는 온도 및 pH의 영향)

  • Lee, Mu Gang;Kim, Yeong Cheol;Choe, Jong Won
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.667-674
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    • 2004
  • The objective of this study was to investigate the effects of pH and temperature on the formation of bromate, which is ozonation by-products, during ozonation. In this experiment, the operating parameters including pH 3 ~ 10 and temperature 15 ~ $30^{\circ}C$ were studied. Through the study for the bromate formation, reaction rate constant, and ozonation effect index on pH and temperature, the results obtained are as follows. At the same initial pH condition, the increase of pH shown similar trends even if the reaction variables such as temperature and reaction time of ozonation were exchanged. As pH and temperature were increasing, the bromate concentration was increased but bromine(HOBr+OBr) was decreased with increasing pH from 3 to 10. The activation energy(J/mol) for bromate formation decreased with increasing pH. The rate constants of bromate formation for the reaction of ozone and bromide, and ozone dosage coefficient$(K_{0})$ increased with temperature and pH. Ozonation effect index(OI) decreased with increasing temperature and pH.

A Study on the Quality Improvement of Mobile App Services of Medical Institutions: Focus on the Kano Model and PCSI Index

  • PARK, Ae-Jun;LEE, Yeon-Sook
    • The Journal of Industrial Distribution & Business
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    • v.10 no.6
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    • pp.19-27
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    • 2019
  • Purpose - The purpose of this study was to examine quality improvement priorities by examining not only quality classifications but also PCSI (Kano, 1984) of mobile app service qualities of general hospitals in the Metropolitan Area and offer potential improvements. Research design, data, and methodology - The study examined five of service qualities, including app design, reaction, convenience, safety and supply of information by precedent studies. 20 test items were selected. A total of 60 positive and negative questions to estimate customer satisfaction and PCSI was investigated. The author collected 300 copies from interviewees who made use of the app services of 13 general hospitals within one year, and classified quality factors by using table of quality assessment and also estimated the customer satisfaction index (Timko, 1993). The study made quality improvement priority by the PCSI index. Results - Reaction of the mobile app service quality ranked the highest PCSI, and payment safety ranked the highest, and customer support and supply of the information ranked high as well. It was observed that design ranked comparatively lower in these categories. Conclusion - Safety, reaction and supply of information should be prioritized to reorganize and improve the mobile app services.

Studies on Manufacturing Possibility of Paper Sludge- Cement Board (I) -Measurement of Inhibitory Index by Hydration Reaction- (제지(製紙) Sludge-Cement Board의 제조가능성(製造可能性)에 관(關)한 연구(硏究)(I) -수화반응(水和反應)에 의(依)한 경화장해지수측정(硬化障害指數測定)-)

  • Kim, Sa-Ick;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.3
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    • pp.74-81
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    • 1993
  • This experiment was carried out to investigate the reaction of hydration of paper sludge during the setting of portland cement in a paper sludge, wood-cement-water mixturte. The percentage of paper sludge per cement is 7.5%, 15%, 30% respectively. The result indicated that the sludge of 7.5% had the most effect on reaction of hydration, and the sludge of 15% had moderately inhibitory effect but there is still possibility to make sludge-cement board. Paper sludge of 30%, Pinus koraiensis Sieb. et Zucc and Populus euramericana Guinier were proved to have the worst inhibitory effect on cement hydration, so pretreatment will be needed before making board with paper sludge-cement mixture.

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The Effect of Genu Valgum on the Body Mass Index, Moment of Lower Limb Joints, Ground Reaction Force (신체질량지수, 하지관절의 모멘트, 지면반발력이 무릎외반슬에 미치는 영향)

  • Lee, Yong-Seon
    • Korean Journal of Applied Biomechanics
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    • v.25 no.3
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    • pp.257-263
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    • 2015
  • Objective : The purpose of this study was to investigate the effect of genu valgum on the body mass index, movement of lower limb joints, and ground reaction force. Methods : Gait patterns of 30 college students with genu valgum were analyzed and the static Q angle of the femur was measured for selecting genu valgum of the subjects. To analyze the kinetic changes during walking, the six-camera Vicon MX motion analysis system was used. The subjects were asked to walk 12 meters using the more comfortable walking method for walking. After they walked 12 meters more than 10 times, their most natural walking patterns were chosen three times and analyzed. Results : As a result of measuring a relationship between genu valgum and Q-angle, as the Q-angle increases, it showed a genu valgum also increased. Body Mass Index showed a significant difference between the groups was higher in the genu valgum group.(p<.001). The analysis result showed that genu valgum had a significant effect on the internal rotation moment in the hip joint(p<.05). Also, genu valgum had a significant effect on the internal rotation moment of the knee joint(p<.05). The comparative analysis of the Medial-Lateral ground reaction force in the genu valgum group showed a tendency to increase the medial ground reaction force(p<.05). The vertical ground reaction forces of the middle of the stance phase(Fz0) showed a significant increase in genu valgum group(p<.05), in particular the results showed a decrease in the early stance phase(p<.001). Conclusion : In conclusion, the change in body mass is considered to be made by proactive regular exercise for improvement of the genu valgum. In addition, the prevention of the deformation caused by secondary of the genu valgum in this study may be used as an indicator of the position alignment rehabilitation for structural and functional improvements. Applying a therapeutic exercise program for the next lap will require changes in posture alignment.

NOx and CO Emission Characteristics of Porous Inert Medium Burner (다공물질 연소기의 NOx 및 CO 배출 특성)

  • 임인권
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.559-567
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    • 1995
  • The combustion process within a porous inert medium (PIM) burner is numerical studied. A detailed chemical reaction scheme including thermal and prompt NO$_{x}$ reactions is used to predict the formation and destruction of pollutants such as NO$_{x}$ and CO. The reaction paths for NO$_{x}$ formation are divided to quantify the amount of NO$_{x}$ formed through thermal NO$_{x}$ reaction or through prompt NO$_{x}$ reaction. Emission index is calculated to compare the actual mass of NO$_{x}$ or CO produced through the combustion of unit mass of fuel. It is found NO formation in PIM burner is confined in flame zone and formation is suppressed due to heat loss at down-stream of the flame. Higher production of NO through prompt NO reaction path is observed due to the higher concentration of fuel derivative species and its higher diffusion at flame front. For all equivalence ratios, CO emission within PIM burner is lower than that from the one-dimensional freely-propagating flame. PIM burner flame has better NO$_{x}$ emission index from .psi. = 0.75 to .psi. = 1.1. to .psi. = 1.1.